A system for controlling contamination in hydrogen production from water-reactive aluminum includes at least one reaction vessel. For example, each reaction vessel may include a container, a conduit, and a plurality of baffles. The container may define a volume, and the conduit may define an orifice outside of the container and spaced away from the container. The plurality of baffles may be disposed in the volume to form a tortuous flow path through the volume to the orifice of the conduit to facilitate rapid production of a large quantity of hydrogen from water-reactive aluminum while reducing the likelihood that ejecta, aerosols, or a combination thereof, may escape the reaction vessel to interfere with end-use of the hydrogen produced.

A hydrogen production system includes: a hydrogen compound slurry in which a hydrogen compound member is suspended in a solvent containing water; a first vessel; a second vessel having an internal temperature higher than that of the first vessel; a first passage connecting the first vessel and the second vessel; and a second passage connecting the first vessel and the second vessel and different from the first passage. The hydrogen production system is configured to allow the hydrogen compound slurry contained in the first vessel to move into the second vessel through the first passage, and the hydrogen compound slurry contained in the second vessel to move into the first vessel through the second passage.

A method of packaging water-reactive aluminum may include directing at least one discrete object into a container, the at least one discrete object including an aluminum alloy, the aluminum alloy plastically deformed and non-recrystallized, introducing, into the container, a liquid metal alloy including one or more activation metals, enclosing the at least one discrete object and the liquid metal alloy with one another in the container to form a kit, for a predetermined period, exposing the kit to a heating environment, and agitating the at least one discrete object and the liquid metal alloy in the container in the heating environment during the predetermined period to form the kit into a packaged unit of water-reactive aluminum.

A method of packaging water-reactive aluminum may include directing at least one discrete object into a container, the at least one discrete object including an aluminum alloy, the aluminum alloy plastically deformed and non-recrystallized, introducing, into the container, a liquid metal alloy including one or more activation metals, enclosing the at least one discrete object and the liquid metal alloy with one another in the container to form a kit, for a predetermined period, exposing the kit to a heating environment, and agitating the at least one discrete object and the liquid metal alloy in the container in the heating environment during the predetermined period to form the kit into a packaged unit of water-reactive aluminum.

Aluminum can be used as a fuel source when reacted with water if its native surrounding oxide coating is penetrated with a gallium-based eutectic. When discrete aluminum objects are treated in a heated bath of eutectic, the eutectic penetrates the oxide coating. After the aluminum objects are treated, the aluminum objects can be reacted in a reactor to produce hydrogen which can, for example, react with oxygen in a fuel cell to produce electricity, for use in a variety of applications.

The invention relates to power engineering equipment, in particular, to an self-contained portable device for filling cylinders with high-pressure hydrogen at preliminary high-pressure hydrogen production from hydrolysis. The technical result of the invention is providing with high-purity high-pressure hydrogen charging in any place, where there is an access to water, with complete elimination of power costs, reducing reactor weight, high performance reliability and easy servicing of the device. The self-contained portable device for charging cylinders with high-pressure hydrogen comprising a reaction chamber containing a solid reagent cartridge and reaction liquid pipe configured to supply liquid reagent to the lower part of the reaction chamber, a refrigerant dryer comprising installed in series a hydrogen cooler, filter-separator and hydrogen dryer, liquid reagent pipeline connected with the reaction liquid pipe, high-pressure hand pump connected with the liquid reagent pipeline to the reaction chamber and configured to feed liquid reagent in portions to the reaction chamber, gaseous hydrogen pipeline connecting the reaction chamber and refrigerant dryer, treated gaseous hydrogen pipeline configured to supply high-pressure hydrogen from the refrigerant dryer to a cylinder, wherein the gaseous hydrogen pipeline, treated gaseous hydrogen pipeline and liquid reagent pipeline are equipped with quick-release couplings, and the reaction chamber is placed in the reaction chamber cooling tank.

A hydrogen generation device capable of generating hydrogen using an inexpensive material is provided. The hydrogen generation device includes: a water flow path unit through which a solution flows in from outside and exits; a hydrogen generation unit made of a metal, the hydrogen generation unit generating hydrogen by a reaction with the flowing-in solution; and a hydrogen collection unit for collecting the generated hydrogen, wherein the hydrogen generation unit is disposed so that friction with the flowing-in solution peels off a surface film of the metal to expose an active surface of the metal, the metal being the hydrogen generation unit itself.

A hydrogen generation device capable of generating hydrogen using an inexpensive material is provided. The hydrogen generation device includes: a water flow path unit through which a solution flows in from outside and exits; a hydrogen generation unit made of a metal, the hydrogen generation unit generating hydrogen by a reaction with the flowing-in solution; and a hydrogen collection unit for collecting the generated hydrogen, wherein the hydrogen generation unit is disposed so that friction with the flowing-in solution peels off a surface film of the metal to expose an active surface of the metal, the metal being the hydrogen generation unit itself.

The invention provides particulate compositions, which generate hydrogen when contacted with water, the compositions comprising particles of: aluminium; one or more metal oxides; and one or more chloride salts of alkali metals or alkaline earth metals.

The invention also provides methods of preparing such compositions and methods of generating hydrogen by contacting the compositions with water.

The invention provides particulate compositions, which generate hydrogen when contacted with water, the compositions comprising particles of: aluminium; one or more metal oxides; and one or more chloride salts of alkali metals or alkaline earth metals.

The invention also provides methods of preparing such compositions and methods of generating hydrogen by contacting the compositions with water.