Provided is a porous composite membrane including graphene oxide sheets; nanoparticles bound to a surface of the graphene oxide sheets solely by electrostatic and/or Van der Waals interactions. The present invention also relates to a method of producing the porous composite membrane, a gas separation system including the porous composite membrane, and uses of the porous composite membrane in a process for separating H.sub.2 from a gas stream and a process for reducing H.sub.2O swelling in a graphene oxide-based membrane.

A power generation system, includes: a fuel cell that includes a negative electrode and a positive electrode and is configured to generate electric power by chemical reaction between hydrogen and oxygen; a separator that includes a hydrogen-permselective separation membrane and is configured to obtain permeated gas and non-permeated gas from mixed gas; and a negative electrode gas supply passage configured to supply the mixed gas containing hydrogen to the separator and supply the permeated gas obtained by the separator to the negative electrode. The separation membrane includes a porous support layer and a separation functional layer provided on the porous support layer. The separation functional layer contains at least one kind of chemical compound selected from the group consisting of polyamide, graphene, MOF (Metal Organic Framework), and COF (Covalent Organic Framework).

A power generation system, includes: a fuel cell that includes a negative electrode supplied with hydrogen-containing gas and a positive electrode supplied with oxygen-containing gas, and is configured to generate electric power by chemical reaction between hydrogen and oxygen; a separator that includes a hydrogen-permselective separation membrane and is configured to obtain permeated gas and non-permeated gas from mixed gas; and a circulating passage through which negative electrode-side exhaust gas of the fuel cell is sent to the separator, and through which the permeated gas is supplied to the negative electrode. The separation membrane includes a porous support layer and a separation functional layer provided on the porous support layer. The separation functional layer contains at least one kind of chemical compound selected from the group consisting of polyamide, graphene, MOF (Metal Organic Framework), and COF (Covalent Organic Framework).

Integrated process comprising: synthesis of methanol from a methanol synthesis gas (12); synthesis of ammonia from an ammonia make-up gas (25), and synthesis of carbon monoxide from a methane-containing stream, wherein: the synthesis of methanol provides a liquid stream of methanol (13) and a gaseous stream (14) of unreacted synthesis gas; a portion (14a) of said gaseous stream is separated as purge gas; said purge gas is subjected to a hydrogen recovery step, providing a hydrogen-containing stream (19) which is used as a hydrogen source for making the ammonia make-up gas, and a tail gas (20) which is used as a methane source for the synthesis of carbon monoxide by oxidation of a methane-containing stream.

Membrane-based hydrogen purifiers having graphite frame members. The purifiers include a hydrogen-separation membrane module with at least one membrane cell containing at least one hydrogen-selective membrane, which includes a permeate face and an opposed mixed gas face, and a fluid-permeable support structure that physically contacts and supports at least a central region of the permeate face. The membrane cell further includes a permeate-side frame member and a mixed gas-side frame member. The permeate-side frame member is interposed between the hydrogen-selective membrane and the fluid-permeable support structure to physically contact a peripheral region of the permeate face and a peripheral region of the fluid-permeable support structure. The mixed gas-side frame member physically contacts a peripheral region of the mixed gas face. At least one of the permeate-side frame member and the mixed gas-side frame member is a graphite frame member.

Hydrogen-producing fuel processing systems and related methods. The systems include a hydrogen-producing region configured to produce a mixed gas stream from a feedstock stream, a hydrogen-separation membrane module having at least one hydrogen-selective membrane and configured to separate the mixed gas stream into a product hydrogen stream and a byproduct stream, and an oxidant delivery system configured to deliver an oxidant-containing stream to the hydrogen-separation membrane module in situ to increase hydrogen permeance of the hydrogen-selective membrane. The methods include operating a hydrogen-producing fuel processing system in a hydrogen-producing regime, and subsequently operating the hydrogen-producing fuel processing system in a restoration regime, in which an oxidant-containing stream is delivered to the hydrogen-separation membrane module in situ to expose the at least one hydrogen-selective membrane to the oxidant-containing stream to increase the hydrogen permeance of the at least one hydrogen-selective membrane.

A liquid fuel synthesis system includes a liquid fuel synthesis portion and a sweep gas supply unit. The liquid fuel synthesis portion is partitioned into a non-permeation side space and a permeation side space by the separation membrane. A temperature of the sweep gas flowing into the permeation side space is higher than at least one of a temperature of the raw material gas flowing into the non-permeation side space and a temperature of a first outflow gas flowing out of the non-permeation side space. A temperature of a second outflow gas flowing out of the permeation side space is higher than at least one of the temperature of the raw material gas flowing into the non-permeation side space and the temperature of the first outflow gas flowing out of the non-permeation side space.

The present invention relates to a system and method for separating and recovering hydrogen from coke oven gas (COG) in steel industry, particularly a system and method for separating and recovering hydrogen at a concentration of 99.9% by volume or more from coke oven gas (COG) in steel industry with a recovery rate of 95% or more.

The present specification discloses a membrane reactor comprising a reaction region; a permeate region; and a composite membrane disposed at a boundary of the reaction region and the permeate region, wherein the reaction region comprises a bed filled with a catalyst for dehydrogenation reaction, wherein the composite membrane comprises a support layer including a metal with a body-centered-cubic (BCC) crystal structure, and a catalyst layer including a palladium (Pd) or a palladium alloy formed onto the support layer, wherein ammonia (NH.sub.3) is supplied to the reaction region, the ammonia is converted into hydrogen (H.sub.2) by the dehydrogenation reaction in the presence of the catalyst for dehydrogenation reaction, and the hydrogen permeates the composite membrane and is emitted from the membrane reactor through the permeate region.

A gas separation membrane module includes a center pipe; a plurality of separation membranes each having a feed surface and a permeate surface, the separation membranes arranged such that the feed surfaces face each other and the permeate surfaces face each other; a feed channel material arranged between the feed surfaces; and a permeate channel material arranged between the permeate surfaces, wherein the separation membranes, the feed channel material, and the permeate channel material are wound around the center pipe, an average pore size on a front surface and an average pore size on a back surface of the feed channel material are each 0.95 mm or less, and an average pore size on a front surface and an averaged pore size on a back surface of the permeate channel material are each 0.95 mm or less.