This disclosure relates to a method for obtaining superhydrophobic corrosion-resistant coatings. State-of-the-art approaches involve etching methods with elevated temperatures and/or longer duration which are complex and use high concentration of combination of acids, alkali, and salt solutions in etching process to obtain a roughness which makes it difficult to handle usage of chemicals and controlling process. The method of the present disclosure has addressed this issue by selection of optimum concentrations of combinations of one or more type of acids, oxidizing agents which are safe, easy to handle and provide better control over the process. The method of the present disclosure is easy, inexpensive, and environmentally friendly. The superhydrophobic corrosion-resistant coatings possess contact angles greater than 151° and coating efficiency more than 85 percent arrived at by using corrosion currents from polarization studies.

Provided is a magnesium-containing metal material that includes coatings having excellent corrosion resistance on a surface. Specifically, provided is a magnesium-containing metal material with coating, which is characterized by including: a magnesium hydroxide-containing first coating on a surface of a magnesium-containing metal material composed of magnesium or a magnesium alloy; a hydroxyapatite and/or hydroxyapatite carbonate-containing third coating over the first coating; and a dibasic calcium phosphate-containing second coating between the first coating and the third coating.

Provided is a method for treating a surface of an aluminum article capable of imparting an effective anchoring effect to a surface of the aluminum article and enabling a strong chemical bond between the surface of the aluminum article and an organic material layer such as a coated resin layer or a laminated FRP applied to the surface without using a chemical solution that is not easy to treat. In the method for treating a surface of an aluminum article according to the present invention, the surface of the aluminum article is subjected to at least one of an etching treatment, a boehmite treatment, and a zirconium treatment, and then further subjected to at least one of a silane coupling agent treatment, an isocyanate compound treatment, and a thiol compound treatment.

Provided is a method for treating a surface of an aluminum article capable of imparting an effective anchoring effect to a surface of the aluminum article and enabling a strong chemical bond between the surface of the aluminum article and an organic material layer such as a coated resin layer or a laminated FRP applied to the surface without using a chemical solution that is not easy to treat. In the method for treating a surface of an aluminum article according to the present invention, the surface of the aluminum article is subjected to at least one of an etching treatment, a boehmite treatment, and a zirconium treatment, and then further subjected to at least one of a silane coupling agent treatment, an isocyanate compound treatment, and a thiol compound treatment.

To provide a sanitary facility member having excellent ease of contamination removal and excellent persistence of ease of contamination removal. A sanitary facility member including: a base material, at least the surface of which includes a metal element; a metal oxide layer formed on the surface of the base material; and an organic layer provided on the metal oxide layer; wherein the metal element is at least one element selected from the group consisting of Cr, Zr, and Ti, the metal oxide layer includes at least the metal element and an oxygen element, and the organic layer is bonded to the metal oxide layer by bonding (M-O—P bonding) of the metal element (M) and a phosphorus atom (P) of at least one group (X) selected from a phosphonic acid group, a phosphoric acid group, and a phosphinic acid group via an oxygen atom (O), the group X being bonded to a group R (where R is a hydrocarbon or a group having an atom other than carbon in 1 or 2 locations in a hydrocarbon group).

To provide a sanitary facility member having excellent ease of contamination removal and excellent persistence of ease of contamination removal. A sanitary facility member including: a base material, at least the surface of which includes a metal element; a metal oxide layer formed on the surface of the base material; and an organic layer provided on the metal oxide layer; wherein the metal element is at least one element selected from the group consisting of Cr, Zr, and Ti, the metal oxide layer includes at least the metal element and an oxygen element, and the organic layer is bonded to the metal oxide layer by bonding (M-O—P bonding) of the metal element (M) and a phosphorus atom (P) of at least one group (X) selected from a phosphonic acid group, a phosphoric acid group, and a phosphinic acid group via an oxygen atom (O), the group X being bonded to a group R (where R is a hydrocarbon or a group having an atom other than carbon in 1 or 2 locations in a hydrocarbon group).

A negative electrode for a lithium secondary battery including a lithium metal layer and a protective layer including a three-dimensional structural body made of metal and lithium nitride on the lithium metal layer. The protective layer induces uniform ionic conductivity and electrical conductivity on the surface of the negative electrode. A method for manufacturing method a negative electrode for a lithium secondary battery including the steps of forming a metal hydroxide having a three-dimensional structure, forming a metal nitride having a three-dimensional structure by a nitridation reaction of the metal hydroxide of the three-dimensional structure; and transferring the metal nitride having the three-dimensional structure onto a lithium metal layer to form a protective layer. A lithium secondary battery including the negative electrode for a lithium secondary battery.

A corrosion-resistant workpiece is provided. The corrosion-resistant workpiece includes a matrix including a valve metal or an alloy including a valve metal; an oxide layer formed on the matrix, the oxide layer including a plurality of pores, wherein each pore of the plurality has a pore volume; and a polymeric composition disposed within at least a portion of the plurality of pores, wherein greater than or equal to about 70% of the pore volume for each pore having the polymeric composition disposed therein is filled with the polymeric composition. A method of fabricating the corrosion-resistant workpiece is also provided.

Disclosed is a combined treatment method for improving corrosion resistance of metal component in chlorine-containing solution. First, the metal component is placed in the chlorine-containing solution. Large-area overlapping laser shock peening without an absorbing layer is used, when laser pulses are irradiated on the target metal component, the metal matrix surface absorbs the laser energy, vaporizes and expands to form a high-temperature and high-pressure plasma, a chlorine-containing passivation film is formed, to improve the surface corrosion resistance of the metal component. After that, the surface layer of the metal component is subjected to surface polishing, followed by large-area overlapping laser shock peening with an absorbing layer at room temperature, to further improve the corrosion resistance of the metal component. The combined treatment method of the present invention can be applied to improve the corrosion resistance of metal components in highly corrosive chlorine-containing environments of seawater and the like.

Disclosed is a combined treatment method for improving corrosion resistance of metal component in chlorine-containing solution. First, the metal component is placed in the chlorine-containing solution. Large-area overlapping laser shock peening without an absorbing layer is used, when laser pulses are irradiated on the target metal component, the metal matrix surface absorbs the laser energy, vaporizes and expands to form a high-temperature and high-pressure plasma, a chlorine-containing passivation film is formed, to improve the surface corrosion resistance of the metal component. After that, the surface layer of the metal component is subjected to surface polishing, followed by large-area overlapping laser shock peening with an absorbing layer at room temperature, to further improve the corrosion resistance of the metal component. The combined treatment method of the present invention can be applied to improve the corrosion resistance of metal components in highly corrosive chlorine-containing environments of seawater and the like.