The present invention relates to a photo-electrochemical device for production of a gas, liquid or solid using concentrated electromagnetic irradiation. The device comprises a photovoltaic component configured to generate charge carriers from the concentrated electromagnetic irradiation; and an electrochemical component configured to carry out electrolysis of a reactant. The photovoltaic component contacts the electrochemical component at a solid interface to form an integrated photo-electrochemical device; and further includes at least one reactant channel or a plurality of reactant channels extending between the photovoltaic component and the electrochemical component to transfer heat and the reactant from the photovoltaic component to the electrochemical component. The integrated photo-electrochemical device and auxiliary devices (such as concentrator, flow controllers) build a system which can flexibly react to changes in operating condition and guarantee best performance.

An electrode of a chemical cell includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, each conductive projection of the array of conductive projections having a semiconductor composition for catalytic conversion of carbon dioxide (CO.sub.2) in the chemical cell, and a plurality of nanoparticles disposed over the array of nanowires, each nanoparticle of the plurality of nanoparticles having a metallic composition for the catalytic conversion of CO.sub.2 in the chemical cell. Each nanoparticle of the plurality of nanoparticles has a size at least an order of magnitude smaller than a lateral dimension of each conductive projection of the array of conductive projections.

An electrode of a chemical cell includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, each conductive projection of the array of conductive projections having a semiconductor composition for catalytic conversion of carbon dioxide (CO.sub.2) in the chemical cell, and a plurality of nanoparticles disposed over the array of nanowires, each nanoparticle of the plurality of nanoparticles having a metallic composition for the catalytic conversion of CO.sub.2 in the chemical cell. Each nanoparticle of the plurality of nanoparticles has a size at least an order of magnitude smaller than a lateral dimension of each conductive projection of the array of conductive projections.

Summary

The present application relates to a catalyst for hydrogen evolution reaction (HER) including a transition metal matrix and noble metal atoms formed in the transition metal matrix, in which the noble metal atoms have oxygen adsorbed thereto, and oxygen is derived from the transition metal matrix.

A synthesis gas production system for producing CO and H.sub.2 by electrolyzing an aqueous solution containing CO.sub.2 includes: an electrolysis device including an anode chamber and a cathode chamber separated by a separator membrane; a cathode-side circulation line connected to the cathode chamber to circulate a cathode solution containing CO.sub.2; a catalyst supply device provided in the cathode-side circulation line to supply a CO production catalyst to the cathode solution; and a gas composition detection device configured to measure a ratio between CO and H.sub.2 in a production gas produced in the cathode chamber. At least one of control of a supply amount of the CO production catalyst by the catalyst supply device and control of a voltage applied between the anode and the cathode by the electrolysis device is performed to make a ratio of H.sub.2 to CO in the production gas be within a predetermined target range.

An electrolyser (F) for generating hydrogen from water, the electrolyser comprising an electrode (102), the electrode (120) comprising nanoparticles selected from Group 1 nanoparticles or alloys or composites or mixtures thereof.

An electrolyser (F) for generating hydrogen from water, the electrolyser comprising an electrode (102), the electrode (120) comprising nanoparticles selected from Group 1 nanoparticles or alloys or composites or mixtures thereof.

Processes and systems for electrochemical exfoliation that use a compression reactor and, more particularly, to processes and systems for electrochemical exfoliation of planar parent materials, such as graphite. A reactor for electrochemical exfoliation may include a container configured to hold an electrolyte solution. The reactor may further include a porous chamber, wherein the porous chamber is configured to hold a parent material in fluid communication with the electrolyte solution. The reactor may further include a pressure source positioned to apply a pressure along a length of the porous chamber to thereby compress the parent material in the porous chamber. The reactor may further include a first counter electrode. The reactor may further include a working electrode. The reactor may further include an electrical power source in electrical communication with the first counter electrode and the working electrode.

Formaldehyde is obtained from CO.sub.2 through hydrogenation of CO.sub.2 to methanol while the subsequent oxidation of methanol yields formaldehyde. This formaldehyde combined with the electrochemically produced glycolaldehyde generates sugars, thus establishing a route from CO.sub.2 to sugars.

An electrochemical cell cathode catalyst layer includes electrocatalyst particles, an electrocatalyst support having an electronically conductive porous material including a plurality of pores with a diameter of less than or equal to 10 nm having a surface morphology comprising a plurality of peaks and valleys, the surface morphology being configured to contain the electrocatalyst particles within the plurality of pores and to enhance mass transport of molecular oxygen to the electrocatalyst particles by adsorbing molecular oxygen to the surface morphology, and an ionomer adhered to the electrocatalyst, the electrocatalyst support, or both.