The invention concerns a method for treating a hydrocarbon feed gas stream containing at least CO.sub.2 and H.sub.2S to recover a high quality purified CO.sub.2 gas stream, comprising a. Separating said hydrocarbon feed gas stream into a sweetened hydrocarbon gas stream, and an acid gas stream; b. Introducing said gas stream into a Claus unit, c. Introducing the tail gas into a hydrogenation reactor and then into a quench contactor of the Tail Gas Treatment Unit (TGTU); d. Contacting said tail gas stream with a non-selective amine-based solvent into a non-selective acid gas absorption unit of the TGTU; e. Sending the off gas to an incinerator; f. Contacting said enriched gas stream (vii) with a selective H.sub.2S-absorption solvent into a selective H.sub.2S-absorption unit thereby recovering a highly purified CO.sub.2 gas stream and a H.sub.2S-enriched gas stream, as well as the device for carrying said method.

A method to recover sulfur comprising the steps of feeding an acid gas stream to a combustion furnace, condensing the cooled furnace stream to produce a first gas stream, feeding the first gas stream to a first adsorber comprises a molecular sieve, feeding the first hot dry gas stream to a first catalytic reactor, cooling the first catalytic outlet stream in a first condenser, feeding the second gas stream to a second adsorber, feeding the second hot dry gas stream to a second catalytic reactor, cooling the second catalytic outlet stream in a second condenser, introducing the third gas stream to a third adsorber, feeding the third hot dry gas stream to a third catalytic reactor to produce a third catalytic outlet stream, and cooling the third catalytic outlet stream in a third condenser to produce a third sulfur stream and a tail gas stream.

A method to recover sulfur comprising the steps of feeding an acid gas stream to a combustion furnace, condensing the cooled furnace stream to produce a first gas stream, feeding the first gas stream to a first adsorber comprises a molecular sieve, feeding the first hot dry gas stream to a first catalytic reactor, cooling the first catalytic outlet stream in a first condenser, feeding the second gas stream to a second adsorber, feeding the second hot dry gas stream to a second catalytic reactor, cooling the second catalytic outlet stream in a second condenser, introducing the third gas stream to a third adsorber, feeding the third hot dry gas stream to a third catalytic reactor to produce a third catalytic outlet stream, and cooling the third catalytic outlet stream in a third condenser to produce a third sulfur stream and a tail gas stream.

A process for removing sulphur dioxide from the gaseous effluent of a smelter furnace comprising the steps of: providing the gaseous effluent from a smelter; separating the sulphur dioxide from the gaseous effluent to provide concentrated sulphur dioxide and effluent for discharge into the atmosphere; mixing the concentrated sulphur dioxide with a fuel gas; heating the mixture such that the concentrated sulphur dioxide and fuel gas react to form a gaseous product mixture comprising sulphur and hydrogen sulphide; and removing the majority of preferably substantially all of the sulphur and hydrogen sulphide from the gaseous product mixture; wherein the remaining gaseous product mixture is incinerated before being vented into the atmosphere or is recycled into the smelter furnace.

An elemental sulfur recovery unit comprising a thermal unit configured to combust an acid gas feed comprising hydrogen sulfide, an oxygen source, and a fuel gas to create a reaction furnace outlet stream, comprising elemental sulfur, a waste heat boiler configured to capture heat from the reaction furnace outlet stream to create a waste heat boiler effluent, a condenser configured to condense the waste heat boiler effluent to produce a non-condensed gases stream and a condensed stream comprising elemental sulfur, a process gas reheater configured to generate a hot gases stream, a hydrogenation reactor configured to convert the hot gases stream to create a hydrogenation effluent comprising hydrogen sulfide, a process desuperheater configured to cool the hydrogenation effluent to generate a cooled effluent, and an absorber unit configured to absorb the hydrogen sulfide from the cooled effluent to produce a hydrogen sulfide recycle stream and a waste gas stream.

A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes: supplying the hydrocarbon feedstock to an oxidation reactor, where the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; collecting a residue stream that includes oxidized sulfur compounds; supplying a residue stream that includes oxidized sulfur compounds; supplying the residue stream to a gasifier to produce a syngas stream and a hydrogen sulfide stream; supplying the extracted hydrocarbon stream to a stripper to produce a stripped oil stream, which is then supplied to an adsorption column, such that the adsorption column can produce a high purity hydrocarbon product stream, a second residue stream, and a spent adsorbent stream, the spent adsorbent stream containing another portion of the oxidized compounds; and supplying the spent adsorbent stream to the gasifier to produce additional syngas for the syngas stream, thereby disposing of the adsorbent.

Contemplated systems and methods for removing polysulfides and hydrogen sulfide from liquid sulfur of a Claus plant include (a) physically separated steps of catalytic decomposition of polysulfides and gas stripping, or (b) use of the stripping gas as the continuous phase in a packed column with decomposition catalyst to so avoid catalyst attrition.

Systems and methods for separating hydrogen sulfide from carbon dioxide in a high-pressure mixed stream are disclosed herein. The methods include receiving the high-pressure mixed stream in an oxidation reactor and at an inlet pressure of at least 0.3 megapascals. The high-pressure mixed stream includes 0.01 to 5 mole percent hydrogen sulfide and at least 90 mole percent carbon dioxide. The methods further include oxidizing the high-pressure mixed stream with an oxidant to generate a high-pressure oxidized stream, includes oxidized hydrogen sulfide and carbon dioxide, at an oxidation pressure of at least 0.3 megapascals. The methods also include separating the high-pressure oxidized stream into an oxidized hydrogen sulfide product and a carbon dioxide product and generating the carbon dioxide product at a pressure of at least 0.3 megapascals. The systems include the high-pressure mixed stream, an oxidation reactor, and a separation assembly.

A sour gas stream is sub-stoichiometrically combusted to produce soot and a sour syngas stream. At least 10% of the carbon in the sour gas stream is converted into the soot. At least a portion of the hydrogen sulfide of the sour syngas stream is reacted with sulfur dioxide to produce a syngas stream comprising the carbon dioxide, the carbon monoxide, the hydrogen, water, elemental sulfur vapor, a residual portion of the hydrogen sulfide, and a residual portion of the sulfur dioxide. The syngas stream is reacted with steam to produce a shifted sour gas stream including more carbon dioxide, more hydrogen, more hydrogen sulfide, and less carbon monoxide in comparison to the syngas stream. Water and hydrogen sulfide is separated from the shifted sour gas stream to produce a sweet gas stream. The sweet gas stream is separated into a hydrogen product stream and an exhaust stream.

Methods and apparatuses for separating CO.sub.2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.