A hydrogen production apparatus including a photocatalyst and generating hydrogen from water includes a wavelength separation unit separating sunlight by wavelength, an infrared light conversion unit converting infrared light separated by the wavelength separation unit to visible light, and an ultraviolet light conversion unit converting ultraviolet light separated by the wavelength separation unit to visible light.

This disclosure relates to reactor systems and methods of decomposing ammonia. In some aspects, a catalyst reactor includes an elongated conduit extending along a longitudinal axis. The elongated conduit can include a wall defining an interior cavity, an inlet configured for receiving a first fluid, and an outlet to flow the first fluid out of the elongated conduit, the wall having an interior cross-section defined by a major axis, W, and a minor axis, H, the major axis and the minor axis defining an aspect ratio, α=W/H, wherein the aspect ratio is greater than 2.0; and a catalytic structure disposed within the interior cavity of the elongated conduit.

The present disclosure relates to a hydrogen gas production method including: a first step of generating a mixed gas containing hydrogen and carbon dioxide from a hydrogen storage agent by dehydrogenation reaction using a catalyst in a reactor; a second step of purifying the generated mixed gas to acquire a gas having a high hydrogen concentration; a third step of separating a solution in the reactor into a solution enriched with the catalyst and a permeate using a separation membrane unit; and a fourth step of supplying the solution enriched with the catalyst to the reactor for reusing in the first step.

A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

A flow reactor system for providing on-demand H.sub.2 evolution at pressure from a liquid organic hydrogen carrier and/or blends thereof includes a reactor that includes a reaction vessel having an inlet and outlet. The inlet is configured to introduce reactants into the reaction vessel, and the outlet is configured to release reaction products. The reaction vessel is configured to hold therein a catalyst system capable of catalyzing the evolution of molecular hydrogen from a liquid organic hydrogen carrier. Advantageously, the reaction vessel is configured to operate at pressures greater than or equal to 50 psig (e.g., from about 50 psig to about 10500 psig. The flow reactor system also includes a source of preheated liquid organic hydrogen carrier in fluid communication with the reactor and a purification system in fluid communication with the outlet that provides purified molecular hydrogen gas for on-demand applications.

There is provided a membrane comprising: a porous support layer having a first surface and a second surface; a palladium (Pd)-based selective layer on a first surface of the support layer; and a zeolite protective layer on a second surface of the support layer, wherein the support layer is between the Pd-based selective layer and the zeolite protective layer. There is also provided a method of forming the same.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.

Here disclosed is a composite catalyst for methane cracking and a method of producing the composite catalyst. The composite catalyst includes a substrate formed of metal oxide, and one or more catalytic transition metals solubilized in the metal oxide, wherein the metal oxide includes a metal which differs from the one or more catalytic transition metals, wherein the metal oxide forms a matrix which the one or more catalytic transition metals are solubilized in to render transition metal ions from the one or more catalytic transition metals, wherein the transition metal ions under a reducing atmosphere diffuse to reside as transition metal nanoparticles at a surface of the substrate and the transition metal nanoparticles under an oxidizing atmosphere diffuse away from the surface to reside as transition metal ions in the metal oxide, and wherein the transition metal nanoparticles at the surface induce carbon from the methane cracking to deposit on the transition metal nanoparticles and have the carbon deposited grow away from the substrate.

The present invention describes a processes, systems, and catalysts for the utilization of carbon dioxide into high quality synthesis gas that can then be used to produce fuels (e.g., diesel fuel) and chemicals. In one aspect, the present invention provides a process for the conversion of a feed gas comprising carbon dioxide and hydrogen to a product gas comprising carbon monoxide and water.

The present disclosure provides systems and methods for processing ammonia. The system may comprise one or more reactor modules configured to generate hydrogen from a source material comprising ammonia. The hydrogen generated by the one or more reactor modules may be used to provide additional heating of the reactor modules (e.g., via combustion of the hydrogen), or may be provided to one or more fuel cells for the generation of electrical energy.