A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.

A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas engine; power produced by said gas engine; is transferred to at least one power user of the process, such as a compressor; heat is re-covered from exhaust gas of said gas engine;, and at least part of said heat may be recovered as low-grade heat available at a temperature not greater than 200° C., to provide process heating to at least one thermal user of the process, such as CO2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.

A process for recovering oil and gas from an underground formation by injecting an ammonia containing enhanced oil recovery formulation into the oil-bearing formation, which process comprises (i) reacting steam with methane containing gas, (ii) combining the reaction mixture obtained with further steam, (iii) removing carbon dioxide to obtain hydrogen, (iv) reacting at least part of the hydrogen with nitrogen, (v) separating off ammonia, (vi) mixing ammonia with water and injecting it into the underground formation, (vii) recovering oil and gas, (viii) separating methane from the fluid recovered from the recovery well, (ix) removing sulfur compounds, and (ix) using in step (i) the methane obtained in step (viii).

An ammonia plant system upgrade utilizing both a direct and indirect multistage chilling system in the ammonia plant air compression train to increase process air flow to the secondary ammonia reformer of an existing ammonia plant as well as upgrades to provide more pre-heating along with increased process air flow.

The ammonia synthesis system of the present invention includes an ammonia synthesis reaction unit (10) that synthesizes ammonia from nitrogen and hydrogen; an ammonia cooler (20) that cools an ammonia-containing gas discharged from the ammonia synthesis reaction unit (10); a gas-liquid separator (30) that separates ammonia liquefied by the ammonia cooler (20) from a circulated gas; and an ammonia synthesizing gas supplying unit (40) that supplies nitrogen gas and hydrogen gas, the circulated gas being supplied to the ammonia synthesis reaction unit, the circulated gas supplied to the ammonia synthesis unit having an ammonia gas concentration of 3% by volume or more. The method for producing ammonia of the present invention includes reacting nitrogen and hydrogen using a circulated gas having an ammonia gas concentration of 3% by volume or more and using an ammonia synthesis catalyst under a condition of a reaction pressure of 10 MPa or less to produce ammonia. The present invention can provide an ammonia synthesis system and an ammonia production method in which an energy required for producing ammonia is reduced.

Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.

A method for revamping a catalytic converter wherein: said catalytic converter comprises a pressure vessel and a catalytic cartridge containing at least one catalyst bed, the pressure vessel includes a cylindrical shell with a full aperture and includes a removable cover of said aperture, and the catalytic cartridge is removable through said upper aperture, and the method includes: installing an additional shell over the aperture of the original shell, thus obtaining an axially extended shell of the pressure vessel; providing an axially extended catalytic cartridge having an axially extended room for holding catalyst in the so obtained axially extended shell.

The system includes a methane reformer, a combined cycle power generator, and a switch. The reformer is configured to react methane with steam. The combined cycle power generator includes a steam turbine, a gas turbine, a power generator, and a water boiler. The steam turbine is configured to rotate in response to receiving steam. The gas turbine is configured to rotate in response to receiving a mixture of fuel and air. The power generator is configured to convert rotational energy from the steam turbine and the gas turbine into electricity. In a first position, the switch is configured to direct exhaust from the gas turbine to the reformer, thereby providing heat to the reformer. In a second position, the switch is configured to direct exhaust from the gas turbine to the water boiler, thereby providing heat to the water boiler to generate steam.

A method for improving efficiency of an existing ammonia synthesis gas plant or a new ammonia synthesis gas plant by establishing a combination of secondary steam reforming using oxygen from electrolysis of water for the production of ammonia synthesis gas.

Systems/methods for continuous operation of fixed bed reactors using gaseous fuels for the purpose of power generation through integration with a combined cycle power plant are provided. The fixed bed reactors are assumed to operate in a semi-batch mode composed of reactor modules that are integrated into module trains that comprise the chemical-looping combustion island of the power plant. The scheduling of each reactor train is cast as an optimization problem that maximizes thermodynamic efficiency subject to constraints imposed to each reactor and the entire island. When the chemical-looping reactors are arranged cyclically, each feeding to or being fed from another reactor, in an operating scheme that mimics simulated moving bed reactors, the thermodynamic efficiency of the reactor island can be improved. Allowing the reversal of module order in the cyclically arranged reactor modules further improves the overall thermodynamic efficiency (to 84.7%), while satisfying constraints imposed for carbon capture, fuel conversion, power plant safety and oxygen carrier stability.