Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

Improved processes and systems are disclosed for producing renewable hydrogen suitable for reducing metal ores, as well as for producing activated carbon. Some variations provide a process comprising: pyrolyzing biomass to generate a biogenic reagent comprising carbon and a pyrolysis off-gas; converting the pyrolysis off-gas to additional reducing gas and/or heat; reacting at least some of the biogenic reagent with a reactant to generate a reducing gas; and chemically reducing a metal oxide in the presence of the reducing gas. Some variations provide a process for producing renewable hydrogen by biomass pyrolysis to generate a biogenic reagent, conversion of the biogenic reagent to a reducing gas, and separation and recovery of hydrogen from the reducing gas. A reducing-gas composition for reducing a metal oxide is provided, comprising renewable hydrogen according to a hydrogen-isotope analysis. Reacted biogenic reagent may also be recovered as an activated carbon product. Many variations are disclosed.

The invention is directed to a process to prepare a char product and a syngas mixture comprising hydrogen and carbon monoxide from a solid torrefied biomass feed comprising the following steps: (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles; (ii) separating the char particles as the char product from the gaseous fraction; (iii) subjecting the gaseous fraction obtained in step (ii) to a continuously operated partial oxidation to obtain a syngas mixture further comprising water and having an elevated temperature and (iv) contacting the syngas mixture with a carbonaceous compound to chemically quench the syngas mixture. The temperature of the syngas is reduced in step (iv) from between 1000 and 1600° C. to a temperature of between 800 and 1200° C.

Process for the synthesis of ammonia from natural gas comprising conversion of a charge of desulphurized natural gas and steam, with oxygen-enriched air or oxygen, into a synthesis gas, and treatment of the synthesis gas with shift reaction and decarbonation, wherein a part of the CO2-depleted synthesis gas, obtained after decarbonation, is separated and used as fuel fraction for one or more furnaces of the conversion section, and the remaining part of the gas is used to produce ammonia.

A process of partial oxidation is performed in a reactor which includes a reaction chamber and a burner assembly, wherein: the burner assembly has a single oxidant nozzle located within an fuel channel, said oxidant nozzle comprises a nozzle pipe and a nozzle outlet, the nozzle pipe and the fuel channel are arranged to produce a diffusion flame, the nozzle outlet has a shape with two or more elongate lobes projecting from a center of the nozzle pipe.

Systems and methods for direct crude oil upgrading to hydrogen and chemicals including separating an inlet hydrocarbon stream into a light fraction and a heavy fraction comprising diesel boiling point temperature range material; producing from the light fraction syngas comprising H.sub.2 and CO; reacting the CO produced; producing from the heavy fraction and separating CO.sub.2, polymer grade ethylene, polymer grade propylene, C.sub.4 compounds, cracking products, light cycle oils, and heavy cycle oils; collecting and purifying the CO.sub.2 produced from the heavy fraction; processing the C.sub.4 compounds to produce olefinic oligomerate and paraffinic raffinate; separating the cracking products; oligomerizing a light cut naphtha stream; hydrotreating an aromatic stream; hydrocracking the light cycle oils to produce a monoaromatics product stream; gasifying the heavy cycle oils; reacting the CO produced from gasifying the heavy cycle oils; collecting and purifying the CO.sub.2; and processing and separating produced aromatic compounds into benzene and paraxylene.

A method of natural gas treatment including introducing a natural gas containing stream into a dryer unit, thereby producing a treated natural gas containing stream. Introducing the treated natural gas containing stream into a nitrogen rejection unit, thereby producing a further treated natural gas stream as a nitrogen rejection unit product. Splitting the nitrogen rejection unit product into at least two portions, introducing the first portion of the further treated natural gas stream into a reformer unit as first part of feed, and introducing a second portion of the further treated natural gas stream into the dryer unit as a regeneration stream, thereby producing a regeneration waste stream. Introducing at least a portion of the regeneration waste stream into the reformer unit as second part of feed.

A solid oxide cell device is provided which uses hydrocarbon fuel gas and oxygen to remove carbon dioxide from a gas stream, converting it to syngas (carbon monoxide and hydrogen), preferably without any input of external energy beyond that derived from the input gases. Existing processes can then be used to convert the syngas to stable liquid or solid organic chemicals, so that all the input carbon is fixed. Partial oxidation of hydrocarbon fuel gas in a solid oxide fuel cell produces syngas and electricity, and the electricity powers a solid oxide electrolyser which reacts carbon dioxide with further hydrocarbon fuel gas to produce more syngas The fuel cell and electrolyser together can achieve self-sustaining carbon dioxide utilization.

A reactor configuration is proposed for selectively converting gaseous, liquid or solid fuels to a syngas specification which is flexible in terms of H.sub.2/CO ratio. This reactor and system configuration can be used with a specific oxygen carrier to hydro-carbon fuel molar ratio, a specific range of operating temperatures and pressures, and a co-current downward moving bed system. The concept of a CO.sub.2 stream injected in-conjunction with the specified operating parameters for a moving bed reducer is claimed, wherein the injection location in the reactor system is flexible for both steam and CO.sub.2 such that, carbon efficiency of the system is maximized.

The present invention relates to siloxane hydrogen carrier compounds and to a method for producing hydrogen from said siloxane hydrogen carrier compounds.