A furnace may include at least two vertical shafts, each of which may have at an upper end thereof an inlet for material to be burnt and at a lower end thereof a burnt material outlet. The inlet and the outlet may be connected by a transfer channel. In each case, at least one main burner may be positioned above the transfer channel, and a cooling gas inlet may be positioned below the transfer channel. At least one additional burner may be positioned below the transfer channel in each of the shafts. Such a furnace can be operated such that the material to be burnt in the currently fired shaft is at least partially calcined in a main burning zone above the transfer channel, and then thermally aftertreated in an additional burning zone positioned between the transfer channel and the additional burner.

A furnace may include at least two vertical shafts, each of which may have at an upper end thereof an inlet for material to be burnt and at a lower end thereof a burnt material outlet. The inlet and the outlet may be connected by a transfer channel. In each case, at least one main burner may be positioned above the transfer channel, and a cooling gas inlet may be positioned below the transfer channel. At least one additional burner may be positioned below the transfer channel in each of the shafts. Such a furnace can be operated such that the material to be burnt in the currently fired shaft is at least partially calcined in a main burning zone above the transfer channel, and then thermally aftertreated in an additional burning zone positioned between the transfer channel and the additional burner.

The disclosure discloses a method for preparing calcium oxide using multistage suspension preheater kiln. The steps of the method are: (1) the limestone powder is fed to the multistage suspension preheater kiln for preheating to 800 C. to 900 C.; (2) A preheated material is fed to a decomposition furnace, and calcined at 900 C. to 1100 C. for 25 s to 35 s; (3) A calcined material is fed to a rotary kiln, and calcined at 1100 C. to 1300 C. for 25 to 35 minutes, and finally cooled to obtain calcium oxide.

The disclosure discloses a method for preparing calcium oxide using multistage suspension preheater kiln. The steps of the method are: (1) the limestone powder is fed to the multistage suspension preheater kiln for preheating to 800 C. to 900 C.; (2) A preheated material is fed to a decomposition furnace, and calcined at 900 C. to 1100 C. for 25 s to 35 s; (3) A calcined material is fed to a rotary kiln, and calcined at 1100 C. to 1300 C. for 25 to 35 minutes, and finally cooled to obtain calcium oxide.

Integrated refinery processes and systems for generating hydrogen by direct decomposition of hydrocarbons. The integrated processes and systems can be used to capture carbon and sulfur in solid form, reducing carbon dioxide and sulfur oxide emissions. The processes include reacting sour gas with a metal-based sorbent in a reactor to produce sulfur-bearing solids and water, and to partially reform hydrocarbons in the sour gas to produce hydrogen-rich syngas; and cracking remaining hydrocarbons thermally with or without the presence of a catalyst to produce hydrogen and solid carbon.

Integrated refinery processes and systems for generating hydrogen by direct decomposition of hydrocarbons. The integrated processes and systems can be used to capture carbon and sulfur in solid form, reducing carbon dioxide and sulfur oxide emissions. The processes include reacting sour gas with a metal-based sorbent in a reactor to produce sulfur-bearing solids and water, and to partially reform hydrocarbons in the sour gas to produce hydrogen-rich syngas; and cracking remaining hydrocarbons thermally with or without the presence of a catalyst to produce hydrogen and solid carbon.

Provided are a chemical heat storage material having excellent cyclic durability and a method for producing the same. A chemical heat storage material includes: a surface layer formed of silica and/or calcium silicate; and calcium oxide particles with the surface layer.

Provided herein are methods comprising a) calcining limestone in a cement plant to form carbon dioxide and calcium compound selected from calcium oxide, calcium hydroxide, or combination thereof; b) treating the calcium compound with N-containing salt in water to produce an aqueous solution comprising calcium salt and N-containing salt; and c) contacting the aqueous solution with the carbon dioxide under one or more precipitation conditions to produce a precipitation material comprising calcium carbonate and a supernatant aqueous solution wherein the calcium carbonate comprises vaterite.

A system for making oxide material may comprise a preheating cyclone stage for receiving a solid carbonate material and operating at a temperature less than a calcination temperature of the solid carbonate material, a calcination cyclone stage for heating the preheated solid carbonate material and operating at a temperature of at least the calcination temperature to convert the preheated solid carbonate material to a solid oxide material and carbon dioxide gas, a cooling cyclone stage for cooling the solid oxide material and operating at a temperature less than the calcination temperature to cool the solid oxide material to ambient temperature, a first recirculating system to extract and recirculate a first gas from an outlet of the calcination cyclone stage to an inlet of the calcination cyclone stage zone, and a second recirculating system to extract and recirculate a second gas from the cooling cyclone stage to the preheating cyclone stage.

A system for making oxide material may comprise a preheating cyclone stage for receiving a solid carbonate material and operating at a temperature less than a calcination temperature of the solid carbonate material, a calcination cyclone stage for heating the preheated solid carbonate material and operating at a temperature of at least the calcination temperature to convert the preheated solid carbonate material to a solid oxide material and carbon dioxide gas, a cooling cyclone stage for cooling the solid oxide material and operating at a temperature less than the calcination temperature to cool the solid oxide material to ambient temperature, a first recirculating system to extract and recirculate a first gas from an outlet of the calcination cyclone stage to an inlet of the calcination cyclone stage zone, and a second recirculating system to extract and recirculate a second gas from the cooling cyclone stage to the preheating cyclone stage.