A reactor for carrying out an endothermic reaction, in particular a high-temperature reaction, in which a product gas is obtained from a feed gas, wherein: the reactor surrounds a reactor interior; the reactor is configured to provide a reactor bed in a reaction zone of the reactor interior, which reactor bed comprises a large number of solid material particles; the reactor is also configured to guide the feed gas into the reaction zone; in order to heat the feed gas, the reactor is designed to heat the solid material particles in the reaction zone such that, by transferring heat from the solid material particles to the feed gas, the feed gas in the reaction zone can be heated to a reaction temperature in order to participate as a starting product in the endothermic reaction for producing the product gas.

A process for producing a gas stream comprising carbon monoxide comprising the steps of (a) feeding a gas mixture comprising carbon dioxide and hydrogen to a burner and combusting it with a sub-stoichiometric amount of an oxygen gas stream to form a combusted gas mixture comprising carbon monoxide, carbon dioxide, hydrogen and steam, (b) passing the combusted gas mixture through a bed of reverse water-gas shift catalyst to form a crude product gas mixture containing carbon monoxide, steam, hydrogen and carbon dioxide, (c) cooling the crude product gas mixture to below the dew point and recovering a condensate to form a dewatered product gas, (d) removing carbon dioxide from the dewatered product gas in a carbon dioxide removal unit to form the gas stream comprising carbon monoxide, and (e) combining carbon dioxide recovered by the carbon dioxide removal unit with the gas mixture comprising hydrogen and carbon dioxide.

The present invention generally relates to improved catalysts that provide for reduced product contaminants, related methods and improved reaction products. It more specifically relates to improved direct fuel production and redox catalysts that provide for reduced levels of certain oxygenated contaminants, methods related to the use of those catalysts, and hydrocarbon fuel or fuel-related products that have improved characteristics. In one aspect, the present invention is directed to a method of converting one or more carbon-containing feedstocks into one or more hydrocarbon liquid fuels. The method includes the steps of: converting the one or more carbon-containing feedstocks into syngas; and, converting the syngas to one or more hydrocarbons (including liquid fuels) and a water fraction. The water fraction comprises less than 500 ppm of one or more carboxylic acids.

A method and system for reforming CO.sub.2 rich natural gases is disclosed which comprises: a cold plasma unit configured to convert CO.sub.2 rich natural gases into a plasma state; and a gas reforming reactor configured to reform said CO.sub.2 rich gas mixture at said plasma state into a syngas. The catalytic reforming reactor is separate and different from the DBD cold plasma unit. Means for latent heat of condensation, endothermic/exothermic reactions, and convection currents is used to achieve energy efficiency.

Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.

A catalyst composition suitable for the ethanol reforming process at low temperature with enhanced stability on long term, comprises a noble metal, such as platinum or rhodium, and a transition non-noble metal, such as nickel or cobalt, supported by a carrier comprising, cerium, zirconium, optionally aluminium, supplemented with potassium. It is provided also a method for the stable production of hydrogen from an ethanol containing gas stream, comprising subjecting the gas stream to catalytic ethanol reforming as to form a rich H2 stream, using the catalyst as defined above.

A bimetallic catalyst composition containing a mesh substrate having supported thereon an alumina washcoat on which are impregnated bimetallic particles of rhodium and ruthenium in specified amounts. A process for the catalytic partial oxidation of a hydrocarbon, such as methane or natural gas, involving contacting the hydrocarbon with an oxidant in the presence of the aforementioned bimetallic catalyst under reaction conditions sufficient to produce synthesis gas, that is, to a mixture of hydrogen and carbon monoxide.

Bifunctional catalyst compositions, methods, and systems are provided for the use of CO.sub.2 as a soft oxidizing agent to effectively convert low-value small alkanes to high-value small olefins. The bifunctional catalyst comprises a metal oxide catalyst and a redox-active ceramic support.

A method of dry reforming of methane (CH.sub.4) is provided. The method includes contacting at a temperature of 500 to 1000 degree Celsius (° C.) a reactant gas mixture including methane and carbon dioxide (CO.sub.2) with a bimetallic supported catalyst. The bimetallic supported catalyst includes a porous catalyst support and a bimetallic catalyst. The porous catalyst support includes aluminum oxide (Al.sub.2O.sub.3) and magnesium oxide (MgO). The bimetallic catalyst includes nickel (Ni) and copper (Cu) disposed on the porous catalyst support. The method further includes collecting a product gas mixture including hydrogen (H.sub.2) and carbon monoxide (CO). The bimetallic supported catalyst includes 8 to 16 weight percent (wt. %) nickel and 2 to 14 wt. % copper, each based on a total weight of bimetallic supported catalyst.

Ceramic compositions with catalytic activity are provided, along with methods for using such catalytic ceramic compositions. The ceramic compositions correspond to compositions that can acquire increased catalytic activity by cyclic exposure of the ceramic composition to reducing and oxidizing environments at a sufficiently elevated temperature. The ceramic compositions can be beneficial for use as catalysts in reaction environments involving swings of temperature and/or pressure conditions, such as a reverse flow reaction environment. Based on cyclic exposure to oxidizing and reducing conditions, the surface of the ceramic composition can be converted from a substantially fully oxidized state to various states including at least some dopant metal particles supported on a structural oxide surface.