The disclosure provides a method of producing hydrogen. The method comprises conducting a thermochemical reaction by contacting a metal, or an alloy thereof, with steam to produce a metal oxide and/or a metal hydroxide and hydrogen. The method then comprises contacting the metal oxide and/or the metal hydroxide produced in the thermochemical reaction with water or a basic aqueous solution to produce a solution comprising a metal ion. Finally, the method comprises conducting an electrochemical reaction by applying a voltage across an anode and a cathode, whereby at least a portion of the cathode contacts the solution comprising the metal ion, to produce hydrogen, oxygen and the metal, or the alloy thereof.

The disclosure provides a method of producing hydrogen. The method comprises conducting a thermochemical reaction by contacting a metal, or an alloy thereof, with steam to produce a metal oxide and/or a metal hydroxide and hydrogen. The method then comprises contacting the metal oxide and/or the metal hydroxide produced in the thermochemical reaction with water or a basic aqueous solution to produce a solution comprising a metal ion. Finally, the method comprises conducting an electrochemical reaction by applying a voltage across an anode and a cathode, whereby at least a portion of the cathode contacts the solution comprising the metal ion, to produce hydrogen, oxygen and the metal, or the alloy thereof.

A hydrogen mixed gas generation method using a device that includes a heating pipe housing therein a reduction acceleration member and a heating part including a heating device that heats the heating pipe includes a first process and a second process. The first process includes: causing raw water to flow into the heating pipe and heating the flowing raw water to generate water vapor; heating the generated water vapor to between 500° C. to 800° C.; causing the heated water vapor to be in contact with the reduction acceleration member that is heated along with the raw water to reduce the water vapor and generate hydrogen gas. The second process includes: diluting the hydrogen gas generated in the first process to obtain hydrogen mixed gas whose concentration of hydrogen gas is between 500 ppm to 20000 ppm.

A composition having: titania aerogel having titania nanoparticles and copper nanoparticles. Each of the copper nanoparticles is in contact with more than one of the titania nanoparticles. A method of: providing a titania aerogel, and forming or depositing copper nanoparticles onto the surface of the titania aerogel.

A composition having: titania aerogel having titania nanoparticles and copper nanoparticles. Each of the copper nanoparticles is in contact with more than one of the titania nanoparticles. A method of: providing a titania aerogel, and forming or depositing copper nanoparticles onto the surface of the titania aerogel.

A pilot plant for chemical looping hydrogen generation using a single-column packed bed and hydrogen generation method. The plant has a feeding system, reaction system, tail gas treatment and analysis system, and auxiliary system. The reaction system has a packed bed reactor, inside which a thermal storage layer, oxygen carrier layer and supporting layer are arranged successively from top to bottom. The feeding system has a delivery pipe, metering pump, mass flow controller and fuel mixer. The tail gas treatment and analysis system has a cooler, gas-liquid separator, mass flow meter, gas analyzer and tail gas pipe. The packed bed reactor is subjected to fuel reduction, purge, steam oxidation, purge, air combustion and purge stages successively under control of the feeding system. The pilot plant enables evaluation for oxygen carriers and identification for technological difficulties and can generate high-purity hydrogen without using complex gas purification devices.

According to one embodiment, a magnesium-recycling hydrogen generation system includes: a by-product acquisition unit that separates a by-product from a post-reaction solution, which is a solution after reacting with a hydrogen generation material containing a hydrogen-containing magnesium compound that generates hydrogen via a reaction with the solution, to acquire the by-product including more than one type of oxygen-containing magnesium compound that contains oxygen produced by the reaction, a raw material production unit that reacts the by-product with a halogen-containing substance containing halogen and other atoms than the halogen to produce a raw material containing magnesium halide, a hydrogen generation material production unit that reduces the raw material with plasma containing hydrogen to produce the hydrogen generation material, and a hydrogen generator that reacts the hydrogen generation material with the solution to generate hydrogen.

The invention is a method for coproducing Hydrogen and certain metals by reducing a metal oxide(s) with MgH.sub.2 or with metal and water, wherein the non-water oxides used in the method include SiO.sub.2, Cr.sub.2O.sub.3, TiO.sub.2, SnO.sub.2, ZrO.sub.2, CuO, ZnO, WO.sub.3, Ta.sub.2O.sub.5, Cs.sub.2Cr.sub.2O.sub.7 or CsOH. The method reacts the MgH.sub.2 with a metal oxide or directly uses metal and water instead of a hydride, and initiates a reaction with the metal oxide. The reaction releases Hydrogen and reduces the subject oxide to metal.

The invention is a method for coproducing Hydrogen and certain metals by reducing a metal oxide(s) with MgH.sub.2 or with metal and water, wherein the non-water oxides used in the method include SiO.sub.2, Cr.sub.2O.sub.3, TiO.sub.2, SnO.sub.2, ZrO.sub.2, CuO, ZnO, WO.sub.3, Ta.sub.2O.sub.5, Cs.sub.2Cr.sub.2O.sub.7 or CsOH. The method reacts the MgH.sub.2 with a metal oxide or directly uses metal and water instead of a hydride, and initiates a reaction with the metal oxide. The reaction releases Hydrogen and reduces the subject oxide to metal.

The process describes the capability of solid-state metals to oxidize in water to produce hydrogen when stimulated by laser. The solid-state metals with an adherent surface layer of the oxide component is introduced into water or another suitable oxidizer. The metal-oxidizer reaction to form hydrogen is initiated and maintained by a laser periodically/continually ablating the metal. The energy, pulse duration and wavelength of the laser may be tailored to control the rate of reaction of the source material with the oxidizer, and thereby control the rate of formation of hydrogen. Application of energy produced by such method may include powering large scale commercial and residential energy companies, providing sustainable and continuous fuel for intergalactic missions, providing an alternative fuel sources for on-board hydrogen-powered vehicles and smaller scale applications such as emergency generators.