An electrolytic reaction system for generating gaseous hydrogen and oxygen includes a reaction chamber for accommodating an electrolyte as well as an electrode arrangement, which is formed of anodic and cathodic electrodes. Between lateral surfaces of electrodes arranged to be spaced apart from one another, at least one flow channel for the electrolyte is formed, which extends between a first axial end for admitting the electrolyte into the electrode arrangement and a second axial end for discharging the electrolyte out of the electrode arrangement. The at least one flow channel has at least one first flow cross-section and at least one second flow cross-section, wherein the second flow cross-section has a smaller size than the first flow channel, and the comparatively smaller second flow cross-section is formed in a partial section of the at least one flow channel closest to the second axial end of the electrode arrangement.

An electrolytic reaction system for generating gaseous hydrogen and oxygen includes a reaction chamber for accommodating an electrolyte as well as an electrode arrangement, which is formed of anodic and cathodic electrodes. Between lateral surfaces of electrodes arranged to be spaced apart from one another, at least one flow channel for the electrolyte is formed, which extends between a first axial end for admitting the electrolyte into the electrode arrangement and a second axial end for discharging the electrolyte out of the electrode arrangement. The at least one flow channel has at least one first flow cross-section and at least one second flow cross-section, wherein the second flow cross-section has a smaller size than the first flow channel, and the comparatively smaller second flow cross-section is formed in a partial section of the at least one flow channel closest to the second axial end of the electrode arrangement.

An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a cathode, and a cathode current distributor. The anode, the ion-exchange membrane, the cathode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.

An electrolyzer cell comprises a first half cell comprising a housing at least partially enclosing a cell interior, a first electrode coated with a first catalyst coating, wherein the first electrode is coupled to the housing in the cell interior without welding, a second electrode coupled to the housing in the cell interior without welding, and a separator positioned between the first electrode and the second electrode, wherein a voltage is applied between the first electrode and the second electrode.

An electrolyzer cell comprises a first half cell comprising a housing at least partially enclosing a cell interior, a first electrode coated with a first catalyst coating, wherein the first electrode is coupled to the housing in the cell interior without welding, a second electrode coupled to the housing in the cell interior without welding, and a separator positioned between the first electrode and the second electrode, wherein a voltage is applied between the first electrode and the second electrode.

An alkaline electrolyser device for hydrogen production includes a first and a second electric charge battery substantially identical. Each electric charge battery has a first electrode of copper, silver or their alloys, coated with zinc, a second electrode with a ferrous catalyst, and an alkaline aqueous solution in which the first and second electrodes are immersed. An output opening placed in correspondence of the second electrode is suitable to allow the escape from the battery of gases which develop in correspondence of the second electrode. The batteries are short-circuited with an electric power supply member placed between the first or the second electrodes, with a predefined polarity such that the voltage across the electrodes is higher than 1.3 V. In this configuration, the first battery undergoes a discharging process producing hydrogen gas, whilst, contextually, the second battery undergoes a charging process generating oxygen gas. When the discharge cycle of the first battery is completed, the polarity of the electric power supply is inverted, so that the second battery begins to discharge producing hydrogen gas and, at the same time, the first battery recharges producing oxygen gas. The polarity inversion is repeated cyclically so that oxygen and hydrogen are produced alternately in the two batteries.

An alkaline electrolyser device for hydrogen production includes a first and a second electric charge battery substantially identical. Each electric charge battery has a first electrode of copper, silver or their alloys, coated with zinc, a second electrode with a ferrous catalyst, and an alkaline aqueous solution in which the first and second electrodes are immersed. An output opening placed in correspondence of the second electrode is suitable to allow the escape from the battery of gases which develop in correspondence of the second electrode. The batteries are short-circuited with an electric power supply member placed between the first or the second electrodes, with a predefined polarity such that the voltage across the electrodes is higher than 1.3 V. In this configuration, the first battery undergoes a discharging process producing hydrogen gas, whilst, contextually, the second battery undergoes a charging process generating oxygen gas. When the discharge cycle of the first battery is completed, the polarity of the electric power supply is inverted, so that the second battery begins to discharge producing hydrogen gas and, at the same time, the first battery recharges producing oxygen gas. The polarity inversion is repeated cyclically so that oxygen and hydrogen are produced alternately in the two batteries.

[Problem] To provide a stacked structure including electrodes that can effectively prevent misalignment between units. [Solution] A stacked structure 2 including electrodes 232, 332, 412, 233, 333, 422, wherein multiple units 23, 33, 24, 41, 42 including flat units are stacked and fastened by fasteners 25, the respective units 23, 33, 24, 41, 42 comprising frame-shaped fastening portions 237a, 237b, 337a, 337b, 247a, 247b, 417a, 417b, 427a, 427b on outer peripheral portions on both surfaces thereof, being stacked by the surfaces of the respective fastening portions 237a, 237b, 337a, 337b, 247a, 247b, 417a, 417b, 427a, 427b being pressed against each other, and being formed so that the width of fastening portions 247a, 247b, 337a, 337b, 427a, 427b on one unit is different from the width of fastening portions 237a, 237b, 417a, 417b on another unit.

An electrochemical apparatus includes a separator having a first reaction region and a second reaction region; a first reaction layer disposed to correspond to the first reaction region; a second reaction layer disposed to correspond to the second reaction region; a first partition wall portion protruding from one surface of the separator, disposed along a boundary between the first reaction layer and the second reaction layer, and including a first connecting flow path configured to connect the first reaction region and the second reaction region so that the first reaction region and the second reaction region fluidically communicate with each other through the first connecting flow path; and a first sealing member disposed at an end portion of the first partition wall portion and configured to seal a portion between the first reaction layer and the second reaction layer, enlarging a reaction region without increasing a size of a reaction layer.

The present invention relates to the application of high electrical conductivity electrodes in whatever type of the electrolysis of water to produce hydrogen to substantially reduce power consumption. The high electrical conductivity electrodes are selected from copper electrodes or graphene electrodes and are coated with a catalyst. Type of electrolysis may be conventional diaphragm or membrane type, diaphragm-less or Unipolar electrolysis of water to produce hydrogen.