A system for controlling hydrogen production from water-reactive aluminum includes a regulator. For example, the regulator may include a plurality of discrete objects and a retainer. Each one of the discrete objects includes aluminum in an activated form reactable with water to produce hydrogen. The retainer may encase the plurality of discrete objects collectively in an elongate shape having an axial dimension greater than a radial dimension. Within the elongate shape, the plurality of discrete objects may define voids therebetween. The retainer may be permeable across its thickness such that water may enter the retainer to react with the activated form of aluminum of the discrete objects in a local concentration that promotes heat generation for rapid reaction while water about the retainer may globally cool the material in the retainer, with the combination promoting rapid and efficient reaction of aluminum to produce hydrogen.

A system for controlling hydrogen production from water-reactive aluminum includes a regulator. For example, the regulator may include a plurality of discrete objects and a retainer. Each one of the discrete objects includes aluminum in an activated form reactable with water to produce hydrogen. The retainer may encase the plurality of discrete objects collectively in an elongate shape having an axial dimension greater than a radial dimension. Within the elongate shape, the plurality of discrete objects may define voids therebetween. The retainer may be permeable across its thickness such that water may enter the retainer to react with the activated form of aluminum of the discrete objects in a local concentration that promotes heat generation for rapid reaction while water about the retainer may globally cool the material in the retainer, with the combination promoting rapid and efficient reaction of aluminum to produce hydrogen.

A stable aluminum slurry fuel and related systems and methods of use are provided herein. Certain embodiments of the disclosure are related to an aluminum slurry fuel comprising a plurality of aluminum particles dispersed in a carrier fluid. In some embodiments, the aluminum particles comprise an activating composition comprising gallium and/or indium. Additionally, methods of making and using the aluminum slurry fuel are presented herein. For instance, the resultant aluminum slurry fuel may react exothermically with water over a wide range of temperatures to produce hydrogen. The resulting slurry fuel may be used as an energy source for various applications and/or for generating hydrogen for other applications.

A stable aluminum slurry fuel and related systems and methods of use are provided herein. Certain embodiments of the disclosure are related to an aluminum slurry fuel comprising a plurality of aluminum particles dispersed in a carrier fluid. In some embodiments, the aluminum particles comprise an activating composition comprising gallium and/or indium. Additionally, methods of making and using the aluminum slurry fuel are presented herein. For instance, the resultant aluminum slurry fuel may react exothermically with water over a wide range of temperatures to produce hydrogen. The resulting slurry fuel may be used as an energy source for various applications and/or for generating hydrogen for other applications.

The invention provides an apparatus for generating hydrogen including first and second reactant containers linked to a reactor vessel. The reactant containers contain reactants which, when mixed in the reactor vessel, react to form hydrogen gas. Peristaltic pumps pump the reactants from the reactant containers to the reactor vessel. The peristaltic pumps are selected to provide a maximum pumping pressure in the range from 0.1 bar to 10 bar. An electronic control means is programmed to control the flow of reactants to the reactor vessel so as to maintain the pressure of hydrogen gas within the apparatus at a value of no more than 10 Bar.

The invention provides an apparatus for generating hydrogen including first and second reactant containers linked to a reactor vessel. The reactant containers contain reactants which, when mixed in the reactor vessel, react to form hydrogen gas. Peristaltic pumps pump the reactants from the reactant containers to the reactor vessel. The peristaltic pumps are selected to provide a maximum pumping pressure in the range from 0.1 bar to 10 bar. An electronic control means is programmed to control the flow of reactants to the reactor vessel so as to maintain the pressure of hydrogen gas within the apparatus at a value of no more than 10 Bar.

A hydrogen-developing body of an apparatus for producing hydrogen from an electrolyte solution is disclosed. The hydrogen-developing body is formed from magnesium (Mg) or zinc (Zn) or the like, or an alloy thereof, or has an electrolyte-contacting surface which is formed from magnesium (Mg) or zinc (Zn) or the like, or an alloy thereof. The electrolyte-contacting surface has regions formed from iron (Fe) or a Fe alloy, or the like, which are pellet-shaped and stochastically embedded into the surface such that the Fe/Fe alloy pellets are exposed to the environment of the body.

A method uses a chemical system to generate hydrogen gas. The chemistry involves a two-step reaction. In the first step, an alkaline hydride reacts with water to produce a hydroxide and hydrogen. In the second step, the hydroxide reacts with aluminum to produce even more hydrogen. The fuel is composed out of a mixture of powders of the alkaline hydride and aluminum. The fuel is encapsulated in a water soluble capsule for easy dispensing and protection against short time exposure to moisture. For large scale systems, the fuel is mixed with a low hydrophilicity ionic liquid to make it into a slurry that can be dispensed into a reaction chamber. The generation system comprises a tank, a pump, a first tube, a second tube, one or more capsules, a tank sensor assembly, and a processing system. The method comprises the steps of dispensing the capsules or the slurry in the tank; supplying water to the tank; and collecting hydrogen gas from the tank. After supplying water to the tank, the two reaction steps, being safe and controllable, facilitating hydrolysis reaction of metal and metal salts, are carried out. The produced hydrogen may be used in a fuel cell or a biomedical application.

Materials, kits, and methods are directed to controlling reactability of activated aluminum to produce hydrogen when exposed to water. For example, a moisture-stabilized material may be treatable with one or more additives to form a water-reactive source of hydrogen. The moisture-stabilized material may include a bulk volume including aluminum, at least one activation metal disposed along the aluminum within the bulk volume, the at least one activation metal more noble than the aluminum, and a salt along at least an outer surface of the bulk volume, the salt dissolvable in water to form an ion-containing solution at a rate faster than a reaction rate of water with the aluminum of the bulk volume.

Materials, kits, and methods are directed to controlling reactability of activated aluminum to produce hydrogen when exposed to water. For example, a moisture-stabilized material may be treatable with one or more additives to form a water-reactive source of hydrogen. The moisture-stabilized material may include a bulk volume including aluminum, at least one activation metal disposed along the aluminum within the bulk volume, the at least one activation metal more noble than the aluminum, and a salt along at least an outer surface of the bulk volume, the salt dissolvable in water to form an ion-containing solution at a rate faster than a reaction rate of water with the aluminum of the bulk volume.