Provided is a hydrogen generating apparatus adaptable to fluctuating hydrogen demand, particularly by enabling large-scale hydrogen production, generating pure hydrogen at a high yield. The hydrogen generating apparatus 1 includes a tabular dielectric body 2 having a first surface 11 with a source gas flow channel 13 formed as a recess and a second surface 12 approximately parallel to the first surface 11, a grounding electrode 3, a hydrogen flow channel plate 4 with a hydrogen flow channel 18 and a hydrogen outlet 19, being arranged on a first surface 11 side of dielectric body 2, a hydrogen separation membrane 5 between source gas flow channel 13 and hydrogen flow channel 18, and a high-voltage power supply 6 that causes electric discharge in source gas flow channel 13 between hydrogen separation membrane 5 and grounding electrode 3. Hydrogen separation membrane 5 transmits hydrogen generated by electric discharge in source gas flow channel 13 into hydrogen flow channel 18.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

Hydrogen generation assemblies, hydrogen purification devices, and their components are disclosed. In some embodiments, the devices may include a permeate frame with a membrane support structure having first and second membrane support plates that are free from perforations and that include a plurality of microgrooves configured to provide flow channels for at least part of the permeate stream. In some embodiments, the assemblies may include a return conduit fluidly connecting a buffer tank and a reformate conduit, a return valve assembly configured to manage flow in the return conduit, and a control assembly configured to operate a fuel processing assembly between run and standby modes based, at least in part, on detected pressure in the buffer tank and configured to direct the return valve assembly to allow product hydrogen stream to flow from the buffer tank to the reformate conduit when the fuel processing assembly is in the standby mode.

A hydrogen permeation membrane is provided that can include a carbon-based material (C) and a ceramic material (BZCYT) mixed together. The carbon-based material can include graphene, graphite, carbon nanotubes, or a combination thereof. The ceramic material can have the formula BaZr.sub.1-x-y-zCe.sub.xY.sub.yT.sub.zO.sub.3-?, where 0?x?0.5, 0?y?0.5, 0?z?0.5, (x+y+z)>0; 0???0.5, and T is Yb, Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, or a combination thereof. In addition, the BZYCT can be present in the C-BZCYT mixture in an amount ranging from about 40% by volume to about 80% by volume. Further, a method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.

In some implementations, a system for producing hydrogen and oxygen from water includes a target, an oxygen selective membrane, a cooling chamber, and a hydrogen selective membrane. The target heats to at least a temperature that thermally decomposes water, receives water vapor, heats the received water vapor to the temperature that thermally decomposes water to form a heated vapor, and passes the heated vapor to an oxygen selective membrane. The oxygen selective membrane separates, at or near the temperature that thermally decomposes water, oxygen from the heated vapor to form a hydrogen-rich vapor. The cooling chamber cools the hydrogen-rich vapor to at least a specified temperature. The hydrogen selective membrane separates hydrogen in the hydrogen-rich vapor to leave substantially water vapor.

An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.

An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.

An industrial, commercial and residential Hydrogen production and conversion system is provided. The Hydrogen production and conversion system includes a reactor vessel for facilitating the production of Hydrogen gas and Oxygen gas, a separator vessel for separating the produced Hydrogen and Oxygen gas, a Hydrogen receiver vessel for receiving the separated Hydrogen gas, a compressor for compressing the received Hydrogen gas and a Hydrogen storage vessel for storing the compressed Hydrogen gas and providing the stored Hydrogen gas to one or more power systems to be used as fuel.

The present invention relates to a process for forming a bio-derived hydrogen gas from a biomass feedstock, and the bio-derived hydrogen gas formed therefrom. The present invention also relates to the use of a bio-derived hydrogen gas in fuel cells, petroleum refining and in forming bio-derived ammonia and methane.

Hydrogen-producing fuel processing systems and related methods. The systems include a hydrogen-producing region configured to produce a mixed gas stream from a feedstock stream, a hydrogen-separation membrane module having at least one hydrogen-selective membrane and configured to separate the mixed gas stream into a product hydrogen stream and a byproduct stream, and an oxidant delivery system configured to deliver an oxidant-containing stream to the hydrogen-separation membrane module in situ to increase hydrogen permeance of the hydrogen-selective membrane. The methods include operating a hydrogen-producing fuel processing system in a hydrogen-producing regime, and subsequently operating the hydrogen-producing fuel processing system in a restoration regime, in which an oxidant-containing stream is delivered to the hydrogen-separation membrane module in situ to expose the at least one hydrogen-selective membrane to the oxidant-containing stream to increase the hydrogen permeance of the at least one hydrogen-selective membrane.