Solid oxide electrolytic cell assembly (SOEC) and methods for making SOECs are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC). The functionalized ZTC is formed by forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites. In the method, the functionalized ZTC is incorporated into electrodes by forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte, and calcining the mixture. The method includes forming an electrode assembly, forming the SO electrolytic cell assembly, and coupling the SO electrolytic cell assembly to a heat source.

A compression apparatus includes at least one compression unit, a voltage applier, an anode end plate provided on an anode separator located at a first end in a direction of stacking, a cathode end plate provided on a cathode separator located at a second end in the direction of stacking, and first and second plates provided between the cathode end plate and the cathode separator located at the second end. The compression apparatus causes, by using the voltage applier to apply a voltage, protons taken out from an anode fluid that is supplied to the anode to move to the cathode via the electrolyte membrane and produces compressed hydrogen. The first plate has formed therein a first space in which to store a cathode gas containing the compressed hydrogen. The second plate is provided with a first manifold through which the cathode gas flows and a first communicating path through which to lead, to the first space, the cathode gas having flowed in from the first manifold.

A compression apparatus includes at least one compression unit, a voltage applier, an anode end plate provided on an anode separator located at a first end in a direction of stacking, a cathode end plate provided on a cathode separator located at a second end in the direction of stacking, and first and second plates provided between the cathode end plate and the cathode separator located at the second end. The compression apparatus causes, by using the voltage applier to apply a voltage, protons taken out from an anode fluid that is supplied to the anode to move to the cathode via the electrolyte membrane and produces compressed hydrogen. The first plate has formed therein a first space in which to store a cathode gas containing the compressed hydrogen. The second plate is provided with a first manifold through which the cathode gas flows and a first communicating path through which to lead, to the first space, the cathode gas having flowed in from the first manifold.

A compressor for a solid oxide electrolyzer cell (SOEC) system, the system including one or more stamps that receives hydrogen input and outputs wet hydrogen, a heat exchanger or condenser that is configured to decrease the temperature of the wet hydrogen, a compressor that is configured to increase the pressure of the wet hydrogen, and a dryer that is configured to reduce the dew point of the wet hydrogen.

A compressor for a solid oxide electrolyzer cell (SOEC) system, the system including one or more stamps that receives hydrogen input and outputs wet hydrogen, a heat exchanger or condenser that is configured to decrease the temperature of the wet hydrogen, a compressor that is configured to increase the pressure of the wet hydrogen, and a dryer that is configured to reduce the dew point of the wet hydrogen.

An electrolyzer system includes a stack of solid oxide electrolyzer cells configured receive steam and output a hydrogen exhaust and an oxygen exhaust, a supplemental steam generator configured to generate the steam provided to the stack by vaporizing water using heat extracted from the oxygen exhaust, a water preheater configured to preheat water using heat extracted from the oxygen exhaust, and a primary steam generator configured to generate the steam provided to the stack by vaporizing the water preheated by the water preheater.

An electrolyzer system including a hotbox, one or more stacks disposed within the hotbox, a fuel exhaust conduit that receives fuel exhaust output by the stack, a fuel exhaust separator that separates liquid from the fuel exhaust, and a recycling conduit that fluidly connects the fuel exhaust to the fuel inlet conduit.

An electrolyzer system including a hotbox, one or more stacks disposed within the hotbox, a fuel exhaust conduit that receives fuel exhaust output by the stack, a fuel exhaust separator that separates liquid from the fuel exhaust, and a recycling conduit that fluidly connects the fuel exhaust to the fuel inlet conduit.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.

A device and a method for producing hydrogen and byproduct oxygen by using green electricity electrolyzed water are provided. The device comprises an oxygen purifying system, a heat exchange system, an air separation compression and expansion system, an air separation rectification system and a liquid oxygen storage system. The method comprises the following steps: first, purifying oxygen prepared by electrolyzing water by green electricity to remove impurities such as hydrogen, carbon monoxide, carbon dioxide and water in the oxygen, then feeding the pure oxygen into the heat exchange system, performing heat exchange liquefaction to obtain liquid oxygen, coupling the liquid oxygen generated by rectification of the air separation rectification system, and obtaining pressurized oxygen through the heat exchange system and the air separation compression and expansion system.