Patent classifications
C01B3/34
METHOD AND FACILITY FOR PRODUCING A TARGET COMPOUND
The invention relates to a method (100) for producing a target compound, wherein a paraffin is subjected to an oxidative dehydrogenation (1) with oxygen to obtain an olefin, and wherein the olefin is subjected to a hydroformylation (2) with carbon monoxide to obtain an aldehyde, wherein the paraffin and the olefin have a carbon chain having a first carbon number and the aldehyde has a carbon chain having a second carbon number which is one greater than the first carbon number. It is provided that carbon dioxide is formed as a by-product in the oxidative dehydrogenation (1), that the carbon dioxide is subjected to dry reforming (3) at least in part with methane to obtain carbon monoxide and hydrogen, and that the carbon monoxide obtained in the dry reforming (3) and/or the hydrogen obtained in the dry reforming (3) is supplied to the hydroformylation (2). A corresponding installation is also the subject matter of the invention.
METHOD AND FACILITY FOR PRODUCING A TARGET COMPOUND
The invention relates to a method (100) for producing a target compound, wherein a paraffin is subjected to an oxidative dehydrogenation (1) with oxygen to obtain an olefin, and wherein the olefin is subjected to a hydroformylation (2) with carbon monoxide to obtain an aldehyde, wherein the paraffin and the olefin have a carbon chain having a first carbon number and the aldehyde has a carbon chain having a second carbon number which is one greater than the first carbon number. It is provided that carbon dioxide is formed as a by-product in the oxidative dehydrogenation (1), that the carbon dioxide is subjected to dry reforming (3) at least in part with methane to obtain carbon monoxide and hydrogen, and that the carbon monoxide obtained in the dry reforming (3) and/or the hydrogen obtained in the dry reforming (3) is supplied to the hydroformylation (2). A corresponding installation is also the subject matter of the invention.
BIOGAS CONVERSION TO MIXED ALCOHOLS
Some variations provide a process for producing mixed alcohols, comprising: purifying a biogas feedstock to generate a renewable natural gas stream comprising methane; introducing the renewable natural gas stream into a methane-to-syngas unit operated at effective conditions to convert the methane to a first syngas stream containing at least H.sub.2, CO, and CO.sub.2; purifying the first syngas stream, including separating the CO.sub.2 from the first syngas stream, and optionally separating some of the H.sub.2 from the first syngas stream, thereby generating a clean syngas stream; introducing the clean syngas stream into a mixed-alcohol reactor operated at effective alcohol synthesis conditions with an alcohol-synthesis catalyst, thereby generating mixed alcohols; and purifying the mixed alcohols to generate a mixed-alcohol product. The mixed-alcohol product may be blended with a hydrocarbon fuel, such as gasoline, to produce a blended fuel. The blended fuel has significantly lower carbon intensity than the base hydrocarbon fuel.
BIOGAS CONVERSION TO MIXED ALCOHOLS
Some variations provide a process for producing mixed alcohols, comprising: purifying a biogas feedstock to generate a renewable natural gas stream comprising methane; introducing the renewable natural gas stream into a methane-to-syngas unit operated at effective conditions to convert the methane to a first syngas stream containing at least H.sub.2, CO, and CO.sub.2; purifying the first syngas stream, including separating the CO.sub.2 from the first syngas stream, and optionally separating some of the H.sub.2 from the first syngas stream, thereby generating a clean syngas stream; introducing the clean syngas stream into a mixed-alcohol reactor operated at effective alcohol synthesis conditions with an alcohol-synthesis catalyst, thereby generating mixed alcohols; and purifying the mixed alcohols to generate a mixed-alcohol product. The mixed-alcohol product may be blended with a hydrocarbon fuel, such as gasoline, to produce a blended fuel. The blended fuel has significantly lower carbon intensity than the base hydrocarbon fuel.
INTEGRATED METHODS FOR CHEMICAL SYNTHESIS
The integrated processes herein provide improved carbon efficiency for processes based on coal or biomass gasification or steam methane reforming. Provided are also ethylene oxide carbonylation products such as beta-propiolactone and succinic anhydride having a bio-based content between 0% and 100%, and methods for producing and analyzing the same.
APPARATUS, METHOD, AND RCORDING MEDIUM
Provided is an apparatus for generating a operation plan of a hydrogen production system comprising a hydrogen production apparatus, comprising: a demand predicting unit for generating a predicted demand amount for each of a plurality of types of hydrogen with a different environmental load of production over a target period of the operation plan; and an operation planning unit for generating the operation plan, which is for generating a plurality of types of hydrogen with a different environmental load of production by the hydrogen production apparatus, based on a predicted hydrogen demand amount of each of the plurality of types of hydrogen.
CO2 UTILIZATION IN MOLTEN SALT REACTOR (MSR) FOR ULTRA ENERGY EFFICIENCY AND REDUCED EMISSIONS
A system for a carbon neutral cycle of gas production may include a molten salt reactor configured to generate zero carbon dioxide (CO.sub.2) emissions electricity. The system may include a desalination unit configured to receive the zero-CO.sub.2 emissions electricity from the molten salt reactor and produce a desalinated water. The system may include an electrolysis unit configured to be powered by the zero-CO2 emissions electricity generated by the molten salt reactor and generate hydrogen (H.sub.2) and oxygen (O.sub.2) from the desalinated water. The system may include an oxy-combustion unit configured to receive and combust a hydrocarbon fuel with the O.sub.2 from the electrolysis unit to produce electricity and CO.sub.2. The system may include a CO.sub.2 capture system adapted to capture the CO.sub.2 produced by the oxy-combustion unit and a catalytic hydrogenation unit configured to receive and convert H.sub.2 from the electrolysis unit and CO.sub.2 from the CO.sub.2 capture system to produce the hydrocarbon fuel.
HYDROGEN SULFIDE ADSORBENT IN BIOGAS AND BIOGAS PURIFICATION SYSTEM USING THE SAME
Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.
HYDROGEN SULFIDE ADSORBENT IN BIOGAS AND BIOGAS PURIFICATION SYSTEM USING THE SAME
Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.
HYDROGEN PURIFICATION DEVICES
Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure.