The invention relates to a process for the production of hydrogen-enriched synthesis gas by a catalytic water-gas shift reaction, comprising the steps: introducing a gaseous flow (1) comprising at least one organic sulphide, optionally in its oxide form, in a first reactor (2) comprising a catalyst X.sub.1, collecting a sulfur-containing gaseous flow (3) from the first reactor, introducing the raw synthesis gas (4) in a second reactor (6), introducing the sulfur-containing gaseous flow (3) in the second reactor where the catalytic water-gas shift reaction takes place and comprising a sulfur-resistant shift catalyst X.sub.2, collecting an outlet flow (7) comprising hydrogen-enriched synthesis gas from the second reactor.

The invention also relates to the use of said at least one organic sulphide, optionally in its oxide form, in a process for the production of hydrogen-enriched synthesis gas by a catalytic water-gas shift reaction.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

A modular direct reduction system for producing direct reduced iron (DRI) includes a reformer system which receives a flow of feed gas and which discharges a flow of reducing gas, the reformer system including a plurality of separate reformer modules connected together and wherein each reformer module includes a reformer vessel including an internal chamber, a reactor tube extending through the internal chamber of the reformer vessel and containing a catalyst configured to react with the feed gas received by the reactor tube to form the reducing gas, and a burner to burn a fuel gas to heat the reactor tube, and a furnace system connected to the reformer system and including a furnace having a first inlet which receives an iron ore, a second inlet which receives the reducing gas from the reformer system to form the DRI, and an outlet which discharges the DRI.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

A process and system for generating hydrogen gas are described, in which water is electrolyzed to generate hydrogen and oxygen, and a feedstock including oxygenate(s) and/or hydrocarbon(s), is non-autothermally catalytically oxidatively reformed with oxygen to generate hydrogen. The hydrogen generation system in a specific implementation includes an electrolyzer arranged to receive water and to generate hydrogen and oxygen therefrom, and a non-autothermal segmented adiabatic reactor containing non-autothermal oxidative reforming catalyst, arranged to receive the feedstock, water, and electrolyzer-generated oxygen, for non-autothermal catalytic oxidative reforming reaction to produce hydrogen. The hydrogen generation process and system are particularly advantageous for using bioethanol to produce green hydrogen.

According to one aspect of the invention, a catalyst tower is provided, which comprises a gas inlet and a catalyst holding plate set therein. The gas inlet is the opening where the catalyst tower and the upstream piping connects with one another. The distance between the gas inlet and the catalyst holding plate is directly proportional to the difference in diameter between the catalyst tower and the upstream piping.

H2 production, sulfuric acid and SO2 production process refers to an innovative process VIA the phenomena of the Sulfur-Iodine (S-I) thermochemical cycle. The process consist of the acid gas burner to burn all the acid gases with air, enriched air or oxygen and without using any fuel gas to produce SO2. The acid gases are normally processed in the prior arts of the sulfur recovery units. Iodine is used to produce the hydrogen.

A portion or all of the acid gases are sent to the acid gas burner in accordance with the present invention.

The present innovation not only produces hydrogen but also reduces the SO2 and CO2 emissions.

The produced SO2 is sent to other units to produce other fertilizer products and the produced CO2 is sent to CO2 removal or CO2 Liquefaction process.

The hydrogen is produced is used to supply the needs within the facility like hydrotreaters to reduce external import and to reduce the operating costs.

A novel synthetic crystalline molecular sieve material, designated boron SSZ-121 is provided. The boron SSZ-121 can be synthesized using 1,3-bis(1-adamantyl)imidazolium cations as a structure directing agent. The boron SSZ-121 may be used in organic compound conversion reactions and/or sorptive processes.

A hydrocarbon reforming catalyst that is used in production of a synthesis gas containing hydrogen and carbon monoxide from a hydrocarbon-based gas includes a composite oxide having a perovskite structure, wherein the composite oxide has at least one crystal phase among a first crystal phase containing BaZrO.sub.3 as a main component and a second crystal phase containing BaCeO.sub.3 as a main component, and contains Rh.

Embodiments of apparatuses and methods for reforming of hydrocarbons including recovery of products are provided. In one example, a method comprises separating a reforming-zone effluent into a net gas phase stream and a liquid phase hydrocarbon stream. The net gas phase stream is separated for forming an H.sub.2-rich stream and a first liquid phase hydrocarbon stream. The H.sub.2-rich stream may be contacted with an adsorbent to form an H.sub.2-ultra rich stream and a gas stream. C.sub.3/C.sub.4 hydrocarbons are absorbed from the gas stream with the liquid phase hydrocarbon stream. The gas stream may be contacted with an H.sub.2/hydrocarbon separation membrane to separate the PSA tail gas stream and form an H.sub.2-rich permeate stream and an H.sub.2 depleted non-permeate residue stream.