A steam methane reformer (SMR) system includes an outer tube, wherein a first end of the outer tube is closed; an inner tube disposed in the outer tube, wherein a first end of the inner tube is open. A flow channel is defined within the inner tube and an annular space is defined between the outer tube and the inner tube, the flow channel being in fluid communication with the annular space. The SMR system includes a catalytic foam disposed in the annular space between the outer tube and the inner tube, the catalytic foam comprising a catalyst.

The present invention addresses to a catalyst, and the method for obtaining the same, for generating hydrogen and/or syngas. More specifically, the present invention describes a catalyst based on nickel, molybdenum and tungsten, for steam reforming processes of natural gas or other hydrocarbon streams (refinery gas, propane, butane, naphtha or any mixture thereof) that presents high resistance to deactivation by coke deposition. According to the present invention, the catalyst has NiMoW as its active phase, in bulk form and/or supported on an alumina oxide and other high surface area oxide supports, and may also contain other promoters. Furthermore, the present invention teaches the production of a catalyst whose active phase of NiMoW has high activity for hydrocarbon steam reforming reaction.

Provided herein are catalyst materials and processes for processing hydrocarbons. For example, doped ceria-supported metal catalysts are provided exhibiting good activity and stability for commercially relevant dry reforming of methane as well as mixed hydrocarbon feedstocks under process conditions including low temperature and long term operation. Useful doped ceria-supported metal catalysts include nickel dispersed over Ti-doped ceria.

Systems and methods are provided for using oxycombustion to provide heat within a reverse flow reactor environment. The oxygen for the oxycombustion can be provided by oxygen stored in an oxygen storage component in the reactor. By using an oxygen storage component to provide the oxygen for combustion during the regeneration step, heat can be added to a reverse flow reactor while reducing or minimizing addition of diluents and while avoiding the need for an air separation unit. As a result, a regeneration flue gas can be formed that is substantially composed of CO.sub.2 and/or H.sub.2O without requiring the additional cost of creating a substantially pure oxygen-containing gas flow.

The present disclosure relates to a catalyst composition comprising: (a) nickel; (b) at least one promoter selected from Cu Zn, Mo, Co, Mg, Ce, Ti, Zr, Fe, Pd, Ag, Pt, or combinations thereof; and (c) a support material, wherein, the nickel loading is in the range of 6-19 wt % and the at least one promoter loading is in the range of 0.2-5 wt % with respect to the support material. The present disclosure further discloses a process for preparing a catalyst composition and a process each for the production of hydrogen gas and carbon nanotubes. Also disclosed herein, is use of a catalyst composition for obtaining hydrogen gas and carbon nanotubes.

The present subject matter relates to co-producing H-CNG and CNTs. The process comprises adding catalyst to a first reactor (110) and activating the catalyst and performing a reaction to obtain H-CNG and CNTs. At a first predetermined time after reaction has progressed in the first reactor (110), catalyst is added to a second reactor (120), activated, and then the reaction proceeds simultaneously in the first reactor (110) and second reactor (120). The use of multiple reactors with staggered start times helps in the continuous co-production of H-CNG and CNTs. Catalyst preparation process is integrated with the co-production process for efficient heat recovery. The first and second reactors are fluidized bed reactors with cantilever trays having weirs for controlling the residence time of the catalyst in the reactor and thereby controlling the purity of CNTs produced.

The present invention relates to a dry reforming catalyst in which an active material is impregnated on the surface of a metal oxide support and the active material is surrounded by a surfactant, a method of preparing the same, and a method of producing a synthetic gas using the catalyst. Since the surfactant on the surface of the active material prevents the active material from being sintered and the active material surface from being covered with carbon, the dry reforming catalyst exhibits high activity at high temperature for a long period of time without having to use a precious metal, and thus is useful for the production of a synthetic gas.

Methods and systems for converting methane to syngas are provided. Certain exemplary methods and systems involve reacting methane and carbon dioxide with a nickel oxide catalyst in a reaction chamber, thereby providing syngas and a reduced nickel species. The reduced nickel species can be regenerated by oxidation with air in a regeneration chamber, thereby generating a regenerated nickel oxide and heat. The regenerated nickel oxide and heat can be returned to the reaction chamber to drive the syngas reaction.

Steam-hydrocarbon reforming reactor with a reformer tube containing ceramic-supported catalyst pellets and metal foam particles. The ceramic-supported catalyst pellets have a porous support comprising one or more of alumina, calcium aluminate, and magnesium aluminate. The metal foam particles comprise Fe and/or Ni. The ceramic-supported catalyst pellets and metal foam particles may be layered or interspersed.

Disclosed is a supported nanoparticle catalyst, methods of making the supported nanoparticle 5 catalysts and uses thereof. The supported nanoparticle catalyst includes catalytic metals M1, M2, M3, and a support material. M1 and M2 are different and are each selected from nickel (Ni), cobalt (Co), manganese (Mn), iron (Fe), copper (Cu) or zinc (Zn), wherein M1 and M2 are dispersed in the support material. M3 is a noble metal deposited on the surface of the nanoparticle catalyst and/or dispersed in the support material. The nanoparticle catalyst is 10 capable of producing hydrogen (H2) and carbon monoxide (CO) from methane (CH4) and carbon dioxide (CO2).