An autothermal reforming catalytic structure for generating hydrogen gas from liquid hydrocarbons, steam and an oxygen source. The autothermal reforming catalytic structure includes a support structure and nanosized mixed metal oxide particles dispersed homogenously throughout the support structure.

A syngas generator is disclosed as an exothermic gas generator that can accommodate high combustion temperatures of a natural gas/oxygen flame. The generator includes four sections: a heavily insulated combustion chamber, a catalyst chamber, a spray chamber, and a heat exchanger. These four sections may be arranged in series and tightly bolted together to form a gas-tight system. Natural gas, oxygen and steam are supplied to a burner at the inlet end of the combustion chamber. This mixture is ignited and the resulting hot process gas is then fed into a catalyst bed where it reacts with the steam and is converted to carbon monoxide and hydrogen (syngas). The syngas is fed to a Fischer-Tropsch unit to create liquid fuel.

A bimetal oxysulfide solid-solution catalyst is provided. The bimetal oxysulfide solid-solution catalyst is represented by the following formula:
Cu.sub.xM.sup.(2).sub.yO.sub.zS.sub.γ wherein M.sup.(2) includes monovalent Silver (Ag), divalent Zinc (Zn), Manganese (Mn), Nickel (Ni), Cobalt (Co), and Tin (Sn.sup.II), trivalent Indium (In), Cerium (Ce), Antimony (Sb), and Gallium (Ga), tetravalent Tin (Sn.sup.IV), or pentavalent Molybdenum (Mo), 0<y<0.3, 0.7<x<1.0, 0<z<0.5, and 0.5<γ<1.0. In addition, a manufacturing method of the bimetal oxysulfide solid-solution catalyst and applications of the bimetal oxysulfide solid-solution catalyst are also provided.

A mesoporous metal doped cerium oxide catalyst is provided. The catalyst can contain nanotextured cerium oxide (CeO.sub.2) which can be utilized for hydrogen production or reformate gas purification in a water gas shift reaction. The catalyst may be advantageously used to remove CO from a gas containing CO. The catalyst may also be incorporated into a fuel processor.

Methods, reactor tubes, reactors, and systems for catalysis are disclosed. A reactor tube includes an outer shell defining a catalyst bed, a catalyst within the catalyst bed, and an inner tube extending through the catalyst bed. An interior of the inner tube is isolated from the catalyst within the catalyst bed. Methods of activating a catalyst are also disclosed herein.

The present invention relates to a steam reforming catalyst for hydrogen production. More specifically, the present invention provides a novel catalysts support for sustainable hydrogen production by steam reforming process using bio-based materials feedstock such as ethanol, glycerol, n-butanol and ethylene glycol. The said improved support catalyst and metal doped catalysts therefrom, are comprising of combination of crystalline Mesoporous cellular foam (MCF) silica and basic site assistant for enhancing catalytic activity of doped active metals thereon and lower coke formation. The benefits of present invention is in the cost efficient steam reforming process for hydrogen production, wherein the said catalysts are efficiently providing a high reactant conversion at lower temperature, no coke formation, high thermal stability for longer time and effective catalytic performance for multiple cycles.

A plant and process for producing a hydrogen rich gas are provided, said process comprising the steps of: reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O; shifting said synthesis gas in a shift configuration including a high temperature shift step; removal of CO.sub.2 upstream hydrogen purification unit, such as a pressure swing adsorption unit (PSA), and recycling off-gas from hydrogen purification unit and mix it with natural gas upstream prereformer feed preheater, prereformer, reformer feed preheater or ATR or shift as feed for the process.

A catalyst suitable for use in carbon oxide conversion reactions is described, said catalyst in the form of a shaped unit formed from an oxidic catalyst powder, said catalyst comprising 30-70% by weight of copper oxide, combined with zinc oxide, alumina and silica, having a Si:AI atomic ratio in the range 0.005 to 0.15:1, and having a BET surface area >105 m.sup.2/g and a copper surface area >37 m.sup.2/g catalyst. The catalyst is prepared by a co-precipitation method using an alumina sol.

The invention is in the field of catalysis. In particular, the invention is directed to a catalytic reactor body, a method for the production of a catalytic reactor body and a use of a catalytic reactor body.

The invention provides a catalytic reactor body, comprising a circumferential reactor wall extending in a main fluid flow direction of the reactor body between a reactor inlet and a reactor outlet thereby forming a channel for conducting a fluid; and a reactor bed arranged in the channel and being integrally formed with the circumferential reactor wall, wherein the reactor bed forms a plurality of sub-channels for guiding the fluid from the reactor inlet to the reactor outlet, each sub-channel defining a predetermined fluid path between the reactor inlet and the reactor outlet and being configured for directing the fluid in a direction at least partly transverse to the main flow direction.

The present invention generally relates to improved catalysts that provide for reduced product contaminants, related methods and improved reaction products. It more specifically relates to improved direct fuel production and redox catalysts that provide for reduced levels of certain oxygenated contaminants, methods related to the use of those catalysts, and hydrocarbon fuel or fuel-related products that have improved characteristics. In one aspect, the present invention is directed to a method of converting one or more carbon-containing feedstocks into one or more hydrocarbon liquid fuels. The method includes the steps of: converting the one or more carbon-containing feedstocks into syngas; and, converting the syngas to one or more hydrocarbons (including liquid fuels) and a water fraction. The water fraction comprises less than 500 ppm of one or more carboxylic acids.