A method for producing a metal nitride and/or a metal carbide, a metal nitride and/or metal carbide optionally produced according to the method, and the use of the metal nitride and/or carbide in catalysis optionally catalytic hydroprocessing. Optionally, the method comprises: i) contacting at least one metal oxide comprising at least one first metal M.sup.1 with a cyanometallate comprising at least one second metal M.sup.2 to form a reaction mixture; and, ii) subjecting the reaction mixture to a temperature of at least 300 C. for a reaction period. Optionally, the metal nitride and/or metal carbide is a metal nitride comprising tungsten nitride.

A molybdenum compound is represented by a general formula MoX.sub.a (in the formula, X is a Group 14 element, a Group 15 element, or a Group 16 element, and a is 0.5, 1, or 2), has the number of functional groups per unit area of 10 per nm.sup.2 or less when X is the Group 14 element in the general formula MoX.sub.a, has the number of functional groups per unit area of 100 per nm2 or less when X is the Group 15 element or the Group 16 element in the general formula MoXa, and has a particle diameter of 10 nm or more and less than 1,000 nm.

The present invention provides a method for recycling waste cemented carbide by molten salt chemistry, comprising the steps of: (1) carrying out vacuum dehydration on a molten salt media; (2) carrying out oxidation-dissolution reaction on waste cemented carbide in the molten salt media; (3) carrying out deoxidation treatment on a molten salt system; (4) carrying out thermal reduction reaction on the molten salt system; and (5) washing, filtering and vacuum drying obtained mixture by thermal reduction reaction to carry out separation and collection of the molten salt media and waste cemented carbide nanopowder. Compared with existing method for recycling waste cemented carbide, the invention has the advantages of short flow, simple equipment, low energy consumption, and excellent recycled products. Moreover, the invention doesn't produce solid/gas/liquid harmful substances to pollute the environment, and can create enormous economic and social benefits.

The present invention provides a method for recycling waste cemented carbide by molten salt chemistry, comprising the steps of: (1) carrying out vacuum dehydration on a molten salt media; (2) carrying out oxidation-dissolution reaction on waste cemented carbide in the molten salt media; (3) carrying out deoxidation treatment on a molten salt system; (4) carrying out thermal reduction reaction on the molten salt system; and (5) washing, filtering and vacuum drying obtained mixture by thermal reduction reaction to carry out separation and collection of the molten salt media and waste cemented carbide nanopowder. Compared with existing method for recycling waste cemented carbide, the invention has the advantages of short flow, simple equipment, low energy consumption, and excellent recycled products. Moreover, the invention doesn't produce solid/gas/liquid harmful substances to pollute the environment, and can create enormous economic and social benefits.

An aqueous solution composition contains more than or equal to 10 mass % and less than or equal to 30 mass % of tungstate ions relative to 1 kg of water, more than or equal to 0.05 mass % and less than or equal to 5 mass % of transition metal ions relative to 1 kg of water, and a remainder of counter anions and water. The transition metal ions include cobalt ions. The counter anions include organic acid ions. The organic acid ions are multidentate ligands.

The present invention(s) is directed to novel conductive M.sub.n+1X.sub.n(T.sub.s) compositions exhibiting high volumetric capacitances, and methods of making the same. The present invention(s) is also directed to novel conductive M.sub.n+1X.sub.n(T.sub.s) compositions, methods of preparing transparent conductors using these materials, and products derived from these methods.

The present invention(s) is directed to novel conductive M.sub.n+1X.sub.n(T.sub.s) compositions exhibiting high volumetric capacitances, and methods of making the same. The present invention(s) is also directed to novel conductive M.sub.n+1X.sub.n(T.sub.s) compositions, methods of preparing transparent conductors using these materials, and products derived from these methods.

A method that uses a pressurized reactive medium composed of inert solvents such as pressurized liquid or supercritical fluid carbon dioxide (C02), and sulfur hexafluoride (SF6) and reactive dissolved species ozone (03) and/or boron trifluoride (BF3) and general boron trihalogenides (BX3) to react with two-dimensional (2D) layered materials and thereby synthesize covalently oxygen and/or BX3 functionalized exfoliated 2D layered materials. When 2D layered materials are dispersed in these reactive liquids or fluids by ultrasound sonication or high shear mixing, a simultaneous covalent functionalization and exfoliation of the 2D layered materials happens. Following attainment of the required extent of functionalization and exfoliation, the unreacted 03, BX3, SF6 and C02 can be easily removed as gases by decompression leaving behind the solid phase, thereby leading to efficient and economical production of functionalized and exfoliated 2D layered materials.

An aligned film having first and second faces opposed to each other, the aligned film having (a) a plurality of layers aligned non-parallel to the first and second faces between the faces of the aligned film, each layer having a crystal lattice represented by: M.sub.n+1X.sub.n (wherein M is at least one metal of Group 3, 4, 5, 6, or 7; X is a carbon atom, a nitrogen atom, or a combination thereof; and n is 1, 2, or 3), each X is positioned within an octahedral array of M, and at least one of two opposing surfaces of each said layer have at least one modifier or terminal T selected from a hydroxy group, a fluorine atom, an oxygen atom, and a hydrogen atom; and (b) magnetic nanoparticles carried on a layer surface and/or between two adjacent layers of the plurality of layers.

An aligned film having first and second faces opposed to each other, the aligned film having (a) a plurality of layers aligned non-parallel to the first and second faces between the faces of the aligned film, each layer having a crystal lattice represented by: M.sub.n+1X.sub.n (wherein M is at least one metal of Group 3, 4, 5, 6, or 7; X is a carbon atom, a nitrogen atom, or a combination thereof; and n is 1, 2, or 3), each X is positioned within an octahedral array of M, and at least one of two opposing surfaces of each said layer have at least one modifier or terminal T selected from a hydroxy group, a fluorine atom, an oxygen atom, and a hydrogen atom; and (b) magnetic nanoparticles carried on a layer surface and/or between two adjacent layers of the plurality of layers.