Patent classifications
C25B3/13
CHIRAL MAGNETIC NANOCOIL AND SYNTHESIS METHODS THEREOF
Disclosed herein is a technique for synthesizing chiral magnetic nanocoils using an electrodeposition technique, which can be used to fabricate magnetic nanosensors capable of generating an electric field by strongly reacting to an external magnetic field, such as Faraday's law of electromagnetic induction at the nanoscale, depending on the coil shape of the nanostructure. In accordance with one embodiment, a method of synthesizing a chiral magnetic nanocoil may include generating a primary particle composed of metal ions by applying an external electric field, binding a chiral molecule to a surface of the generated primary particle, and controlling an assembly direction of a next primary particle by the bound chiral molecule.
COMPOSITE NANOPARTICLES AND METHODS OF PREPARATION THEREOF
The present invention is directed to composite nanoparticles comprising a metal, a rare earth element, and, optionally, a complexing ligand. The invention is also directed to composite nanoparticles having a core-shell structure and to processes for preparation of composite nanoparticles of the invention.
Ultra-low shrinkage polyester industrial yarn and its preparation method
The present invention discloses an ultra-low shrinkage polyester industrial yarn and its preparation method. The ultra-low shrinkage polyester industrial yarn is prepared by subjecting a polyester to dissolution, washing and solid state polycondensation followed by spinning. The ultra-low shrinkage polyester industrial yarn has a dry heat shrinkage rate of 1.80.25% under test conditions of 177 C.10 min0.05 cN/dtex. The polycondensation catalyst consists of magnesium ethylene glycol and antimony ethylene glycol, has a small thermal degradation coefficient. The present invention reduces oligomers during polymerization, reduces thermal degradation during processing, and as a result the invention greatly reduces impurities and nucleating agent in the polyester, leading to an increase in the probability of homogeneous nucleation based on the reduction of heterogeneous nucleation. The dissolution and washing of polyester further decreases oligomer content, facilitating the growth of the grain size and the optimization of crystal perfection in the ultra-low shrinkage polyester industrial yarn.
A low chromatic aberration polyester different-shrinkage composite yarn and its preparation method
A low chromatic aberration polyester different-shrinkage composite yarn is made of polyester POY yarn and polyester FDY composite yarn. The polyester POY yarn and polyester FDY yarn is obtained by spinning the polyester solution, the rupture strength of the low color polyester different-shrinkage composite yarn is 1.9 cN/dtex, the elongation at break is 30.05.0%, the crimp shrinkage is 2.503.0%, the network degree is 205/m, the color difference E is less than 0.200. In the invention, the magnesium ethylene glycol is relatively mild, the thermal degradation coefficient is small, the oligomers in the polymerization process is reduced, and the oligomers in the dissolution process are further reduced, so that the appearance of stains and streaks reduces during the dyeing and post-processing heat setting of the polyester fiber, which ensures the fiber's leveling and rubbing fastness.
An ultra-low shrinkage polyester industrial yarn and its preparation method
The present invention discloses an ultra-low shrinkage polyester industrial yarn and its preparation method. The ultra-low shrinkage polyester industrial yarn is prepared by subjecting a polyester to dissolution, washing and solid state polycondensation followed by spinning. The ultra-low shrinkage polyester industrial yarn has a dry heat shrinkage rate of 1.80.25% under test conditions of 177 C.10 min0.05 cN/dtex. The polycondensation catalyst consists of magnesium ethylene glycol and antimony ethylene glycol, has a small thermal degradation coefficient. The present invention reduces oligomers during polymerization, reduces thermal degradation during processing, and as a result the invention greatly reduces impurities and nucleating agent in the polyester, leading to an increase in the probability of homogeneous nucleation based on the reduction of heterogeneous nucleation. The dissolution and washing of polyester further decreases oligomer content, facilitating the growth of the grain size and the optimization of crystal perfection in the ultra-low shrinkage polyester industrial yarn.
An industrial polyester and its preparation method
A polyester obtained by the esterification of terephthalic acid and ethylene glycol and the polycondensation catalysed by a mixture of magnesium ethylene glycol and antimony ethylene glycol followed by granulation. In the polyester sections, the carboxyl end group is less than 15 mol/t, the mass percentage of oligomer is lower than 0.5%, and weight percentage of diethylene glycol is lower than 0.5%.
A flame-retardant polyester fiber and its preparation method
A flame-retardant polyester fiber obtained by spinning flame-retardant polyester and irradiating with ultraviolet light and having a limiting oxygen index value of greater than 30. Flame retardant 2-carboxyethylphenylphosphinic acid to improve the flame retardant properties of polyester, the use of polyester containing unsaturated double bond in UV irradiation, the double bond opens to form a crosslinking point, the formation of a certain amount of the network structure improves the heat-resistant temperature of the poly-fiber and improves the anti-dripping performance of the polyester fiber.
BREAK-RESISTANT PARTITION WALL COMPRISING SOLID ELECTROLYTE CERAMICS FOR ELECTROLYTIC CELLS
The present invention relates, in a first aspect, to a dividing wall W suitable for use in an electrolysis cell E. The dividing wall W comprises a frame element R that forms an edge element R.sub.R and a separating element R.sub.T. The frame element R comprises two opposite parts R.sub.1 and R.sub.2, with at least two alkali metal cation-conducting solid-state electrolyte ceramics F.sub.A and F.sub.B disposed therebetween. The separating element R.sub.T lies between alkali metal cation-conducting solid-state electrolyte ceramics encompassed by the dividing wall W and separates these from one another. It is a feature of the invention that the two parts R.sub.1 and R.sub.2 are secured to one another by at least one securing element B.sub.R at the edge element R.sub.R and at least one securing element B.sub.T at the separating element R.sub.T.
Compared to the cases according to the prior art in which the dividing wall W encompasses the solid-state electrolyte in one piece, this arrangement is firstly more flexible since the individual ceramics have more degrees of freedom available in order to react to fluctuations in temperature, for example by shrinkage or expansion. This increases stability with respect to mechanical stresses in the ceramic. At the same time, the mechanical stability of the arrangement of the at least two solid-state electrolyte ceramics between the parts R.sub.1 and R.sub.2 is increased in that the parts R.sub.1 and R.sub.2 are secured to one another both at the edge element R.sub.R and at the separating element R.sub.T by at least one securing element B.sub.R or B.sub.T.
In a second aspect, the present invention relates to an electrolysis cell E encompassing a cathode chamber K.sub.K divided by the dividing wall W from the adjacent chamber, which is the anode chamber K.sub.A or a middle chamber K.sub.M of the electrolysis cell E.
In a third aspect, the present invention relates to a process for producing an alkali metal alkoxide solution in the electrolysis cell E according to the second aspect of the invention.
BREAK-RESISTANT PARTITION WALL COMPRISING SOLID ELECTROLYTE CERAMICS FOR ELECTROLYTIC CELLS
The present invention relates, in a first aspect, to a dividing wall W suitable for use in an electrolysis cell E. The dividing wall W comprises a frame element R that forms an edge element R.sub.R and a separating element R.sub.T. The frame element R comprises two opposite parts R.sub.1 and R.sub.2, with at least two alkali metal cation-conducting solid-state electrolyte ceramics F.sub.A and F.sub.B disposed therebetween. The separating element R.sub.T lies between alkali metal cation-conducting solid-state electrolyte ceramics encompassed by the dividing wall W and separates these from one another. It is a feature of the invention that the two parts R.sub.1 and R.sub.2 are secured to one another by at least one securing element B.sub.R at the edge element R.sub.R and at least one securing element B.sub.T at the separating element R.sub.T.
Compared to the cases according to the prior art in which the dividing wall W encompasses the solid-state electrolyte in one piece, this arrangement is firstly more flexible since the individual ceramics have more degrees of freedom available in order to react to fluctuations in temperature, for example by shrinkage or expansion. This increases stability with respect to mechanical stresses in the ceramic. At the same time, the mechanical stability of the arrangement of the at least two solid-state electrolyte ceramics between the parts R.sub.1 and R.sub.2 is increased in that the parts R.sub.1 and R.sub.2 are secured to one another both at the edge element R.sub.R and at the separating element R.sub.T by at least one securing element B.sub.R or B.sub.T.
In a second aspect, the present invention relates to an electrolysis cell E encompassing a cathode chamber K.sub.K divided by the dividing wall W from the adjacent chamber, which is the anode chamber K.sub.A or a middle chamber K.sub.M of the electrolysis cell E.
In a third aspect, the present invention relates to a process for producing an alkali metal alkoxide solution in the electrolysis cell E according to the second aspect of the invention.
Composite nanoparticles containing rare earth metal and methods of preparation thereof
The present invention is directed to composite nanoparticles comprising a metal, a rare earth element, and, optionally, a complexing ligand. The invention is also directed to composite nanoparticles having a core-shell structure and to processes for preparation of composite nanoparticles of the invention.