Patent classifications
C01B7/04
Catalyst For Preparing Chlorine Gas By Hydrogen Chloride Oxidation, And Preparation Method And Application Thereof
A catalyst for preparing chlorine gas by hydrogen chloride oxidation, comprising the following components calculated according to mass content based on the total weight of the catalyst: 0.5-20 wt % copper; 2-10 wt % manganese; 0.05-2 wt % boron; 0.01-3 wt % chromium; 0.1-10 wt % rare earth metal; 0.1-10 wt % potassium; and 3-15 wt % titanium; also comprising 0.02-1.1 wt % phosphorus; and 0.03-1.9 wt % iron; the carrier content is 55-90 wt %. In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80-85%. Almost all of the 0-1000 mg/kg of chlorinated benzene contained in hydrogen chloride gas can be converted into CO.sub.2 and H.sub.2O without generating polychlorinated benzene.
METHOD FOR PRODUCING CHLORINE BY OXIDATION OF HYDROGEN CHLORIDE
The method for producing chlorine by oxidation of hydrogen chloride with oxygen in the presence of a catalyst in a fixed-bed reactor, wherein [I] a material containing hydrogen chloride and oxygen is allowed to contact a catalyst in a temperature range of 280 to 370 C., and [II] the material containing hydrogen chloride and oxygen has an oxygen concentration of 45 to 75 vol %.
METHOD FOR PRODUCING CHLORINE BY OXIDATION OF HYDROGEN CHLORIDE
The method for producing chlorine by oxidation of hydrogen chloride with oxygen in the presence of a catalyst in a fixed-bed reactor, wherein [I] a material containing hydrogen chloride and oxygen is allowed to contact a catalyst in a temperature range of 280 to 370 C., and [II] the material containing hydrogen chloride and oxygen has an oxygen concentration of 45 to 75 vol %.
PHOTOCATALYTIC OXIDATION OF HYDROGEN CHLORIDE WITH OXYGEN
The invention relates to a method for the production of chlorine by means of photocatalytic oxidation of gaseous hydrogen chloride with oxygen as an oxidizing agent, in which the reaction is started on the surface of a photocatalyst by the action of UV radiation in a selective energy range.
PHOTOCATALYTIC OXIDATION OF HYDROGEN CHLORIDE WITH OXYGEN
The invention relates to a method for the production of chlorine by means of photocatalytic oxidation of gaseous hydrogen chloride with oxygen as an oxidizing agent, in which the reaction is started on the surface of a photocatalyst by the action of UV radiation in a selective energy range.
Method for processing hydrogen chloride from isocyanate preparation
A method for processing hydrogen chloride from isocyanate preparation comprises the steps: a) providing hydrogen chloride; b) purifying the hydrogen chloride provided; and furthermore step c) or step d): c) bringing the purified hydrogen chloride into contact with water and/or with hydrochloric acid which is not saturated with respect to uptake of hydrogen chloride, d) further processing the purified hydrogen chloride to chlorine by partial oxidation. The hydrogen chloride provided in step a) contains organic and/or nitrogen-containing impurities and in step b) the purification is carried out by bringing hydrogen chloride into contact with hydrochloric acid which is saturated to the extent of 90% with respect to uptake of hydrogen chloride at least in a first gas scrubber (10) and circulating this hydrochloric acid at least partially through the first gas scrubber (10).
Method for processing hydrogen chloride from isocyanate preparation
A method for processing hydrogen chloride from isocyanate preparation comprises the steps: a) providing hydrogen chloride; b) purifying the hydrogen chloride provided; and furthermore step c) or step d): c) bringing the purified hydrogen chloride into contact with water and/or with hydrochloric acid which is not saturated with respect to uptake of hydrogen chloride, d) further processing the purified hydrogen chloride to chlorine by partial oxidation. The hydrogen chloride provided in step a) contains organic and/or nitrogen-containing impurities and in step b) the purification is carried out by bringing hydrogen chloride into contact with hydrochloric acid which is saturated to the extent of 90% with respect to uptake of hydrogen chloride at least in a first gas scrubber (10) and circulating this hydrochloric acid at least partially through the first gas scrubber (10).
PROCESS FOR PREPARING CHLORINE
The present invention relates to a continuous process for preparing chlorine and a production unit for carrying out said process. The present invention further relates to a use of said production unit for the continuous production of chlorine.
PROCESS FOR PREPARING CHLORINE
The present invention relates to a continuous process for preparing chlorine and a production unit for carrying out said process. The present invention further relates to a use of said production unit for the continuous production of chlorine.
Method for preparing chlorine gas through catalytic oxidation of hydrogen chloride
A method for preparing chlorine gas through catalytic oxidation of hydrogen chloride is carried out by one-time hydrogen chloride feeding and multi-stage oxygen feeding, one-time oxygen feeding and multi-stage hydrogen chloride feeding, or both, returning a product gas stream without separation thereof, and optionally carrying out heat insulation means. In the present invention, excessive reaction heat concentration is prevented, therefore, the method of the present invention is a chlorine gas recovery method implemented through the Deacon catalytic oxidation of hydrogen chloride that may be industrialized.