C01B3/0021

HYDROGEN STORAGE MATERIAL

Disclosed is a method of: providing a hydrogenated sp.sup.2 carbon allotrope, and releasing hydrogen gas from the carbon allotrope. The method may be used an apparatus having: a vessel for containing the hydrogenated sp.sup.2 carbon allotrope, a fuel cell capable of using hydrogen gas a fuel, and a tube for transporting hydrogen gas from the vessel to the fuel cell. The carbon allotrope may be made by: providing a mixture of an sp.sup.2 carbon allotrope and liquid ammonia, adding an alkali metal to the mixture, and sonicating the mixture to form a hydrogenated form of the carbon allotrope. The hydrogenated carbon can be at least 3.5 wt % hydrogen covalently bound to the carbon.

Graphene oxide/metal nanocrystal multilaminates the atomic limit for safe, selective hydrogen storage

Various embodiments of the invention describe an environmentally stable, and exceptionally dense hydrogen storage (6.5 wt % and 0.105 kg H.sub.2/L in the total composite, 7.56 wt % in Mg) using atomically thin and gas-selective reduced graphene oxide sheets as encapsulants. Other approaches to protecting reactive materials involve energy intensive introduction of considerable amounts of inactive, protective matrix which compromises energy density. However, these multilaminates are able to deliver exceptionally dense hydrogen storage far-exceeding 2020 DOE target metrics for gravimetric capacity (5.5 wt %), and ultimate full-fleet volumetric targets (0.070 kg H.sub.2/L) for fuel cell electric vehicles. Methods of stabilizing reactive nanocrystalline metals in zero-valency also has wide-ranging applications for batteries, catalysis, encapsulants, and energetic materials.

Nanocomposite based on graphene for reversible storage of hydrogen

A nanocomposite for the reverse storage of hydrogen based on monolayer sheets of polycrystalline or monocrystalline grapheme having a form of a cylindrical spiral roll of polycrystalline or monocrystalline graphene with a preferably constant spacing in the range from 0.2 to 2 nm, whereby the said spiral roll of polycrystalline graphene has grains with a minimum diameter of 50 nm.

Carbon-based compositions with highly efficient volumetric gas sorption

The present application is generally directed to gas storage materials such as activated carbon comprising enhanced gas adsorption properties. The gas storage materials find utility in any number of gas storage applications. Methods for making the gas storage materials are also disclosed.

Solid-gas reaction substance-filled reactor and method for manufacturing the same

A solid-gas reaction substance-filled reactor includes a core part in which heat medium heat-transfer tubes and spacers are alternately stacked, a gas introduction/discharge part that communicates with opening ends of the spacers, and a heat medium introduction/discharge part that communicates with heat medium flow paths. Filled bodies including metallic foil bags and a solid-gas reaction substance filled in the bags are inserted into the spacers. At least the filled bodies and the heat medium heat-transfer tubes are brazed to each other. The solid-gas reaction substance-filled reactor is obtained by stacking the filled bodies with the solid-gas reaction substance filled into the metallic bags, the heat medium heat-transfer tubes, and the spacers in a predetermined order and then brazing them.

Process for Producing a Hydrogen Storage Means

A process for producing a hydrogen storage means. Separate layers comprising a hydrogen-storing material and a heat-conducting material are introduced into a press mold. The separate layers of the hydrogen-storing material and the heat-conducting material are compressed together to generate a sandwich structure. The heat-conducting material, on use of the sandwich structure as hydrogen storage means, assumes the task of conducting heat.

Electrochemical hydrogen storage electrodes and cells

Hydrogen storage negative electrodes based on group IV elements, for example hydrogen storage negative electrodes based on silicon and/or carbon, are highly effective towards reversibly charging/discharging hydrogen in an hydride electrochemical cell.

CARBON-BASED COMPOSITIONS WITH HIGHLY EFFICIENT VOLUMETRIC GAS SORPTION

The present application is generally directed to gas storage materials such as activated carbon comprising enhanced gas adsorption properties. The gas storage materials find utility in any number of gas storage applications. Methods for making the gas storage materials are also disclosed.

Hydrogen storage carbon material

A hydrogen storage carbon material having a carbon structure suited for hydrogen storage and a production method thereof. The hydrogen storage carbon material according to this embodiment includes a carbon structure which has a ratio of an ultramicropore volume to a micropore volume of 60% or more, and in which stored hydrogen exhibits, in .sup.1H-NMR measurement, a second peak at a position corresponding to a chemical shift of from 2 ppm to 20 ppm with respect to a first peak attributed to gaseous hydrogen.

CARBON-BASED HYDROGEN STORAGE MATERIAL HAVING AUTOCATALYTIC CAPABILITY, PRODUCTION METHOD THEREOF, AND HYDROGEN ADSORBING - STORING METHOD, HYDROGEN RELEASING METHOD, AND HYDROGEN ADSORPTION - STORAGE DEVICE USING THEREOF

The objective of the present invention is to provide a carbon-based hydrogen storage material having an autocatalytic capability, and a production method therefor. The present invention provides a carbon-based hydrogen storage material having an atomic defect, which is a hydrogen adsorbing-storing hydrocarbon compound having an autocatalysis reaction, wherefrom hydrogen that has been adsorbed and stored within the compound is either released while no heat is absorbed, or released while heat is generated. In addition, provided is a production method for the carbon-based hydrogen storage material having the autocatalytic capability, comprising: preparing a hydrocarbon compound serving as a production starting material for the carbon-based hydrogen storage material; setting the production starting material inside a container under a predetermined partial gas pressure; irradiating the production starting material with an ion beam and then performing annealing under predetermined conditions, thereby forming the hydrocarbon compound having the atom defect; and processing with activated hydrogen the hydrocarbon compound having the atom defect. Also provided is a production method for a hydrogen adsorption-storage device using the carbon-based hydrogen storage material.