The present invention relates to a method for the anti-corrosion treatment of components produced from aluminum, in particular casting parts such as vehicle rims, comprising a pretreatment stage and subsequent coating, wherein the pretreatment stage in turn includes a pickle on the basis of sulfuric acid aqueous solutions containing water-soluble compounds of the element Ti and at least one α-hydroxycarboxylic acid which is carried out upstream of an acidic conversion treatment on the basis of an acidic aqueous solution containing water-soluble compounds of the elements Zr and/or Ti.

The present invention relates to a method for forming a black-passivation layer on a zinc-iron alloy of a substrate, a black-passivation composition for depositing a black-passivation layer on such, in which the black-passivation composition includes one or more than one blackening agent selected from the group consisting of formula (I) and formula (II) as described hereinafter, and a respective use of said blackening agents for blackening a zinc-iron alloy.

The present invention relates to a method for substantially nickel-free phosphating of a metallic surface, wherein a metallic surface is treated one after the other with the following compositions: i) with an alkaline, aqueous cleaner composition which comprises at least one water-soluble silicate, and ii) with an acidic, aqueous, substantially nickel-free phosphating composition which comprises zinc ions, manganese ions and phosphate ions. The invention also relates to the above cleaner composition itself and also to a metallic surface phosphate-coated by the above method, and to the use of said surface.

Provided herein is a method for pretreating aluminum materials, particularly aluminum wheels, wherein an aluminum material is successively i) cleaned and subsequently rinsed, ii) optionally subjected to alkaline pickling and subsequently rinsed, iii) optionally contacted with an aqueous composition comprising at least one mineral acid, iv) optionally rinsed and v) contacted with an acidic aqueous composition comprising a) at least one compound selected from the group consisting of titanium, zirconium and hafnium compounds and b) at least one linear terpolymer prepared by controlled radical polymerisation and comprising vinylphosphonic acid monomeric units, hydroxylethyl- and/or hydroxylpropyl-(meth)acrylate monomeric units and (meth)acrylic acid monomeric units, vi) optionally rinsed, vii) optionally contacted with another aqueous composition, viii) optionally rinsed and ix) optionally dried. Further provided herein is a corresponding composition as well as the use of the materials treated according to the method.

Provided herein is a method for pretreating aluminum materials, particularly aluminum wheels, wherein an aluminum material is successively i) cleaned and subsequently rinsed, ii) optionally subjected to alkaline pickling and subsequently rinsed, iii) optionally contacted with an aqueous composition comprising at least one mineral acid, iv) optionally rinsed and v) contacted with an acidic aqueous composition comprising a) at least one compound selected from the group consisting of titanium, zirconium and hafnium compounds and b) at least one linear terpolymer prepared by controlled radical polymerisation and comprising vinylphosphonic acid monomeric units, hydroxylethyl- and/or hydroxylpropyl-(meth)acrylate monomeric units and (meth)acrylic acid monomeric units, vi) optionally rinsed, vii) optionally contacted with another aqueous composition, viii) optionally rinsed and ix) optionally dried. Further provided herein is a corresponding composition as well as the use of the materials treated according to the method.

The present invention relates to a composite material including a porous titania thin film and a preparation method therefor. A composite material according to the present invention allows for a simple thin film formation process because of the use of cellulose crystals, makes it easy to control the structure of the titanium dioxide thin film provided therefor, has a large specific area, and is superior in terms of scratch resistance and photoactivity, thus finding useful applications in the various fields utilizing titanium dioxide as a photocatalyst.

The present invention relates to a method for the corrosion-protective and cleaning pretreatment of metallic components, produced at least partially from metallic materials from the elements iron, zinc and/or aluminum, with the use of an acid aqueous composition containing, in addition to the water-soluble compounds of the elements Zr and/or Ti causing the conversion of the metal surface, a mixture of an aliphatic diol and an aliphatic saturated polyhydroxy compound. It also comprises a chrome(VI)-free aqueous composition based on the constituents mentioned above which delivers outstanding results in cleaning and simultaneous corrosion-protective conversion of technical metal surfaces in one method step.

The present invention relates to a method for the corrosion-protective and cleaning pretreatment of metallic components, produced at least partially from metallic materials from the elements iron, zinc and/or aluminum, with the use of an acid aqueous composition containing, in addition to the water-soluble compounds of the elements Zr and/or Ti causing the conversion of the metal surface, a mixture of an aliphatic diol and an aliphatic saturated polyhydroxy compound. It also comprises a chrome(VI)-free aqueous composition based on the constituents mentioned above which delivers outstanding results in cleaning and simultaneous corrosion-protective conversion of technical metal surfaces in one method step.

Described herein is a method for treatment of at least one surface of a metal containing substrate including at least contacting the surface with an aqueous acidic Ni-free composition (A) including at least zinc cations, manganese cations, and phosphate anions to form a conversion coating on the surface and contacting the formed coating with an aqueous Ni-free composition (B) including one or more linear polymers (P) containing at least vinyl phosphonic acid, (meth)acrylic acid, and hydroxyethyl- and/or hydroxypropyl (meth)acrylate in form of their polymerized monomeric units. Also described herein is the composition (B), a master batch to produce the composition (B), a kit-of-parts including both compositions (A) and (B), a kit-of-parts including respective master batches to produce both compositions (A) and (B), and a coated substrate obtainable by the method described herein.

The present disclosure relates to substrates and methods of producing substrates thereof. The substrates have a metal substrate and a sol-gel coating disposed on the metal substrate. The sol-gel coating includes about 3 wt % to about 15 wt % by volume of an organic corrosion inhibitor to the sol-gel. The sol-gel includes surfactant and a reaction product of an epoxy-containing organosilane, a metal alkoxide, and an acid.