Disclosed is a solution composition which may be used for a single-bath electrochemical passivation and a method using the same. The solution composition includes a metal cation, a metal-oxide anion; and an organic ligand, and optionally includes a non-metallic oxide anion or a polymer. The solution composition may prevent undesired precipitation of metal oxides before performing passivation. In addition, the method of passivation using the solution composition in a single-bath use is also provided.

Disclosed is a solution composition which may be used for a single-bath electrochemical passivation and a method using the same. The solution composition includes a metal cation, a metal-oxide anion; and an organic ligand, and optionally includes a non-metallic oxide anion or a polymer. The solution composition may prevent undesired precipitation of metal oxides before performing passivation. In addition, the method of passivation using the solution composition in a single-bath use is also provided.

The present invention relates to an aqueous coating composition (A) comprising at least one cathodically depositable binder (A1) and optionally at least one crosslinking agent (A2), for at least partly coating an electrically conductive substrate with an electrocoat material, where (A) comprises a total amount of at least 30 ppm of bismuth, based on the total weight of (A), and additionally at least one phosphorus-containing compound (P) blocked with at least one amine of the general formula (I), to the use of (A) for at least partly coating an electrically conductive substrate with an electrocoat material, to a corresponding coating method, and to an at least partly coated substrate obtainable by this method.

The present invention relates to an aqueous coating composition (A) comprising at least one cathodically depositable binder (A1) and optionally at least one crosslinking agent (A2), for at least partly coating an electrically conductive substrate with an electrocoat material, where (A) comprises a total amount of at least 30 ppm of bismuth, based on the total weight of (A), and additionally at least one phosphorus-containing compound (P) blocked with at least one amine of the general formula (I), to the use of (A) for at least partly coating an electrically conductive substrate with an electrocoat material, to a corresponding coating method, and to an at least partly coated substrate obtainable by this method.

The present invention is directed to a coated substrate comprising: A) an electroconductive composite substrate comprising a resinous matrix reinforced with fibers, and B) a cured coating layer electrophoretically deposited on at least at least a portion of a surface of the substrate, wherein the cured coating layer is deposited from a curable, electrodepositable coating composition comprising: (1) a resin component containing an active hydrogen-containing, cationic or anionic resin comprising an acrylic, polyester, polyurethane and/or polyepoxide polymer; and (2) a curing agent. The present invention is further directed to a process for coating a plastic, electroconductive substrate comprising electrophoretically depositing on the substrate the curable, electrodepositable coating composition described above, and heating the coated substrate to a temperature less than 250 F. for a time sufficient to cure the electrodeposited coating on the substrate.

The present invention is directed to a coated substrate comprising: A) an electroconductive composite substrate comprising a resinous matrix reinforced with fibers, and B) a cured coating layer electrophoretically deposited on at least at least a portion of a surface of the substrate, wherein the cured coating layer is deposited from a curable, electrodepositable coating composition comprising: (1) a resin component containing an active hydrogen-containing, cationic or anionic resin comprising an acrylic, polyester, polyurethane and/or polyepoxide polymer; and (2) a curing agent. The present invention is further directed to a process for coating a plastic, electroconductive substrate comprising electrophoretically depositing on the substrate the curable, electrodepositable coating composition described above, and heating the coated substrate to a temperature less than 250 F. for a time sufficient to cure the electrodeposited coating on the substrate.

The invention relates to pigment- and/or filler-containing formulations, comprising one or more solids selected from the group of the pigments and fillers, and an emulsifier (EQ), which has the following formula: R.sup.1N(R.sup.2)(R.sup.3)(R.sup.4)X(EQ), where: R.sup.1 is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; R.sup.2, R.sup.3, and R.sup.4 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms; and X stands for the acid anion of an organic or inorganic acid HX. The invention further relates to coating agents comprising said formulations, the use of said formulations to produce electrocoats, and conductive substrates coated with said coating agent compositions.

The invention relates to pigment- and/or filler-containing formulations, comprising one or more solids selected from the group of the pigments and fillers, and an emulsifier (EQ), which has the following formula: R.sup.1N(R.sup.2)(R.sup.3)(R.sup.4)X(EQ), where: R.sup.1 is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; R.sup.2, R.sup.3, and R.sup.4 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms; and X stands for the acid anion of an organic or inorganic acid HX. The invention further relates to coating agents comprising said formulations, the use of said formulations to produce electrocoats, and conductive substrates coated with said coating agent compositions.

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R.sup.1N.sup.?(R.sup.2)(R.sup.3)(R.sup.4)X.sup.?, where R.sup.1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R.sup.2, R.sup.3, and R.sup.4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles having a Z-average particle diameter of 5 to 500 nm and which are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A). The emulsion polymerization takes place in the presence of one or more emulsifiers (EQ) having the following general formula: R.sup.1N.sup.?(R.sup.2)(R.sup.3)(R.sup.4)X.sup.?, where R.sup.1 is a moiety with 15 to 40 carbon atoms which contains at least one aromatic group and at least one aliphatic group, and which contains at least one functional group selected from hydroxyl groups, thiol groups, and primary or secondary amino groups, and/or has at least one carbon-carbon multiple bond, R.sup.2, R.sup.3, and R.sup.4, independently of one another, are the same or different aliphatic moieties containing 1 to 14 carbon atoms, and X stands for the acid anion of an organic or inorganic acid. The invention further relates to a method for producing the primary dispersions, and to coating agents which include the primary dispersions, and to the use of the primary dispersions for producing electrodeposition coatings, and also to conductive substrates coated with the coating compositions. The invention further relates to emulsifiers which are used for producing the primary dispersions according to the invention.