Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

A process for oxidizing a sulfur stream includes supplying at least one sulfur stream into a furnace; supplying oxygen-enriched combustion air into the furnace; separately supplying pure oxygen into the furnace; and at least partially oxidizing the at least one sulfur stream in the furnace. A related apparatus is also provided and includes a furnace; an inlet for supplying at least one sulfur stream into the furnace; an inlet for supplying a stream of an oxygen-enriched combustion air into the furnace; and an inlet for supplying a pure oxygen stream into the furnace separately from the supplying of the oxygen-enriched combustion air.

A process for oxidizing a sulfur stream includes supplying at least one sulfur stream into a furnace; supplying oxygen-enriched combustion air into the furnace; separately supplying pure oxygen into the furnace; and at least partially oxidizing the at least one sulfur stream in the furnace. A related apparatus is also provided and includes a furnace; an inlet for supplying at least one sulfur stream into the furnace; an inlet for supplying a stream of an oxygen-enriched combustion air into the furnace; and an inlet for supplying a pure oxygen stream into the furnace separately from the supplying of the oxygen-enriched combustion air.