C01P2004/84

Positive electrode active material for non-aqueous electrolyte secondary batteries, production method therefor, and non-aqueous electrolyte secondary batteries using said positive electrode active material

Provided is a positive electrode active material for non-aqueous electrolyte secondary batteries for making high capacity and high output compatible, non-aqueous electrolyte secondary batteries, having the positive electrode active material adopted thereto, and a production method for a positive electrode active material in which the positive electrode active material can be easily produced in an industrial scale. A positive electrode active material for non-aqueous electrolyte secondary batteries, contains: primary particles of a lithium nickel composite oxide represented by at least General Formula: Li.sub.zNi.sub.1-x-yCo.sub.xM.sub.yO.sub.2 (0.95≤z≤1.03, 0<x≤0.20, 0<y≤0.10, x+y≤0.20, and M is at least one type of element selected from Mg, Al, Ca, Ti, V, Cr, Mn, Nb, Zr, and Mo); and secondary particles configured by flocculating the primary particles, wherein an LiAl compound and an LiW compound are provided on surfaces of the primary particles.

Positive electrode active material for non-aqueous electrolyte secondary batteries, production method therefor, and non-aqueous electrolyte secondary batteries using said positive electrode active material

Provided is a positive electrode active material for non-aqueous electrolyte secondary batteries for making high capacity and high output compatible, non-aqueous electrolyte secondary batteries, to which the positive electrode active material is adopted, and a production method for a positive electrode active material in which the positive electrode active material can be easily produced even on an industrial scale. A positive electrode active material for non-aqueous electrolyte secondary batteries, comprising: primary particles of a lithium nickel composite oxide represented by at least General Formula: Li.sub.zNi.sub.1-x-yCo.sub.xM.sub.yO.sub.2 (0.95≤z≤1.03, 0<x≤0.20, 0<y≤0.10, x+y≤0.20, and M is at least one type of element selected from Mg, Al, Ca, Ti, V, Cr, Mn, Nb, Zr, and Mo); and secondary particles configured by aggregating the primary particles, wherein an LiAl compound is provided on surfaces of the primary particles.

CATHODE MATERIAL AND PROCESS

The invention relates to improved particulate lithium nickel oxide materials which are useful as cathode materials in lithium secondary batteries. The invention also provides processes for preparing such lithium nickel oxide materials, and electrodes and cells comprising the materials.

CATHODE MATERIAL AND PROCESS

The invention relates to improved particulate lithium nickel oxide materials which are useful as cathode materials in lithium secondary batteries, and methods of treating them.

POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERY AND PREPARATION METHOD THEREFOR, AND LITHIUM ION BATTERY

A positive electrode material for a lithium ion battery and a preparation method therefor, and a lithium ion battery, relating to the technical field of secondary batteries. The positive electrode material comprises a high-nickel multi-element positive electrode material, the high-nickel multi-element positive electrode material is formed by agglomerating multiple primary grains, and the primary grains are distributed in a divergent shape along the diameter direction of the high-nickel multi-element positive electrode material, the aspect ratio L/R of the primary grains in the positive electrode material is greater than or equal to 3, and the radial distribution ratio of the primary grains in the positive electrode material is greater than or equal to 60%. The lithium ion battery containing the positive electrode material has high capacity and greatly improved particle strength.

POSITIVE ELECTRODE ACTIVE MATERIAL FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY

A positive electrode active material for a non-aqueous electrolyte secondary battery according to an aspect of the present disclosure contains a lithium metal composite oxide having secondary particles formed by the aggregation of primary particles, wherein W is present on the surface and inside of the secondary particles of the lithium metal composite oxide. The amount of W present on the surface of the secondary particles of the lithium metal composite oxide represented by general formula LiαNiaCobAlcMdWeOβ (in the formula, 0.9≤α≤1.2, 0.8≤a≤0.96, 0<b≤0.10, 0<c≤0.10, 0≤d≤0.1, 0.0003≤e/(a+b+c+d+e)≤0.002, 1.9≤β≤2.1, a+b+c+d=1, and M is at least one element selected from among Mn, Fe, Ti, Si, Nb, Zr, Mo, and Zn) is 25-45% of the total amount of W present on the surface and inside of the secondary particles of the lithium metal composite oxide.

POSITIVE ELECTRODE ACTIVE MATERIAL HAVING SURFACE PORTION DOPED WITH HETERO ELEMENTS, AND METHOD FOR PRODUCING SAME

The present invention pertains to: a positive electrode active material precursor containing first secondary particle composed of an aggregate of a plurality of first primary particles, the positive electrode active material precursor including a first center portion represented by chemical formula 1 and a first surface portion represented by chemical formula 2, wherein the thickness of the first surface portion is 2-20% of the average radius of the positive electrode active material precursor; and a positive electrode active material containing the positive electrode active material precursor.

ANODE MATERIALS FOR RECHARGEABLE LITHIUM-ION BATTERIES, AND METHODS OF MAKING AND USING THE SAME
20230120748 · 2023-04-20 ·

A lithium-ion battery anode material containing surface-coated disordered rocksalt lithium vanadium oxide is disclosed. The surface coating contains a species selected from the group consisting of carbon, a metal oxide, a metalloid oxide, a metal fluoride, a metalloid fluoride, a metal phosphate, a metalloid phosphate, and combinations thereof. Materials, designs, synthesis methods, and devices related to fast-charging lithium-ion batteries are provided. This invention fills a technology gap by providing anode materials with disordered rocksalt lithium vanadium oxides to achieve fast charging in 10 minutes or less, greater than 200 W.Math.h/kg energy density, a lifetime of at least 10,000 cycles, and improved battery safety. Methods of making and using the optionally surface-coated disordered rocksalt lithium vanadium oxide are disclosed. Many experimental examples are included, demonstrating several remarkable attributes of this battery technology.

Lithium composite oxide and lithium secondary battery comprising the same

The present invention relates to a lithium composite oxide having improved stability and electrical characteristics as a positive electrode material by inhibiting an interfacial side reaction in the lithium composite oxide and improving the stability of a crystal structure and ion conductivity, and a lithium secondary battery including the same.

Method for obtaining encapsulated nanoparticles

A method for obtaining at least one particle, including: (a) preparing solution A including at least one precursor of at least one of Si, B, P, Ge, As, Al, Fe, Ti, Zr, Ni, Zn, Ca, Na, Ba, K, Mg, Pb, Ag, V, Te, Mn, Ir, Sc, Nb, Sn, Ce, Be, Ta, S, Se, N, F, and Cl; (b) preparing aqueous solution B; (c) forming droplets of solution A; (d) forming droplets of solution B; (e) mixing droplets; (f) dispersing mixed droplets in a gas flow; (g) heating dispersed droplets to obtain the at least one particle; (h) cooling the at least one particle; and (i) separating and collecting the at least one particle. The aqueous solution is acidic, neutral, or basic. In step (a) and/or step (b) at least one colloidal suspension of a plurality of nanoparticles is mixed with the solution. Also, a device for implementing the method.