The invention relates to a method for pickling steel sheets 8, the steel sheets being continuously dipped in a pickling bath 1, containing a pickling solution 10, the bath being connected to a treatment unit including a recirculation tank 3, circulators 12 and 13, a continuous entering flow 11 of the solution being fed into an ultrafiltration device 2 from the recirculation tank 3 and two flows exiting the ultrafiltration device, one filtered exiting flow 21 being then fed back inside the recirculation tank 3 and one unfiltered flow 22, the treatment unit including no storage tank.

A flexible substrate treatment device comprising at least one tank that accommodates treatment liquid, winding rollers including a main roller and a driven roller located above the treatment liquid, a positioning roller located in the treating liquid in each tank, a detecting unit configured to detect radius or diameter of at least one of the winding rollers, and a movable discharge member fixed to a side wall of each tank, including a movable discharge port configured to discharge the treatment liquid and a discharge port position controlling mechanism, wherein the movable discharge port can be moved in a direction X perpendicular to a bottom wall of the tank.

A device and a method for depositing undissolved materials, in particular undissolved silicon compounds, from a pickling fluid in a pickling plant. A pickling circuit of the pickling plant has a pickling tank for pickling metal strips, a return line between the pickling tank and a circuit tank, a circulation pump for circulating a main volume flow of pickling fluid from the pickling tank, and a heating device arranged in a pressure line between the circuit tank and the pickling tank. The device includes a flocculation device for introducing at least one flocculant into the main volume flow, and a deposition device in the circuit tank and preferably designed as an inclined clarifying device, for the sedimentation of undissolved materials directly from the main volume flow. When pickling silicon-containing steel strips (electrical steel strips), an at least two-stage flocculation can be carried out using two or more mixing zone containers.

This grain-oriented electrical steel sheet includes: a base steel sheet; and an insulating coating formed on a surface of the base steel sheet, in which the insulating coating includes an intermediate layer formed on a base steel sheet side and containing a crystalline metal phosphate, and a tension coating layer formed on a surface side of the insulating coating, the surface of the base steel sheet has an etch pit structure, an average thickness of the intermediate layer is 0.2 to 10.0 ?m, an average thickness of the insulating coating is 2.0 to 10.0 ?m, the tension coating layer contains a metal phosphate and silica, and an amount of the silica in the tension coating layer is 20 to 60 mass %.

Methods, systems and apparatuses for treating operating aluminum desmutting solutions by reacting, mixing and filtering a partial desmutting solution flow are disclosed.

To prevent over-pickling of a steel strip during pickling pause, and shorten the time required to switch between pickling operation and pickling pause, a pickling device includes: a pickling tank for storing acid solution and for pickling a steel strip by allowing the steel strip to travel therethrough while the steel strip is immersed in the acid solution; a heat exchanger for heating the acid solution in the pickling tank; a circulation tank for storing the acid solution, provided separately from the pickling tank; an acid-solution circulation unit configured to circulate the acid solution between the pickling tank and the acid-solution storage tank; and a control device configured to control the acid-solution circulation device to maintain a liquid level of the acid solution in the pickling tank at a level below a traveling height of the steel strip.

A method of producing a cold rolled steel strip includes: subjecting a steel strip that has been cold rolled and subsequently continuously annealed to pickling by continuously feeding the steel strip into a mixed acid solution containing a first acid that is oxidizing and a second acid that is non-oxidizing to immerse the steel strip; and subsequently subjecting the steel strip to repickling by continuously feeding the steel strip into an acid solution containing a third acid that is non-oxidizing to immerse the steel strip. The concentration of the first acid in the mixed acid solution is lowered and the concentration of the second acid in the mixed acid solution is raised as the iron ion concentration in the mixed acid solution rises.

A method for pickling a steel plate having a first steel plate portion and a second steel plate portion which is connected to a tail end of the first steel plate portion and which requires a longer time for pickling than the first steel plate portion when pickled under the same condition includes: a step of pickling the steel plate by immersing the steel plate in an acid solution in at least one pickling tank while conveying the steel plate; a step of circulating the acid solution, through a circulation line connected to any of the at least one pickling tank, between the pickling tank and an oxidizing device disposed in the circulation line; a step of oxidizing Fe.sup.2+ in the acid solution to Fe.sup.3+ by the oxidizing device using a gaseous oxidant; and a feeding start step of, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, starting feeding of a liquid oxidant for oxidizing Fe.sup.2+ in the acid solution to Fe.sup.3+ to any of the at least one pickling tank or to the circulation line.

To prevent over-pickling during pickling pause, shorten the time required to switch between pickling operation and pickling pause, and heat acid solution efficiently, a pickling device includes: a pickling tank for storing acid solution and for pickling a steel strip by allowing the steel strip to travel therethrough while the steel strip is immersed in the acid solution; a heat exchanger for heating the acid solution in the pickling tank; a circulation tank for storing the acid solution, provided separately from the pickling tank; an acid-solution circulation device configured to circulate the acid solution between the pickling tank and the circulation tank; a control device configured to withdraw the steel strip from the acid solution; and a guide plate disposed in the pickling tank and configured to guide the acid solution circulated in the pickling tank by the acid-solution circulation device to the heat exchanger.

Continuous annealing equipment (1) including a cleaning device (11, 12) for performing a cleaning treatment on a steel strip (S) and an annealing device (12) for performing an annealing treatment on the steel strip (S) comprises an exhaust gas passage (31, 41) through which an exhaust gas discharged from the annealing device (12) flows, a solution circulation passage (32, 51) through which a cleaning solution used in the cleaning device (11, 12) circulates, and a heat exchanger (53) which forms a part of the solution circulation passage (32, 51) and contacts with the exhaust gas.