C01P2004/34

Hybrid organic-inorganic nano-particles

The invention relates to a method of making hybrid organic-inorganic core-shell nano-particles, comprising the steps of a) providing colloidal organic particles comprising a synthetic polyampholyte as a template; b) adding at least one inorganic oxide precursor; and c) forming a shell layer from the precursor on the template to result in core-shell nano-particles. With this method it is possible to make colloidal organic template particles having an average particle size in the range of 10 to 300 nm; which size can be controlled by the comonomer composition of the polyampholyte, and/or by selecting dispersion conditions. The invention also relates to organic-inorganic or hollow-inorganic core-shell nano-particles obtained with this method, to compositions comprising such nano-particles, to different uses of said nano-particles and compositions, and to products comprising or made from said nano-particles and compositions, including anti-reflective coatings and composite materials.

DISPERSION LIQUID, COMPOSITION, CURED FILM, COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE

A dispersion liquid contains an inorganic oxide particle surface-treated with at least one of a compound represented by Formula Si(R.sup.A1)(X.sup.A1).sub.3 or a compound represented by Formula Si(R.sup.A2)(R.sup.A20)(X.sup.A2).sup.2, polysiloxane having at least one of a T unit represented by Formula [R.sup.B1SiO.sub.3/2] or a D unit represented by Formula [R.sup.B2R.sup.B20SiO], and an organic solvent, where a content of the polysiloxane is 0.5% to 39% by mass with respect to a total amount of the inorganic oxide particle and the polysiloxane, in which in the formula, R.sup.A1, R.sup.A2, R.sup.B1, and R.sup.B2 represent a functional group, X.sup.A1 and X.sup.A2 represent a hydroxyl group or a hydrolyzable group, and R.sup.A20 and R.sup.B20 represent an alkyl group or an aryl group.

Preparation Method and Application for Metal Sulfide Hollow Microspheres with Enriched Sulfur Vacancies
20220246934 · 2022-08-04 ·

Disclosed is a hollow sulfide microsphere with enriched sulfur vacancies, which is prepared by a method comprising the steps of: dissolving cobalt nitrate and nickel nitrate in a mixed solution of N, N-dimethylformamide and acetone with an equal volume; then adding a chelating agent thereto, subjecting a resulting mixture to a solvothermal reaction to obtain a coordination polymer microsphere; dissolving the coordination polymer microsphere and a sulfurization agent in an organic solvent, and reacting to obtain a hollow sulfide microsphere; and subjecting the hollow sulfide microsphere to reduction treatment with sodium borohydride, centrifuging, washing and drying to obtain the hollow sulfide microsphere with enriched sulfur vacancies having a particle size of 1-2.5 μm, a shell thickness of 15-30 nm and a specific capacity of the material of 763.4 C g.sup.−1 (current density is 1 A g.sup.−1).

Fluidized bed reactors for post-processing powdered carbon

A system for post-processing carbon powders includes a fluidized-bed reactor having an interior containing a fluidized-bed region. The system may include a gas feed source, a gas inlet value, a gas-solid separator, and an energy source coupled to the fluidized-bed reactor. Carbon nano-particulates may be loaded, in powder form, into the fluidized-bed region prior to operation. The gas feed source may output a gas-phase mixture into the interior of the fluidized-bed reactor, and the energy source may electromagnetically excite the gas-phase mixture and generate a plasma-phase mixture formed in a plasma region positioned adjacent to or within the interior of the fluidized-bed reactor. The energy source may be positioned at one or more positions relative to the gas inlet valve.

POSITIVE ELECTRODE MATERIAL FOR HIGH-POWER LITHIUM ION BATTERY AND PREPARATION METHOD THEREOF

Disclosed is a positive electrode material for a high-power lithium ion battery. The positive electrode material is in form of secondary particles with a hollow microsphere structure, and a shell of the secondary particles is formed by aggregating a plurality of primary particles. The secondary particles have a uniform particle size, a loose and porous surface, and a large specific surface area. The obtained particles are regular in shape, stable in material structure, so that the positive electrode material has high rate performance and excellent cycle performance. The disclosure also provides a preparation method for the positive electrode material comprising (1) synthesizing a Ni.sub.xCo.sub.yM.sub.z(OH).sub.2 precursor by a co-precipitation method, such that the precursor has a central portion consisted by fine particles and a shell portion consisted by large particles having a larger particle size than that of the fine particles; (2) mixing the precursor and a lithium salt uniformly, and adding an oxide of a doping element during the mixing, and then sintering the mixture to provide a Li.sub.aNi.sub.xCo.sub.yM.sub.zO.sub.2 positive electrode material. The preparation method is simple and low cost, and can be industrialized.

CONDUCTIVE PARTICLE AND MANUFACTURING METHOD THEREOF, ADHESIVE AND APPLICATION THEREOF
20220089917 · 2022-03-24 · ·

The disclosure relates to a conductive particle and a manufacturing method thereof, an adhesive and an application thereof. The conductive particle includes a core, a conductive carbon layer and a conductive polymer layer. The conductive carbon layer covers the core, and the conductive polymer layer is provided on the conductive carbon layer. The conductivity of the conductive particle is higher.

BIODEGRADABLE HOLLOW NANOPARTICLES AND METHODS AND APPARATUS FOR MANUFACTURING THE SAME

Hollow nanoparticles for time-release delivery of a payload. A composition include a mesoporous hollow nanoparticle and a degradation agent, wherein the degradation agent includes one or more of a reducing agent, an acid, or an acidifier. The mesoporous hollow nanoparticle degrades in a presence of the degradation agent for time-release of a payload.

TRANSPARENT SUBSTRATES COMPRISING THREE-DIMENSIONAL POROUS CONDUCTIVE GRAPHENE FILMS AND METHODS FOR MAKING THE SAME

Disclosed herein are graphene coatings characterized by a porous, three-dimensional, spherical structure having a hollow core, along with methods for forming such graphene coatings on glasses, glass-ceramics, ceramics, and crystalline materials. Such coatings can be further coated with organic or inorganic layers and are useful in chemical and electronic applications.

NICKEL COMPOSITE HYDROXIDE AND MANUFACTURING METHOD THEREOF, CATHODE ACTIVE MATERIAL FOR NONAQUEOS-ELECTROLYTE SECONDARY BATTERY AND MANUFACTURING METHOD THEREOF, AND NONAQUEOUS-ELECTROLYTE SECONDARY BATTERY

Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation. The crystallization reaction is performed in a non-oxidizing atmosphere at least in a range after the processing time exceeds at least 40% of the total time of the particle growth process from the start of the particle growth process where the oxygen concentration is 1 volume % or less, and with controlling an agitation power requirement per unit volume into a range of 0.5 kW/m.sup.3 to 4 kW/m.sup.3 at least during the nucleation process.

Iridium and / or iridium oxide microsphere-based porous material, preparation method therefor, and uses thereof

The invention relates to a porous material in the form of microspheres based on iridium and/or iridium oxide, its preparation process, its use as anodic catalyst in a water electrolyser based on a solid polymer electrolyte, also called PEM water electrolyser (with PEM meaning “Proton Exchange Membrane” or “Polymer Electrolyte Membrane”) or for the manufacture of light-emitting diodes for various electronic devices or for cars, and a PEM water electrolyser comprising such a material as an anode catalyst.