A composite structure with an aluminum-based alloy layer containing boron carbide and a manufacturing method thereof are provided. The composite structure includes a substrate with an open hole in that surface and the aluminum-based alloy layer containing boron carbide. The aluminum-based alloy layer is disposed in the open hole and contains aluminum, boron, carbon, and oxygen, wherein the content of aluminum is between 4 at. % and 55 at. %, the content of boron is between 9 at. % and 32 at. %, the content of carbon is between 13 at. % and 32 at. %, the content of oxygen is between 2 at. % and 38 at. %, and the ratio of the content of boron to carbon is between 0.3 and 2.7.

An article including at least one first metallic layer, at least one dielectric layer; and at least one second metallic layer is disclosed. The at least one dielectric layer can include at least one of (i) a photo-initiator, (ii) an oxygen inhibition mitigation composition, (iii) a leveling agent, and (iv) a defoamer.

An article including at least one first metallic layer, at least one dielectric layer; and at least one second metallic layer is disclosed. The at least one dielectric layer can include at least one of (i) a photo-initiator, (ii) an oxygen inhibition mitigation composition, (iii) a leveling agent, and (iv) a defoamer.

An yttrium oxyfluoride sprayed coating contains Y.sub.5O.sub.4F.sub.7 as a main component. In the yttrium oxyfluoride sprayed coating, when the total intensity of all peaks attributable to yttrium oxyfluoride in a diffraction spectrum obtained by X-ray diffractometry is assumed to be 100, the total intensity of all peaks attributable to yttrium fluoride and yttrium oxide is less than 10. Furthermore, in an yttrium oxyfluoride-containing sprayed coating, when the total intensity of all peaks attributable to yttrium oxyfluoride and yttrium fluoride in a diffraction spectrum obtained by X-ray diffractometry is assumed to be 100, the total intensity of all peaks attributable to yttrium oxide is less than 1.

An yttrium oxyfluoride sprayed coating contains Y.sub.5O.sub.4F.sub.7 as a main component. In the yttrium oxyfluoride sprayed coating, when the total intensity of all peaks attributable to yttrium oxyfluoride in a diffraction spectrum obtained by X-ray diffractometry is assumed to be 100, the total intensity of all peaks attributable to yttrium fluoride and yttrium oxide is less than 10. Furthermore, in an yttrium oxyfluoride-containing sprayed coating, when the total intensity of all peaks attributable to yttrium oxyfluoride and yttrium fluoride in a diffraction spectrum obtained by X-ray diffractometry is assumed to be 100, the total intensity of all peaks attributable to yttrium oxide is less than 1.

A thermal spray apparatus to apply coatings to external and internal surfaces in restricted areas is provided. The apparatus includes: a combustion chamber having a primary passage for combustion of fuel received through a fuel input line with oxygen or air received through an oxidizing gas input line; a divergence section located downstream of the combustion chamber; an elbow housing located downstream of the divergence section. A nozzle housing retaining a nozzle having an injection zone and a nozzle throat; a convergence section retained between the elbow housing and the nozzle housing; a feedstock injector for the injection of feedstock material into the injection zone of said nozzle; and a plurality of passageways extending through the combustion chamber, the divergence section, the elbow housing, and the convergence section for passing a coolant therethrough.

A thermal spray apparatus to apply coatings to external and internal surfaces in restricted areas is provided. The apparatus includes: a combustion chamber having a primary passage for combustion of fuel received through a fuel input line with oxygen or air received through an oxidizing gas input line; a divergence section located downstream of the combustion chamber; an elbow housing located downstream of the divergence section. A nozzle housing retaining a nozzle having an injection zone and a nozzle throat; a convergence section retained between the elbow housing and the nozzle housing; a feedstock injector for the injection of feedstock material into the injection zone of said nozzle; and a plurality of passageways extending through the combustion chamber, the divergence section, the elbow housing, and the convergence section for passing a coolant therethrough.

A thermal spray cabin comprising a table to hold a part to be coated and a robot with a robot body and an arm, a spray gun mounted on the arm of the robot, a ventilation system comprising an air inlet and a suction hood designed to create a gas flow with a main stream from the air inlet to the suction hood thereby passing the table in an operating state of the thermal spray cabin. The air inlet, the table, the robot and the suction hood are arranged in such a way, that the robot body is positioned outside the main stream of the gas flow in the operating state.

Provided is an equipment system for producing a piercing-rolling plug to be used for producing a seamless steel tube/pipe, which includes a shotblasting device for applying shotblasting on a surface of the plug, and an arc-spraying device for performing arc-spraying of iron wires on a surface of a base metal of the plug to which the shotblasting is applied, so as to form a film containing oxide and Fe thereon. The arc-spraying device includes plural spraying booths each of which separately forms part of the film in turn in each of sections into which the surface of the base metal of the plug is divided along an axial direction of the plug. The production efficiency of the plug can therefore be maintained at a high level, and steady enhancement of the durability life of the plug can be realized during the piercing-rolling.

Provided is an equipment system for producing a piercing-rolling plug to be used for producing a seamless steel tube/pipe, which includes a shotblasting device for applying shotblasting on a surface of the plug, and an arc-spraying device for performing arc-spraying of iron wires on a surface of a base metal of the plug to which the shotblasting is applied, so as to form a film containing oxide and Fe thereon. The arc-spraying device includes plural spraying booths each of which separately forms part of the film in turn in each of sections into which the surface of the base metal of the plug is divided along an axial direction of the plug. The production efficiency of the plug can therefore be maintained at a high level, and steady enhancement of the durability life of the plug can be realized during the piercing-rolling.