Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

An easily transportable micro-scale process is described for the direct production of liquid fuels from flare gas, biogas, stranded natural gas, natural gas emissions from methane hydrate dissociation, and other low-volume, gas-phase hydrocarbon resources. The process involves the design of an integrated series of tubular catalytic reactors in which each consecutive catalytic reactor in the series has been designed with larger volumes of catalyst so that a single pass efficiency of about 90% or greater is achieved while keeping the temperatures and pressures of each reactor similar and without requiring tailgas recycling to the reactors. Typically, the process employs a direct fuel production catalyst that produces undetectable, detrimental carboxylic acids in the fuel and catalyst reaction water. As a result, the directly produced, premium fuels are non-corrosive and do not degrade during long-term storage.

Method for stable ethanol steam reforming, wherein a catalytic ethanol reforming is carried out in two vessels operating in parallel mode both filled in with a catalyst active for this reaction, with the first vessel acting in operation mode, generating an hydrogen rich stream, and the parallel vessel, acting in regeneration mode, made flowing with steam in order to carry out the gasification of carbonaceous compounds deposited on the catalyst.

Disclosed are a quick-start system for preparing hydrogen via aqueous methanol, and hydrogen preparation method. The system comprises a liquid storage container, a raw material feeding device, a quick-start device, a hydrogen preparation equipment and a membrane separation device; the quick-start device comprises a first start device and a second start device; the first start device comprises a first heating mechanism and a first gasification pipeline, the first gasification pipeline is wound around the first heating mechanism; one end of the first gasification pipeline is connected to the liquid storage container, and methanol is fed into the first gasification pipeline via the raw material feeding device, for the first heating mechanism to heat and gasify; the hydrogen preparation equipment comprises a reforming chamber; the second start device comprises a second gasification pipeline, a main body of the second gasification pipeline is disposed in the reforming chamber; the methanol output by the first gasification pipeline and/or the second gasification pipeline heats the second gasification pipeline while heating the reforming chamber, to gasify the methanol in the second gasification pipeline. The present invention can be quickly started, while having less energy consumption and good practicability.

The invention relates to an installation (1) and a method allowing the near total recovery and space-saving storage of carbon in the form of liquid carbon dioxide (19), from a substance (9) of the group consisting of hydrocarbons/ethers/alcohols, without the use of gas compression. To achieve this, a superheated gas (12) at a pressure of over 5.18 bar is generated from the substance (9) of the group consisting of hydrocarbons/ethers/alcohols and water (10), and this gas is delivered, by means of steam reforming and hydrogen liberation, into a retentate mass flow (15) containing carbon dioxide. Liquid carbon dioxide (19) is obtained therefrom by means of condensation, and is stored in a storage tank (7) while the liberated hydrogen is oxidised to provide mechanical and/or electrical as well as thermal energy. The use of membranes with low hydrogen/carbon dioxide permeation selectivity is permitted by forming a permeate mass flow circuit that is closed in respect of carbon dioxide. Operation at low pressures is permitted by the condensation and storage at temperatures below the ambient temperature, for which purpose cold (17) is generated from said thermal energy in a sorption method.

Hydrogen generation assemblies, hydrogen purification devices, and their components are disclosed. In some embodiments, the devices may include a permeate frame with a membrane support structure having first and second membrane support plates that are free from perforations and that include a plurality of microgrooves configured to provide flow channels for at least part of the permeate stream. In some embodiments, the assemblies may include a return conduit fluidly connecting a buffer tank and a reformate conduit, a return valve assembly configured to manage flow in the return conduit, and a control assembly configured to operate a fuel processing assembly between run and standby modes based, at least in part, on detected pressure in the buffer tank and configured to direct the return valve assembly to allow product hydrogen stream to flow from the buffer tank to the reformate conduit when the fuel processing assembly is in the standby mode.

The present invention relates to a reactor for production of synthesis gas that optionally has a fluid-tight connection to a heat exchanger, and to a process for producing synthesis gas, preferably under high pressure.

A reforming device (10) according to the present invention has a compressor (11), a first heat exchanger (12), a desulfurization device (13), a reformer (14), a raw material gas branching line (L11) that extracts a compressed natural gas (21) from a downstream side of the desulfurization device (13) with respect to the flow direction of the natural gas (21) and supplies the natural gas (21) to the reformer (14), and a flue gas discharging line (L12) that discharges a flue gas (22) generated in the reformer (14), wherein the first heat exchanger (12) is provided in the flue gas discharging line (L12), and the flue gas (22) is used as a heating medium of the compressed natural gas (21).

Methods and systems for the dehydrogenation of hydrocarbons include a direct contact condenser to remove compounds from an offgas process stream. The reduction of compounds can decrease duty on the offgas compressor by removing steam and aromatics from the offgas. The dehydrogenation reaction system can be applicable for reactions such as the dehydrogenation of ethylbenzene to produce styrene, the dehydrogenation of isoamiline to produce isoprene, or the dehydrogenation of n-pentene to produce piperylene.

The present invention is generally directed to the efficient production of low-carbon methanol, ethanol or mixtures of methanol and ethanol from captured CO.sub.2 and renewable H.sub.2 at a generation site. The H.sub.2 is generated from water using an electrolyzer powered by renewable electricity, or from any other means of low-carbon H.sub.2 production. An improved catalyst and process is described that efficiently converts H.sub.2 and CO.sub.2 mixture to syngas in a one-step process, and alcohols, such as methanol and ethanol, are produced from the syngas in a second step. The liquid methanol and ethanol, which are excellent H.sub.2 carriers, are transported to a production site, where another improved catalyst and process efficiently converts them to syngas. The syngas can then be used at the production site for the synthesis of low carbon fuels and chemicals, or to produce purified low carbon H.sub.2. The low carbon H.sub.2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.