Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N.sub.2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.

Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N.sub.2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.

A process is provided for producing ammonia comprising feeding N2 to an electrolytic cell that comprises a cathode with a transition metal sulfide catalytic surface. Also provided a system for generating ammonia with the process, comprising a transition metal sulfide catalyst.

A process is provided for producing ammonia comprising feeding N2 to an electrolytic cell that comprises a cathode with a transition metal sulfide catalytic surface. Also provided a system for generating ammonia with the process, comprising a transition metal sulfide catalyst.

A method of generating oxygen and at least one of hydrogen or ammonia includes receiving ambient air containing moisture, collecting liquid water from the ambient air, receiving, by a water electrolyzer, the collected liquid water and electricity from an electrical source, and performing an electrolysis process by the water electrolyzer to thereby generate the oxygen and the at least one of hydrogen or ammonia from the received liquid water and electricity.

A method of generating oxygen and at least one of hydrogen or ammonia includes receiving ambient air containing moisture, collecting liquid water from the ambient air, receiving, by a water electrolyzer, the collected liquid water and electricity from an electrical source, and performing an electrolysis process by the water electrolyzer to thereby generate the oxygen and the at least one of hydrogen or ammonia from the received liquid water and electricity.

An alternating current (AC) impedance spectroscopy method includes providing an AC impedance spectroscopy ripple from power electronics into an electrochemical device, and absorbing the ripple in the power electronics.

An ammonia manufacturing apparatus includes: an electrochemical reaction unit including a first electrolytic bath for accommodating a first electrolytic solution, an oxidation electrode disposed in the first electrolytic bath, a second electrolytic bath for accommodating a second electrolytic solution containing nitrogen, an ammonia producing catalyst, and a reducing agent, a reduction electrode disposed in the second electrolytic bath, and a diaphragm, and configured to reduce nitrogen by the ammonia producing catalyst and the reducing agent in the second electrolytic bath to produce ammonia, and reduce the reducing agent oxidized due to the production of ammonia, at the reduction electrode by connecting the oxidation electrode and the reduction electrode to a power supply; a nitrogen supply unit including a nitrogen supply part for dissolving nitrogen in the second electrolytic solution; and an ammonia separation unit including a separation part configured to separate ammonia from the second electrolytic solution.

An ammonia manufacturing apparatus includes: an electrochemical reaction unit including a first electrolytic bath for accommodating a first electrolytic solution, an oxidation electrode disposed in the first electrolytic bath, a second electrolytic bath for accommodating a second electrolytic solution containing nitrogen, an ammonia producing catalyst, and a reducing agent, a reduction electrode disposed in the second electrolytic bath, and a diaphragm, and configured to reduce nitrogen by the ammonia producing catalyst and the reducing agent in the second electrolytic bath to produce ammonia, and reduce the reducing agent oxidized due to the production of ammonia, at the reduction electrode by connecting the oxidation electrode and the reduction electrode to a power supply; a nitrogen supply unit including a nitrogen supply part for dissolving nitrogen in the second electrolytic solution; and an ammonia separation unit including a separation part configured to separate ammonia from the second electrolytic solution.

A process for preparing ammonia via an electrolysis cell may involve feeding nitrogen as a first reactant into the electrolysis cell and using water or water vapor as a second reactant for electrolysis. In at least one step downstream of the electrolysis, there is a separation of other components from the ammonia, such as an at-least-partial separation of nitrogen, water, argon and/or hydrogen. Recovery of the reactants is connected upstream of the ammonia electrolysis. The nitrogen used as the first reactant may be procured beforehand in an air fractionation plant. The process may further involve removing from the electrolysis cell oxygen formed as a by-product in the electrolysis at an anode.