C23C2/024

Zinc-plated steel sheet and manufacturing method thereof

A zinc-plated steel sheet of an aspect of the present invention includes a steel sheet having a predetermined chemical composition and a zinc-plated layer. In the steel sheet, steel microstructures in a range of ⅛ thickness to ⅜ thickness, having the center at ¼ thickness from a steel sheet surface, include, by vol %, ferrite: 0% to 10%, bainite: 0% to 20%, tempered martensite: 70% or more, fresh martensite: 0% to 10%, retained austenite: 0% to 10%, and pearlite: 0% to 5%. In the zinc-plated steel sheet, the amount of hydrogen emitted when the steel sheet is heated to 200° C. from a room temperature after removal of the zinc-plated layer is 0.40 ppm or less per mass of the steel sheet, the tensile strength is 1470 MPa or more, and no cracking occurs in a U-shape bending test where a stress equivalent to 1000 MPa is applied for 24 hours.

METHOD FOR PRODUCING A HIGH STRENGTH COATED STEEL SHEET HAVING IMPROVED DUCTILITY AND FORMABILITY, AND OBTAINED COATED STEEL SHEET
20230193412 · 2023-06-22 ·

A method for producing a coated steel sheet having a tensile strength TS of at least 1100 MPa, a total elongation TE according to ISO standard 6892-1 of at least 12%, the product TS×TE of the tensile strength by the total elongation being at least 14200 MPa %, and a hole expansion ratio HER according to ISO standard 16630:2009 of at least 25%, the method including the following successive steps: providing a cold-rolled steel sheet, the chemical composition of the steel containing in weight %: 0.15%≤C≤0.23%, 2.0%≤Mn≤2.7%, with C+Mn/10≥0.420%, 0≤Cr≤0.40%, with Mn+Cr≥2.25%, 0.2%≤Si≤1.6%, 0.02%≤Al≤1.2%, with 1.0%≤Si+Al≤2.2%, 0≤Nb≤0.035%≤Mo≤0.1%, the remainder being Fe and unavoidable impurities, annealing the steel sheet at an annealing temperature T.sub.A so as to obtain a structure comprising at least 65% of austenite and at most 35% of intercritical ferrite, quenching the sheet from a temperature of at least 600° C. at a cooling rate comprised between 20° C./s and 50° C./s down to a quenching temperature QT between 200° C. and 270° C., heating the sheet up to a partitioning temperature PT comprised between 400° C. and 480° C. and maintaining the sheet at this partitioning temperature PT for a partitioning time Pt comprised between 50 s and 250 s, hot-dip coating the sheet at a temperature less than 515° C., cooling the coated sheet down to the room temperature,
the steel sheet having a microstructure consisting of, in surface fraction: between 3% and 15% of retained austenite, at least 30% of tempered martensite, at most 5% of fresh martensite, at most 35% of bainite, the sum of the surface fractions of tempered martensite, fresh martensite and bainite being comprised between 55% and 92%, and between 5% and 35% of ferrite.

Steel sheet and manufacturing method therefor

This steel sheet has a predetermined chemical composition, in which a steel structure of an inside of the steel sheet contains, by volume fraction, soft ferrite: 0% to 30%, retained austenite: 3% to 40%, fresh martensite: 0% to 30%, a sum of pearlite and cementite: 0% to 10%, and a remainder includes hard ferrite, a number proportion of the retained austenite having an aspect ratio of 2.0 or more in the total retained austenite is 50% or more, a soft layer having a thickness of 1 to 100 μm from a surface in a sheet thickness direction is present, in ferrite contained in the soft layer, a volume fraction of grains having an aspect ratio of 3.0 or more is 50% or more, a volume fraction of retained austenite in the soft layer is 80% or less of the volume fraction of the retained austenite in the inside of the steel sheet, and a peak of an emission intensity at a wavelength indicating Si appears in a range of more than 0.2 μm and 10.0 μm or less from the surface.

Coated steel member, coated steel sheet, and methods for producing same

This coated steel member includes: a steel sheet substrate having a predetermined chemical composition; and a coating formed on a surface of the steel sheet substrate and containing Al and Fe, in which the coating has a low Al content region having an Al content of 3 mass % or more and less than 30 mass % and a high Al content region formed on a side closer to a surface than the low Al content region and having an Al content of 30 mass % or more, a maximum C content of the high Al content region is 25% or less of a C content of the steel sheet substrate, a maximum C content of the low Al content region is 40% or less of the C content of the steel sheet substrate, and a maximum C content in a range from an interface between the steel sheet substrate and the coating to a depth of 10 μm on a side of the steel sheet substrate is 80% or less of the C content of the steel sheet substrate.

HIGH-STRENGTH STEEL SHEET, HIGH-STRENGTH HOT-DIP GALVANIZED STEEL SHEET, HIGH-STRENGTH HOT-DIP ALUMINUM-COATED STEEL SHEET, AND HIGH-STRENGTH ELECTROGALVANIZED STEEL SHEET, AND METHODS FOR MANUFACTURING SAME

A high-strength steel sheet with excellent formability and high yield ratio that has TS of 980 MPa or more and YR of 68% or more is obtained by providing a predetermined chemical composition and a steel microstructure that contains, in area ratio, 15 to 55% of polygonal ferrite, 8% or more of non-recrystallized ferrite, and 15 to 30% of martensite, and that contains, in volume fraction, 12% or more of retained austenite, in which the polygonal ferrite has a mean grain size of 4 μm or less, the martensite has a mean grain size of 2 μm or less, the retained austenite has a mean grain size of 2 μm or less, and a value obtained by dividing an Mn content in the retained austenite (in mass %) by an Mn content in the polygonal ferrite (in mass %) equals 2.0 or more.

HOT-ROLLED AND COATED STEEL SHEET FOR HOT-STAMPING, HOT-STAMPED COATED STEEL PART AND METHODS FOR MANUFACTURING THE SAME
20230167557 · 2023-06-01 ·

A method for manufacturing a hot-rolled and coated steel sheet having a thickness between 1.8 mm and 5 mm. The method contains the steps of: providing a semi-product having a composition containing: 0.04%≤C≤0.38%, 0.40%≤Mn≤3%, 0.005%≤Si≤0.70%, 0.005%≤Al≤0.1%, 0.001%≤Cr≤2%, 0.001%≤Ni≤2%, 0.001%≤Ti≤0.2%, Nb≤0.1%, B≤0.010%, 0.0005%≤N≤0.010%, 0.0001%≤S≤0.05%, 0.0001%≤P≤0.1%, Mo≤0.65%, W≤0.30%, Ca≤0.006%, hot-rolling with a final rolling temperature FRT, to obtain a hot-rolled steel product having a thickness between 1.8 mm and 5 mm, then cooling down to a coiling temperature T.sub.coil satisfying: 450° C.≤T.sub.coil≤T.sub.coilmax with T.sub.coilmax=650−140×fγ, T.sub.coilmax being expressed in degrees Celsius and fγ designating the austenite fraction just before the coiling, and coiling to obtain a hot-rolled steel substrate, pickling and coating the hot-rolled steel substrate with Al or an Al alloy by continuous hot-dipping in a bath, to obtain a hot-rolled and coated steel sheet containing a hot-rolled steel sheet and an Al or an Al alloy coating, having a thickness between 10 and 33 μm, on each side of the hot-rolled steel sheet.

HOT ROLLED COATED STEEL SHEET HAVING HIGH STRENGTH, HIGH FORMABILITY, EXCELLENT BAKE HARDENABILITY AND METHOD OF MANFUACTURING SAME
20230167523 · 2023-06-01 · ·

The hot-rolled coated steel sheet comprising: in wt %, C: 0.05-0.14%, Si: 0.1-1.0%, Mn: 1.0-2.0%, P: 0.001-0.05%, S: 0.001-0.01%, AI: 0.01-0.1%, Cr: 0.005-1.0%, Ti: 0.005-0.13%, Nb: 0.005-0.03%, N: 0.001-0.01%, Fe residues, and other inevitable impurities; a mixed structure of ferrite and bainite as a main phase; and as a remaining structure, one or more selected from the group consisting of martensite, austenite, and phase martensite (MA), wherein a fraction of the ferrite and bainite is 95-99 area % and Equation 1 is satisfied. [Equation 1] FCO.sub.{110}<112>+FCO.sub.{112}<111>≥10 where, FCO.sub.{110}<112> and FCO.sub.{112}<111>, each representing an area fraction occupied by a structure having ac crystal orientation of {110}<112> and {112}<111>.

HIGH-STRENGTH STEEL SHEET AND METHOD FOR MANUFACTURING SAME

Disclosed is a steel sheet having a predetermined chemical composition and a steel microstructure that contains, in area ratio, 35% or more and 80% or less of polygonal ferrite and 5% or more and 25% or less of martensite, and that contains, in volume fraction, 8% or more of retained austenite, in which the polygonal ferrite, the martensite, and the retained austenite have a mean grain size of 6 μm or less, 3 μm or less, and 3 μm or less, respectively, and each have a mean grain aspect ratio of 2.0 or less, and in which a value obtained by dividing an Mn content in the retained austenite in mass % by an Mn content in the polygonal ferrite in mass % equals 2.0 or more.

HOT-DIP GALVANIZED STEEL SHEET

A hot-dip galvanized steel sheet wherein the hot-dip galvanized steel sheet comprises a base steel sheet and a hot-dip galvanized layer, a ferrite phase is, by volume fraction, 50% or less in a range of ⅛ thickness to ⅜ thickness centered at a position of ¼ thickness from the surface of the base steel sheet, a hard structure is 50% or more, wherein the hot-dip galvanized steel sheet has the hot-dip galvanized layer in which Fe is 5.0% or less and Al is 1.0% or less, and columnar grains formed of a ζ phase is 20% or more in an entire interface between the plated layer and the base steel sheet, on the surface of the base steel sheet in which a volume fraction of a residual austenite is 3% or less and a ratio of a volume fraction of the hard structure is 0.10 times or more to 0.90 times or less of that of the hard structure in the range of ⅛ thickness to ⅜ thickness in a range of 20 μm depth in a steel sheet direction originating an interface between the hot-dip galvanized layer and the base steel sheet, and wherein the hot-dip galvanized steel sheet has a refined layer at the side of the interface in the base steel sheet, and wherein an average thickness of the refined layer, an average grain size of ferrite in the refined layer and a maximum size of the oxide included in the refined layer are defined respectively.

FERRITIC STAINLESS STEEL SHEET AND METHOD OF PRODUCING SAME, AND AL OR AL ALLOY COATED STAINLESS STEEL SHEET

A ferritic stainless steel sheet comprises a chemical composition containing, in mass %, C: 0.030% or less, Si: 3.0% or less, Mn: 1.0% or less, P: 0.040% or less, S: 0.010% or less, Cr: 11.0% to 30.0%, Al: 8.0% to 20.0%, Ni: 0.05% to 0.50%, N: 0.020% or less, and at least one selected from the group consisting of Zr: 0.01% to 0.20% and Hf: 0.01% to 0.20%, with a balance consisting of Fe and inevitable impurities.