An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate; an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.

A steel sheet with excellent surface quality, and a manufacturing method therefor are provided. The present invention provides a pickled steel sheet with excellent surface quality, comprising, by wt %, carbon (C) in an amount greater than or equal to 0.05% and less than 0.4%, 0.5% or less of silicon (Si) (excluding 0%), 0.05% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.01% or less of boron (B), 0.1-2.5% of manganese (Mn) and/or chromium (Cr), and the balance of iron (Fe) and inevitable impurities, wherein the average thickness of an internal oxide layer and/or a tantalum layer, which are formed on the surface layer of the steel sheet, is 1-10 μm, and the standard deviation of the thickness of the internal oxide layer and/or the tantalum layer in the length direction of the steel sheet is 2 μm or less.

A steel sheet with excellent surface quality, and a manufacturing method therefor are provided. The present invention provides a pickled steel sheet with excellent surface quality, comprising, by wt %, carbon (C) in an amount greater than or equal to 0.05% and less than 0.4%, 0.5% or less of silicon (Si) (excluding 0%), 0.05% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.01% or less of boron (B), 0.1-2.5% of manganese (Mn) and/or chromium (Cr), and the balance of iron (Fe) and inevitable impurities, wherein the average thickness of an internal oxide layer and/or a tantalum layer, which are formed on the surface layer of the steel sheet, is 1-10 μm, and the standard deviation of the thickness of the internal oxide layer and/or the tantalum layer in the length direction of the steel sheet is 2 μm or less.

Provided are a high-carbon steel sheet having good surface quality and a manufacturing method therefor. The present invention provides a high-carbon pickled steel sheet having good surface quality, the steel sheet containing, in weight %, 0.4% or more and less than 1.2% of carbon (C), 0.5% or less (excluding 0%) of silicon (Si), 0.05% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.1 to 2.5% of at least one of manganese (Mn) and chromium (Cr), and the balance of iron (Fe) and inevitable impurities, wherein the average thickness of an internal oxide layer and/or a decarburized layer formed in a surface layer portion of the steel sheet is 1 to 10 μm and the standard deviation of the thickness of the internal oxide layer and/or the decarburized layer in the length direction of the steel sheet is 2 μm or less.

Provided are a high-carbon steel sheet having good surface quality and a manufacturing method therefor. The present invention provides a high-carbon pickled steel sheet having good surface quality, the steel sheet containing, in weight %, 0.4% or more and less than 1.2% of carbon (C), 0.5% or less (excluding 0%) of silicon (Si), 0.05% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.1 to 2.5% of at least one of manganese (Mn) and chromium (Cr), and the balance of iron (Fe) and inevitable impurities, wherein the average thickness of an internal oxide layer and/or a decarburized layer formed in a surface layer portion of the steel sheet is 1 to 10 μm and the standard deviation of the thickness of the internal oxide layer and/or the decarburized layer in the length direction of the steel sheet is 2 μm or less.

Disclosed in the present invention is complex-phase steel having high hole expansibility. The complex-phase steel has a microstructure of ferrite and bainite. The complex-phase steel having high hole expansibility comprises the following chemical elements in percentage by mass: C: 0.06-0.09%, Si: 0.05-0.5%, Al: 0.02-0.1%, Mn: 1.5-1.8%, Cr: 0.3-0.6%, Nb≤0.03%, Ti: 0.05-0.12%, and the balance of Fe and inevitable impurities. In addition, also disclosed in the present invention is a manufacturing method for the foregoing complex-phase steel having high hole expansibility. The method comprises the following steps: (1) smelting and casting; (2) heating; (3) hot-rolling; (4) phosphorous removal; (5) laminar cooling: a relaxation time period is controlled to be 0-8 s, and a laminar cooling rate is 40-70° C./s; (6) coiling; (7) leveling; and (8) pickling. The complex-phase steel having high hole expansibility can simultaneously satisfy the requirements for hole expansibility and good plasticity.

The present invention aims to provide a metal coating method whereby a paint can be applied directly, easily, with high adhesion, and with cost increases suppressed, to the surface of titanium and other metals that have a hard passivated coating on the surface thereof. This method uses paint to coat a metal that has the surface thereof coated in a passivated coating and comprises: an etching step in which the passivated coating is removed using an etching solution and the surface is exposed; a diluent coating step in which, after the etching step, a diluent capable of diluting the paint is coated on the surface that is in a liquid-coated state; and a painting step in which the surface is coated in paint after the diluent coating step.

A surface treatment agent capable of forming a hexavalent chromium-free chemical conversion coating that can provide an excellent corrosion-resistant coating on various metallic materials; a metallic material having a surface treatment coating obtained therefrom; and a method of producing the same. A free fluorine ion-containing surface treatment agent for surface-treating a metallic material, which is obtained by mixing at least one supply source (A) of trivalent chromium-containing ions A; a supply source (B) of ions B that are at least one selected from titanium-containing ions and zirconium-containing ions; a water-soluble or water-dispersible compound (C) containing an alkoxysilyl group, an aromatic ring, a hydroxy group directly bonded to the aromatic ring, and at least one of primary, secondary, tertiary and quaternary amino groups, wherein the alkoxysilyl group is bonded to the nitrogen atom of the amino group directly or via an alkylene group; and a fluorine-containing compound (D) providing fluorine-containing ions.

This austenitic stainless steel contains, in terms of % by mass: C: 0.100% or less, Si: 3.00% or less, Mn: 0.01% or more and 5.00% or less, P: 0.100% or less, S: 0.0050% or less, Ni: 7.00% or more and 38.00% or less, Cr: 17.00% or more and 28.00% or less, Mo: 10.00% or less, and N: more than 0.100% and 0.400% or less, with a remainder being Fe and impurities, and a brightness difference ΔL of a surface of a stainless steel is 5 or less.

A method for producing a cold-rolled flat steel product coated with a metallic anticorrosion layer includes producing a steel melt containing in addition to iron and unavoidable impurities (in % by wt.): C: 0.01-0.35%, Mn: 1-4%, Si: 0.5-2.5%, Nb: to 0.1%, Ti: 0.015-0.1%, P: up to 0.1%, Al: to 0.15%, S: up to 0.01%, N: up to 0.1%, and optionally one or more elements from a group of rare earth metals. The method further includes casting the steel melt to give a preliminary product, hot-rolling the preliminary product to give a hot strip, coiling the hot strip to give a coil, annealing the hot strip, cold-rolling the annealed hot strip to give a cold-rolled flat steel product, finally annealing the cold-rolled flat steel product, and applying a metal anticorrosion layer based on zinc by electrolytic galvanization or hot dip galvanization of the cold-rolled and finally annealed flat steel product.