Provided is a method of generating hydrogen efficiently using a renewable resource as a raw material.

A method of producing hydrogen according to the present disclosure is a method in which hydrogen is generated from a saccharide in the presence of a solvent and the following catalyst: catalyst which contains at least one metal element selected from the metal elements in Groups 8, 9, and 10.

The catalyst is preferably a complex or salt of the metal element, and particularly preferably a complex including the at least one metal element selected from the metal elements in Groups 8, 9, and 10 and at least one ligand selected from pentamethylcyclopentadienyl, cyclopentadienyl, p-cymene, and 1,5-cyclooctadiene.

As the solvent, it is preferable to use at least one selected from an organic acid and an ionic liquid.

The saccharide may be a lignin-saccharide complex, and is preferably cellulose.

The present disclosure relates to a hydrogen gas production method including: a first step of generating a mixed gas containing hydrogen and carbon dioxide from a hydrogen storage agent by dehydrogenation reaction using a catalyst in a reactor; a second step of purifying the generated mixed gas to acquire a gas having a high hydrogen concentration; a third step of separating a solution in the reactor into a solution enriched with the catalyst and a permeate using a separation membrane unit; and a fourth step of supplying the solution enriched with the catalyst to the reactor for reusing in the first step.

A flow reactor system for providing on-demand H.sub.2 evolution at pressure from a liquid organic hydrogen carrier and/or blends thereof includes a reactor that includes a reaction vessel having an inlet and outlet. The inlet is configured to introduce reactants into the reaction vessel, and the outlet is configured to release reaction products. The reaction vessel is configured to hold therein a catalyst system capable of catalyzing the evolution of molecular hydrogen from a liquid organic hydrogen carrier. Advantageously, the reaction vessel is configured to operate at pressures greater than or equal to 50 psig (e.g., from about 50 psig to about 10500 psig. The flow reactor system also includes a source of preheated liquid organic hydrogen carrier in fluid communication with the reactor and a purification system in fluid communication with the outlet that provides purified molecular hydrogen gas for on-demand applications.

A bifunctional catalyst for example for conversion of oxygenates, the bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl.sub.2O.sub.4.

Provided is a method for preparing synthesis gas, and more particularly, a method for preparing synthesis gas including: supplying a cracked gas stream discharged from a cracking furnace of a naphtha cracking center (NCC) process to a gasoline fractionator, separating a side discharge stream from the gasoline fractionator using a first stripper, and separating a lower discharge stream from the gasoline fractionator using a second stripper, wherein a mixed oil stream of a PGO stream and a PFO stream formed by controlling a flow rate of each stream are used.

The invention relates to the use of a reactor, methods, and devices for the quantitative recovery of molecular hydrogen from solid, liquid, or gaseous substances which contain hydrogen and which have heteroatoms, as well as to reactors. In this case, the reactors have material containing chromium. The subject matter of the invention also includes the use of the reactor, the method, and the device for the compound-specific or component-specific measurement of the isotope ratio (δ.sup.2H) of hydrogen using online apparatuses.

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

The present invention concerns a process for producing hydrogen by partial dehydrogenation of an organic liquid, said process comprising a step of supplying at least one organic liquid having a Degree of Hydrogenation DHplus, a step of partially dehydrogenating said liquid, a step of recovering firstly gaseous hydrogen and secondly said organic liquid having a Degree of Hydrogenation DHminus, and wherein the ratio DHplus/DHminus is between 1 and 25, endpoints excluded.

The invention likewise concerns a hydrogenation/dehydrogenation cycle comprising at least the process of the invention for producing hydrogen by partial dehydrogenation of an organic liquid and at least one hydrogenation reaction of said organic liquid.

The present invention relates to a process for producing hydrogen from a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, said process comprising at least one step wherein said liquid is brought into contact with a filtering agent. The invention also relates to the use of a filtering agent for the purification of a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, in a hydrogen production process.

The present invention is to provide a method for refining hydrogen with a hydrogen refining device in which the inside of a cell is divided into a primary side space and a secondary side space by palladium alloy capillaries each having one end being closed and a tube sheet supporting the open end of the palladium alloy capillaries, in which impurity-containing hydrogen is introduced from the primary side space to allow hydrogen to permeate the palladium alloy capillaries so as to collect pure hydrogen from the secondary side space. The method for refining hydrogen has a capability of decreasing the removed amount of gas containing impurities and efficiently collecting pure hydrogen from the secondary side space. From hydrogen with 1000 ppm or less of impurities as raw material hydrogen, gas containing impurities that does not penetrate the palladium alloy capillaries is removed from the primary side space at the flow rate of 10% or less of the introduction flow rate of the raw material hydrogen. Furthermore, gas containing impurities that does not penetrate the palladium alloy capillaries is removed from the primary side space at a flow rate based on the content of impurities contained in raw material hydrogen.