A liquid passivation mixture for passivating an outer layer of a substrate comprises a first material selected from group consisting of sulfur or selenium and a base selected from a group consisting of quaternary ammonium compound, sodium hydroxide (NaOH), potassium hydroxide (KOH), and amine.

Embodiments of the present disclosure provide a surface treatment composition and methods for using same. The composition for removing contaminants from a metallic surface, can include 3 wt % to 40 wt % of at least one bifunctional alkaline compound, 0.03 wt % to 10 wt % of at least one oxidizer comprising a metal salt, and water, where all weight percentages are based on the total weight of the composition.

A steel sheet for a fuel tank includes: a ZnNi alloy plated layer which is placed on one surface or each of both surfaces of a base metal and formed on at least one surface; and an inorganic chromate-free chemical conversion coating film which is placed over the ZnNi alloy plated layer. The ZnNi alloy plated layer has a crack starting from an interface between the ZnNi alloy plated layer and the inorganic chromate-free chemical conversion coating film and reaching an interface between the ZnNi alloy plated layer and the steel sheet, and a water contact angle on a surface of the inorganic chromate-free chemical conversion coating film is more than or equal to 50 degrees.

A steel sheet for a fuel tank includes: a ZnNi alloy plated layer which is placed on one surface or each of both surfaces of a base metal and formed on at least one surface; and an inorganic chromate-free chemical conversion coating film which is placed over the ZnNi alloy plated layer. The ZnNi alloy plated layer has a crack starting from an interface between the ZnNi alloy plated layer and the inorganic chromate-free chemical conversion coating film and reaching an interface between the ZnNi alloy plated layer and the steel sheet, and a water contact angle on a surface of the inorganic chromate-free chemical conversion coating film is more than or equal to 50 degrees.

An additive comprising one or more C.sub.3-C.sub.12 hydroxycarboxylic acids and/or one or more C.sub.3-C.sub.12 hydroxycarboxylic acid salts may be added to an aqueous system having galvanized metallurgy or a carbon steel surface in an effective amount to passivate a galvanized coating on the metallurgy or to decrease white rust formation or other types of corrosion upon the galvanized metallurgy or carbon steel surface in an aqueous system. In a non-limiting embodiment, the C.sub.3-C.sub.12 hydroxycarboxylic acid or the C.sub.3-C.sub.12 hydroxycarboxylic acid salt additive may utilize the zinc in the galvanized coating to achieve passivation. The passivation may occur while the system is shut down or in service. The aqueous system may be or include a cooling tower, a cooling water system, and combinations thereof. The additive may be used with or in the absence of a phosphorous-containing compound.

A composite can include a substrate and a conversion coating overlying the substrate and comprising at least one of a zirconium oxide, a hafnium oxide, or a combination thereof. The conversion coating can be formed from a zirconia or hafnia-based complex obtained by reacting at least one of a zirconium ion source, a hafnium ion source, or a combination thereof, with a chelating compound in a reaction and another chelating compound in another reaction.

A composite can include a substrate and a conversion coating overlying the substrate and comprising at least one of a zirconium oxide, a hafnium oxide, or a combination thereof. The conversion coating can be formed from a zirconia or hafnia-based complex obtained by reacting at least one of a zirconium ion source, a hafnium ion source, or a combination thereof, with a chelating compound in a reaction and another chelating compound in another reaction.

This disclosure relates to hydrophobic metal phosphate ceramic comprising a Group IV element of silicon, germanium, tin, or lead having at least one hydrocarbon covalently bonded thereto. Methods of providing water proofing and/or anti-corrosion protection are provided.

This disclosure relates to hydrophobic metal phosphate ceramic comprising a Group IV element of silicon, germanium, tin, or lead having at least one hydrocarbon covalently bonded thereto. Methods of providing water proofing and/or anti-corrosion protection are provided.

The purpose of the present invention is to provide a water-based treatment solution which makes it possible to form a chemical-conversion-treated coating film having further improved corrosion resistance. The present invention relates to a water-based treatment solution for a chemical conversion treatment of a steel sheet or a plated steel sheet. The water-based treatment solution contains an organic resin including a fluororesin, a Group-4A metal compound, and at least one binding promoter selected from the group consisting of dimethyl adipate, diethyl adipate, di(iso)propyl adipate, di(iso)butyl adipate, dimethyl phthalate, diethyl phthalate, di(iso)propyl phthalate and di(iso)butyl phthalate.