This application provides a metal foil. The metal foil may include a first metal layer and a metal base layer that are stacked up. A roughness Rz of a surface that is of the metal base layer and that is oriented toward the first metal layer is α.sub.1 μm, a roughness Rz of a surface that is of the first metal layer and that is oriented back from the metal base layer is β.sub.1 μm, α.sub.1 may be in a range of 1.8 to 2.9, and β.sub.1 may be in a range of 1 to 1.4.

This application provides a copper plating solution for a composite current collector, including a leveling agent represented by a general formula (1)

##STR00001## where an anion X is F.sup.−, Cl.sup.−, or Br.sup.−; R.sub.1, R.sub.2, and R.sub.3 are each independently selected from O or S; and R.sub.4, R.sub.5, and R.sub.6 are each independently selected from hydrogen, a substituted or unsubstituted alkyl, a substituted or unsubstituted vinyl, a substituted or unsubstituted aryl, and a substituted or unsubstituted heteroaryl.

Provided in the present invention are a flexible electrochemical electrode, a subcutaneous continuous glucose monitoring sensor equipped with the electrochemical electrode, and a preparation method thereof. The electrode directly uses gold layers on both sides of a chemically plated film, respectively as a working electrode and a reference-counter electrode, so as to form an electrochemical two-electrode system. Petaloid platinum nanoparticles are electrodeposited on a surface of the configured working electrode as a catalytic layer; a carbon nanotube/Nafion mesh layer functions as an anti-interference layer, and is formed thereon with an enzyme biochemical sensitive layer by means of electrostatic adsorption, after crosslinking and curing in glutaraldehyde, polyurethane mass transfer is coated to limit a protection layer, so as to prepare a flexible continuous glucose monitoring sensor. The sensor does not require photolithography, screen printing or other technologies to construct an electrochemical electrode system. The present invention effectively simplifies the processing technology, can easily achieve large-scale production and reduce production costs; and meanwhile, the present invention has characteristics such as a wide linear range, low detection limit, powerful anti-interference capacity, high response sensitivity and long-term stability.

A hydrogen permeable membrane comprises a dense layer of a hydrogen permeable metal having first and second faces. The first face of the dense layer has a rough surface which may be formed for example by electrodeposition of a hydrogen permeable metal such as palladium. One or more co-catalysts are provided on the rough surface. The co-catalysts may comprise thin sputtered layers. The one or more co-catalysts have an area density not exceeding 20 .Math.g per cm.sup.2; and/or a majority of the co catalysts are in an outer portion of the rough surface, the outer portion of the rough surface being less than one half of a thickness of the rough surface defined by peaks of the rough surface. The membrane may be used in a cell to facilitate chemical reactions including hydrogenation, dehydrogenation and hydrodeoxygenation reactions.

The present invention relates to a method for the manufacture of a galvannealed steel sheet including the steps of A.) coating of the steel sheet with a first coating consisting of nickel and having a thickness between 150 nm and 650 nm, the steel sheet having the following composition in weight percentage 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<3.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0%, and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.010%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition is made up of iron and inevitable impurities resulting from the elaboration, B.) annealing of the coated steel sheet being annealed at a temperature between 600 to 1200° C., C.) coating of the steel sheet obtained in step B.) with a second coating based on zinc and D.) an alloying heat treatment to form a galvannealed steel sheet.

Method for the manufacture of a coated steel sheet including the following step of A) the provision of a pre-coated steel sheet coating with a first coating including iron and nickel, B) the thermal treatment of such pre-coated steel sheet at a temperature between 600 and 1000° C., and C) the coating of the steel sheet obtained in step B) with a second coating based on zinc.

A manufacturing method of copper foil and circuit board assembly for high frequency transmission are provided. Firstly, a raw copper foil having a predetermined surface is produced by an electrolyzing process. Subsequently, a roughened layer including a plurality of copper particles is formed on the predetermined surface by an arsenic-free electrolytic roughening treatment and an arsenic-free electrolytic surface protection treatment. Thereafter, a surface treatment layer is formed on the roughened layer, and the roughened layer is made of a material which includes at least one kind of non-copper metal elements and the concentration of the non-copper metal elements is smaller than 400 ppm. By controlling the concentration of the non-copper elements, the resistance of the copper foil can be reduced.

A steel sheet has a tensile strength of 1310 MPa or higher, a specified chemical composition, and a steel microstructure containing martensite at an area ratio of 70% or more, bainite at an area ratio of 30% or less, and ferrite and retained austenite at a total area ratio of 5% or less, in which, at a ¼ thickness position of the steel sheet, a number density of carbides having long axes of 0.5 μm or more is 60000 carbides/mm.sup.2 or less, in a ¼-to-¾ thickness region of the steel sheet, a number density of inclusion grains having equivalent circle diameters of 4.0 μm or more is 10 grains/mm.sup.2 or more and 30 grains/mm.sup.2 or less, and, in a surface-to-¼ thickness region of the steel sheet, a number density of inclusion grains having equivalent circle diameters of 4.0 μm or more is 27 grains/mm.sup.2 or less.

A Ni-plated steel sheet according to one aspect of the present invention includes a base steel sheet and a Ni plating layer provided on a surface of the base steel sheet, the Ni plating layer has a Ni—Fe alloy layer formed on a surface of the base steel sheet, and a ratio of a Zn content to a Ni content in the Ni plating layer is 0.0005% to 0.10%. A manufacturing method of the Ni-plated steel sheet according to one aspect of the present invention has electroplating a base steel sheet using a Ni plating bath in which [Zn.sup.2+]/[Ni.sup.2+] is set to 0.0005% to 0.10% to obtain a material Ni-plated steel sheet, and annealing the material Ni-plated steel sheet.

This punched-workpiece with the insulating film includes a punched-workpiece having a cut surface, a plating layer formed on at least the cut surface of the punched-workpiece, and an insulating film formed on the surface of the plating layer.