The present disclosure relates generally to new forms of portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power.

The present invention provides a system and method of storing hydrogen (H.sub.2) and releasing it on demand, comprising and making use of diaminoalkanes and alcohols, or aminoalcohols as liquid-organic hydrogen carrier systems (LOHC). 2-amino-ethanol (AE) or its N-methyl derivative 2-(methylamino)ethanol undergo catalytic dehydrogenation to form a cyclic dipeptide (glycine anhydride—GA) or its N,N-dimethyl derivative (N,N-dimethyl GA) with release of hydrogen. Similarly, ethylenediamine (ED) and ethanol undergo catalytic dehydrogenation to form N,N′-diacetylethylenediamine (DAE) with release of hydrogen. Glycine anhydride (GA) or N,N-dimethyl-GA may be hydrogenated back to 2-aminoethanol (AE) or 2-(methylamino)ethanol, respectively, each of which functions as a hydrogen storage system. N,N′-diacetylethylenediamine (DAE) may be hydrogenated back to ED and ethanol, which functions as a hydrogen storage system. These reactions may be catalyzed by a variety of compounds or complexes, including Ruthenium complexes as described herein.

The present disclosure relates to improved processes for the preparation of metal hydrides. The present disclosure also relates to metal hydrides, e.g., metal hydrides prepared by the processes described herein, that exhibit enhanced hydrogen storage capacity when used as hydrogen storage systems.

Proposed are a naphthalene-based hydrogen storage material including a naphthalene group, the naphthalene-based hydrogen storage material being capable of being used as a hydrogen storage media for supplying hydrogen to a device using hydrogen such as a fuel cell and a hydrogen combustion device, and to a method of storing and releasing hydrogen using the same. The hydrogen storage material can exhibit a significantly high hydrogen capacity, and can have excellent cost competitiveness with the use of a low-cost organic compound which is commercially available in the art.

Provided is a catalyst structure for a liquid organic hydrogen carrier (LOHC) dehydrogenation reactor, including a support, a plurality of channels formed on the support in such a manner that the LOHC may flow therethrough, and an LOHC dehydrogenation catalyst that is coated on the inner surfaces of the channels and is in contact with the LOHC to carry out LOHC dehydrogenation, wherein the hydrogen gas generated from the dehydrogenation is discharged along the channels so that the contact area between the LOHC and the LOHC dehydrogenation catalyst may be increased.

The invention relates to an improved process for preparing metal-organic framework materials, metal-organic frameworks obtainable by such processes, methods using the same, and the use thereof. The process of the invention provides an improved process for preparing metal-organic frameworks in particular monocrystalline metal-organic frameworks having large crystal sizes. The invention also relates to metal organic frameworks comprising iron or titanium, and their uses.

A transition metal amino borohydride material includes a first row transition metal in conjunction with an amine ligand and borohydride, in a condition of having been thermally treated to a temperature of at least 70° C. and up to but not including 800° C. An exemplary such material, Fe(DETA)(BH.sub.4).sub.2 having been heat treated at 300° C., had good hydrogen storage characteristics.

A method for detecting a degree of hydrogenation of a liquid comprises one or more liquid hydrogen carriers, which can be hydrogenated, comprising: detecting a material property of the liquid and determining the degree of hydrogenation of the liquid on the basis of the detected material property of the liquid.

Methods of forming a high surface area compacted MOF powder are disclosed, as well as MOF pellets formed thereby. The method may include synthesizing a metal organic framework (MOF) powder using a first solvent, exchanging the first solvent with a second solvent such that pores of the MOF powder are at least 10% filled with the second solvent, compacting the MOF powder having pores at least 10% filled with the second solvent into a pellet, and desolvating the compacted pellet to remove the second solvent. The pellet may maintain a specific surface area after compacting that is at least 80% its initial specific surface area. Compacting the MOF powder with a solvent at least partially filling its pores may prevent or reduce crushing of the MOF pore structure and maintain surface area, for example, for hydrogen or natural gas storage.

A catalyst used for dehydrogenation of an organic hydrogen-storage material to generate hydrogen, a support for the catalyst, and a preparation process thereof are presented. A hydrogen-storage alloy and a preparation process thereof are also provided. A process for providing high-purity hydrogen, a high-efficiently distributed process for producing high-purity and high-pressure hydrogen, a system for providing high-purity and high-pressure hydrogen, a mobile hydrogen supply system, and a distributed hydrogen supply apparatus are also described.