The objective of the present invention is to provide a method for preparing a cationic electrodeposition coating composition that contains a bismuth compound and exhibits excellent coating material stability, curability, coating film appearance and the like. The present invention provides a method for preparing a cationic electrodeposition coating composition, which comprises a step for mixing a resin emulsion (i) and a pigment-dispersed paste, and wherein: the resin emulsion (i) contains an aminated resin (A) and a blocked isocyanate curing agent (B); the pigment-dispersed paste contains a bismuth mixture (C) that is obtained by mixing a bismuth compound (c1) and an organic acid (c2) in advance, a pigment-dispersed resin (D), an amine-modified epoxy resin emulsion (ii) that contains an amine-modified epoxy resin (E), and a pigment (F); the pigment-dispersed resin (D) has a hydroxyl number of 20-120 mgKOH/g; and the amine-modified epoxy resin (E) has a hydroxyl number of 150-650 mgKOH/g.

Synthetic brochosomes can be prepared by disposing a monolayer of first polymer microspheres on a substrate and forming a layer of metal on the monolayer of the first polymer microspheres. A monolayer of second polymer microspheres is then disposed on the layer of metal to form a template. The second polymer microspheres are smaller than the first polymer microspheres. A brochosome material is then electrodeposited on the template. The brochosome material is selected from the group consisting of a metal, a metal oxide, a polymer or a hybrid thereof. The first polymer microspheres and the second polymer microspheres are then removed to form a coating of synthetic brochosomes of the brochosome material on the substrate.

Synthetic brochosomes can be prepared by disposing a monolayer of first polymer microspheres on a substrate and forming a layer of metal on the monolayer of the first polymer microspheres. A monolayer of second polymer microspheres is then disposed on the layer of metal to form a template. The second polymer microspheres are smaller than the first polymer microspheres. A brochosome material is then electrodeposited on the template. The brochosome material is selected from the group consisting of a metal, a metal oxide, a polymer or a hybrid thereof. The first polymer microspheres and the second polymer microspheres are then removed to form a coating of synthetic brochosomes of the brochosome material on the substrate.

A water-based electrodeposition dispersion for forming an insulating film includes: polymer particles; an organic solvent; a basic compound; and water, wherein the polymer particles include polyamic acid having a predetermined structural unit, and a volume-based median diameter (D.sub.50) of the polymer particles is 0.08 m to 0.7 m.

A water-based electrodeposition dispersion for forming an insulating film includes: polymer particles; an organic solvent; a basic compound; and water, wherein the polymer particles include polyamic acid having a predetermined structural unit, and a volume-based median diameter (D.sub.50) of the polymer particles is 0.08 m to 0.7 m.

A cast wheel having an alloy substrate includes a primary surface and a secondary surface. A first polymeric coating is applied to the primary surface and to the secondary surface sealing the cast alloy wheel within the first polymeric coating. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is coated with metal using physical vapor deposition with the metal being aesthetically distinguishable from the first polymeric coating. A third polymeric coating is applied over the metal. The third polymeric coating, the intermediate coating and the metal from the primary surface of the cast alloy wheel are removed aesthetically distinguishing the primary surface from the secondary surface. A fourth polymeric coating is applied over the primary surface and the secondary surface.

A cast wheel having an alloy substrate includes a primary surface and a secondary surface. A first polymeric coating is applied to the primary surface and to the secondary surface sealing the cast alloy wheel within the first polymeric coating. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is coated with metal using physical vapor deposition with the metal being aesthetically distinguishable from the first polymeric coating. A third polymeric coating is applied over the metal. The third polymeric coating, the intermediate coating and the metal from the primary surface of the cast alloy wheel are removed aesthetically distinguishing the primary surface from the secondary surface. A fourth polymeric coating is applied over the primary surface and the secondary surface.

A cast wheel having an alloy substrate includes a primary surface and a secondary surface. A first polymeric coating is applied to the primary surface and to the secondary surface sealing the cast alloy wheel within the first polymeric coating. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is coated with metal using physical vapor deposition with the metal being aesthetically distinguishable from the first polymeric coating. A third polymeric coating is applied over the metal. The third polymeric coating, the intermediate coating and the metal from the primary surface of the cast alloy wheel are removed aesthetically distinguishing the primary surface from the secondary surface. A fourth polymeric coating is applied over the primary surface and the secondary surface.

A cast wheel having an alloy substrate includes a primary surface and a secondary surface. A first polymeric coating is applied to the primary surface and to the secondary surface sealing the cast alloy wheel within the first polymeric coating. An intermediate polymeric coating is applied over the first polymeric coating. The intermediate polymeric coating is coated with metal using physical vapor deposition with the metal being aesthetically distinguishable from the first polymeric coating. A third polymeric coating is applied over the metal. The third polymeric coating, the intermediate coating and the metal from the primary surface of the cast alloy wheel are removed aesthetically distinguishing the primary surface from the secondary surface. A fourth polymeric coating is applied over the primary surface and the secondary surface.

An object to be solved by the present invention is to discover a thermosetting coating composition ensuring an excellent finished appearance without a decrease in corrosion resistance, and to provide a coated article with such excellent coating performances. The present invention provides a thermosetting coating composition, comprising a modified epoxy resin (A) resulting from a reaction of an epoxy resin (a1) with a modifier (a2), and optionally with an amine compound (a4); and a blocked polyisocyanate compound (B), the modified epoxy resin (A) comprising, at least in a part of the terminals thereof, a specific organic group, and having a number average molecular weight of 800 to 80,000.