The present invention provides a secondary battery-use active material that allows for an improvement in thermal stability after charge and discharge are repeated. The secondary battery-use active material of the present invention includes a cathode active material that includes (A) a main phase and a sub-phase, (B) the main phase containing a first lithium compound represented by Li.sub.aNi.sub.bM.sub.cAl.sub.dO.sub.e (where M is an element such as cobalt, and 0.8<a<1.2, 0.45b1, 0c1, 0d0.2, 0<e1.98, (c+d)>0, and (b+c+d)1), and (C) the sub-phase containing a second lithium compound that contains lithium, aluminum, and oxygen as constituent elements.

This invention generally relates to a process and circuit for reintercalating lithium aluminum double hydroxide (LADH) lithium selective adsorbents. The inventive process includes reintercalating the spent LADH adsorbent with lithium salt in a dilute brine under alkaline conditions at a predetermined intercalation temperature, followed by neutralization using an appropriate acid at a predetermined neutralization temperature. The inventive process can be performed to reintercalate the adsorbent and can be performed multiple times over the life of the adsorbent. The reintercalation process can be conducted at a chemical regeneration facility, or alternatively, in situ, such as at an on-site mineral extraction facility, in a mobile reinteractation circuit, or within adsorbent columns of a lithium extraction (e.g., DLE) circuit. In the later arrangement, the invention can be used in fixed beds, stirred tanks, pseudo- or simulated moving bed (SMB) circuits, or other DLE circuits.

The objective of the present invention is to provide, in an industrially advantageous method, -lithium aluminate which has various favorable physical properties as a MCFC electrolyte holding plate with excellent heat stability and chemical stability, even when the -lithium aluminate is minute with the BET specific surface area being 10 m2/g or greater. A method for producing -lithium aluminate is characterized by mixing hydrated alumina and lithium carbonate in an Al/Li molar ratio of 0.95-1.01 and subjecting the obtained mixture (a) to a first firing reaction to obtain a fired product, and then subjecting a mixture (b) which is the obtained fired product to which an aluminum compound is added to a second firing reaction.

A method and a device for prefixing substrates, whereby at least one substrate surface of the substrates is amorphized in at least one surface area, characterized in that the substrates are aligned and then make contact and are prefixed on the amorphized surface areas.

The present invention relates to heterogeneous acid catalysts comprising or consisting of mixed metal salts, of lithium and aluminum phosphates and sulfates, and combinations with metallic cations, such as magnesium, titanium, zinc, zirconium and gallium, to provide adequate Lewis acidity; organic or inorganic porosity promoters, such as polysaccharides; and agglomerates, such as clays, kaolin and metal oxides of the type M.sub.xO.sub.y, where; M=Al, Mg, Sr, Zr or Ti, and other metals of groups IA, IIA and IVB, x=1 or 2 and y=2 or 3, for the formation of particles. A process is disclosed for obtaining from the catalyst by the hydrolysis of aluminum lithium hydride with water and oxygenated solvent, such as an ether. The catalysts are used in batch reactor and continuous flow systems in reactions that require moderate Lewis acidity, such as refining, petrochemical and general chemistry, including the transesterification of glycerides to produce alkyl esters.

Provided are a positive electrode active material for a secondary battery, in which, since the positive electrode active material includes a lithium-metal oxide having high-temperature stability and a metal oxide on a surface of a particle and a surface side in the particle, there is no concern about gas generation, because the occurrence of cracks on the surface of the active material is prevented during charge and discharge, and high-temperature storage stability and life characteristics may be improved when the positive electrode active material is used in the battery, and a secondary battery including the same.

The objective of the present invention is to provide, in an industrially advantageous method, -lithium aluminate which has various favorable physical properties as a MCFC electrolyte holding plate with excellent heat stability and chemical stability, even when the -lithium aluminate is minute with the BET specific surface area being 10 m2/g or greater. A method for producing -lithium aluminate is characterized by mixing hydrated alumina and lithium carbonate in an Al/Li molar ratio of 0.95-1.01 and subjecting the obtained mixture (a) to a first firing reaction to obtain a fired product, and then subjecting a mixture (b) which is the obtained fired product to which an aluminum compound is added to a second firing reaction.

A composite cathode active material for a lithium battery including: a lithium composite oxide; and a coating layer including a metal oxide and a lithium fluoride, (LiF) wherein the coating layer is disposed on at least a portion of a surface of the lithium composite oxide.

The present disclosure relates to a lithium compound for recovering valuable metals and a method of recovering the same, and a method of recovering a lithium compound for recovering valuable metals includes: preparing a battery; freezing and forcibly discharging the battery; shredding the battery into a battery shredded material; and heating the battery shredded material, wherein the heating of the battery is performed in a temperature range of 1,100 to 1,400 C., a degree of vacuum (Log P [atm]) in the heating of the battery is in a range of 4 to 0, a lithium compound recovered through the heating of the battery contains impurities, and the impurities include, by wt %, 1.8 wt % or less (excluding 0 wt %) of Na, 0.06 wt % or less (excluding 0 wt %) of K, 0.62 wt % or less (excluding 0 wt %) of Ca, and 0.47 wt % or less (excluding 0 wt %) of Mg.

The cathode active material includes secondary particles. The secondary particle includes a plurality of crystallites. Each of the plurality of crystallites includes a lithium metal composite oxide. A structure of the lithium metal composite oxide is a layered-rocksalt structure. In the cross section of the secondary particle, 2.5d.sub.L/d.sub.S28.2, 0.125d.sub.L/D, and 450 are satisfied. d.sub.L indicates the major axis diameter of the crystallite. d.sub.S indicates the minor axis diameter of the crystallite. D indicates the maximum Feret diameter of the secondary particles. represents an angle formed between the first straight line and the second straight line. The first straight line is an extension of the major axis diameter of the crystallite. The second straight line passes through the intersection of the circumscribed circle of the secondary particle and the extension line and the center of the circumscribed circle.