Patent classifications
C01B2203/1211
Process for upgrading renewable liquid hydrocarbons
The invention relates to a catalytic process for upgrading a renewable crude oil produced from biomass and/or waste comprising providing a renewable crude oil and pressurizing it to a pressure in the range in the range 60 to 150 bar, contacting the pressurized renewable crude oil with hydrogen and at least one heterogeneous catalyst contained in a first reaction zone at a weight based hourly space velocity (WHSV) in the range 0.1 to 2.0 h.sub.−1 and at a temperature in the range of 150° C. to 360° C., hereby providing a partially upgraded renewable crude oil, separating the partially upgraded renewable crude oil from the first reaction zone to a partially upgraded heavy renewable oil fraction, a partially upgraded light renewable oil fraction, a water stream and a process gas stream, introducing the separated and partially upgraded heavy renewable oil fraction and separated process gas to a second reaction zone comprising at least two reactors arranged in parallel and being adapted to operate in a first and a second mode of operation, the reactors comprising dual functioning heterogeneous catalyst(-s) capable of performing a catalytic steam cracking reaction in a first mode of operation or a steam reforming reaction in a second mode of operation, where the partially upgraded heavy renewable oil fraction from the first reaction zone is contacted with the dual functioning heterogeneous catalyst and steam at a pressure of 10 to 150 bar and a temperature of 350° C. to 430° C. whereby a catalytic steam cracking of the partially upgraded heavy renewable oil is performed in the reactors in the first mode of operation, hereby providing a further upgraded heavy renewable oil fraction, while separated process gas from the first and/or second reaction zone is contacted with the dual functioning catalyst and steam at a pressure of 0.1 to 10 bar and a temperature of 350 to 600° C. in the reactors in the second mode of operation and contacted with the dual functioning catalyst, thereby producing a hydrogen enriched gas, separating the further upgraded heavy renewable oil fraction from the catalytically steam cracking reactor to at least one light renewable oil fraction, a heavy renewable oil fraction, a hydrogen rich process gas and a water phase, separating hydrogen from the hydrogen enriched gas from the catalytic steam cracking zone and/or from the catalytic steam reforming and recycling it to the first reaction zone, alternating the reactors between the first mode of operation and the second mode of operation at predetermined time intervals thereby allowing for regeneration of the heterogeneous catalyst for the catalytic steam cracking in the first mode of op
A MINIMAL CATALYTIC DI-NICKEL PEPTIDE CAPABLE OF SUSTAINED HYDROGEN EVOLUTION AND METHODS OF USE THEREOF
Compositions and methods for hydrogen production are disclosed.
COMBINED FUEL CELL AND DIGESTION SYSTEM AND METHOD OF OPERATING THEREOF
A system includes a digestion system configured to convert a digestate into a fuel gas, and a fuel cell power system configured to convert the fuel gas into power and heat, and to provide the heat to the digestion system.
PROCESS AND SYSTEM FOR PRODUCING A HYDROCARBON-CONTAINING AND HYDROGEN-CONTAINING GAS MIXTURE FROM PLASTIC
The invention relates to a method and a system for producing a hydrocarbon- and hydrogen-containing gas mixture from plastics, and the use of the system for producing this gas mixture and the use of this gas mixture as a starting material in chemical syntheses or for gas supply.
PROCESS FOR PRODUCING SYNTHETIC FUEL
The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.
SOLID ACID ELECTROCHEMICAL CELLS FOR THE PRODUCTION OF HYDROGEN
Electrochemical cells for the production of hydrogen from liquid fuels and methods of operating the cells to produce hydrogen and electricity are provided. The electrochemical cells are solid state cells that incorporate a thermochemical conversion catalyst and a hydrogen oxidation catalyst into the anode and utilize solid acid electrolytes. This cell design integrates thermally driven chemical conversion of a starting fuel with electrochemical removal of hydrogen from the conversion reaction zone.
DEHYDROGENATION METHOD AND HYDROGEN PRODUCTION SYSTEM USING THE SAME
A dehydrogenation method is provided that includes subjecting a first hydrogen storage body including compound including two or more N-heterocycloalkyl groups, and second hydrogen storage body including a compound including a substituted or unsubstituted cycloalkyl group and an N-heterocycloalkyl group, to a dehydrogenation reaction in the presence of a catalyst to produce hydrogen.
METHOD FOR PREPARING SYNTHESIS GAS AND AROMATIC HYDROCARBON
Provided is a method for preparing synthesis gas and aromatic hydrocarbons, and more particularly, a method for preparing synthesis gas and aromatic hydrocarbons including: supplying a pyrolysis fuel oil (PFO) stream containing PFO and a pyrolysis gas oil (PGO) stream containing PGO to a distillation tower as a feed stream (S10), the PFO stream and the PGO stream being discharged from a naphtha cracking center (NCC) process; and supplying a lower discharge stream from the distillation tower to a combustion chamber for a gasification process and supplying an upper discharge stream from the distillation tower to an SM/BTX preparation process (S20).
Catalyst structure for LOHC dehydrogenation reactor
Provided is a catalyst structure for a liquid organic hydrogen carrier (LOHC) dehydrogenation reactor, including a support, a plurality of channels formed on the support in such a manner that the LOHC may flow therethrough, and an LOHC dehydrogenation catalyst that is coated on the inner surfaces of the channels and is in contact with the LOHC to carry out LOHC dehydrogenation, wherein the hydrogen gas generated from the dehydrogenation is discharged along the channels so that the contact area between the LOHC and the LOHC dehydrogenation catalyst may be increased.
PROCESS FOR REDUCING AN ORGANIC MATERIAL TO PRODUCE METHANE AND/OR HYDROGEN
A process for reducing an organic material to produce methane and/or hydrogen is disclosed. The process includes: (a) contacting the organic material with an excess amount of hydrogen gas in an enclosed reduction chamber at ambient temperature, where the reduction chamber is substantially free of oxygen, and heating the reduction chamber to cause a temperature increase in the organic material from ambient temperature to up to 425° C. at a rate of up to about 8° C. per minute, under positive pressure, to form a first gaseous mixture comprising methane, hydrogen, acid, and partially reduced volatile organic molecules; (b) heating the first gaseous mixture to a temperature of about 675° C. to about 875° C. in the presence of an excess amount of hydrogen gas to form a second gaseous mixture comprising methane, hydrogen, and acid; and (c) neutralizing the second gaseous mixture with a base.