There is disclosed a method of making an electrode for an electrochemical reactor including the steps of providing a template and depositing electrode material such that the electrode material is in contact with the template. This template is provided in a form that produces channels in the electrode material. There is also disclosed an electrode for an electrochemical reactor which includes electrode material and a template, with the template occupying channels in the electrode material.

The invention relates to a system and method for treating wastewater onboard a marine vessel or other limited space application where wastewater treatment is required. In one embodiment of the invention, two polar opposite wastewater treatment processes are incorporated into the same treatment system. The system is a hybrid treatment unit that combines a conventional wastewater treatment using a moving bed biofilm reactor (MBBR) process-based biological treatment unit in combination with a novel electrochemical advanced oxidation process (EAOP) via an in-situ sodium hypochlorite recirculation. The clarified and disinfected effluent from this hybrid treatment unit is filtered to remove residual TSS. The filtered and disinfected effluent is discharged after dechlorination/neutralization. On-site maintenance disinfectant can be produced via the electrochemical/electrochlorination/electro-oxidation process and used for both treatment unit cleaning and disinfection. Additionally, the treatment unit provides a wholly separate stream of electrolysis generated disinfectant for surface disinfection purposes.

A water-processing electrochemical reactor that comprises a cylindrical inner anode (73), an outer tubular cathode (74), an intermediate chamber between the anode (73) and the cathode (74) and being crossed by the water, an outer shell (77) surrounding the cathode (74), a water inlet (71) and a water outlet (78), and a gas inlet (80) and gas outlet (79) connected to the outer shell (77) and to the gas chamber. The cathode surrounds the inner anode (73) and is porous to gas. A gas chamber is defined between the cathode (74) and the outer shell (77). The gas chamber contains a gas comprising oxygen and is at an overpressure that forces the gas through the porous cathode (74).

A water-processing electrochemical reactor that comprises a cylindrical inner anode (73), an outer tubular cathode (74), an intermediate chamber between the anode (73) and the cathode (74) and being crossed by the water, an outer shell (77) surrounding the cathode (74), a water inlet (71) and a water outlet (78), and a gas inlet (80) and gas outlet (79) connected to the outer shell (77) and to the gas chamber. The cathode surrounds the inner anode (73) and is porous to gas. A gas chamber is defined between the cathode (74) and the outer shell (77). The gas chamber contains a gas comprising oxygen and is at an overpressure that forces the gas through the porous cathode (74).

The present disclosure relates to a biocide-generating device for outputting a biocide to a water system. The biocide-generating device includes a power circuit positioned within a housing that defines an electrolytic cell of the biocide-generating device.

An electrode includes a microporous titanium substrate coated with a catalytic layer, and the catalytic layer includes magnetic SnO.sub.2—Sb particles. The magnetic SnO.sub.2—Sb particles are attached to the microporous titanium substrate through an external magnetic field. The microporous titanium substrate includes a plurality of membrane pores having a pore size of 5-50 μm that is smaller than a particle size of the magnetic SnO.sub.2—Sb particles.

An illustrative expendable or reconstructable ozone generator cartridge for an aqueous ozone delivery device, for example, for antimicrobial sanitizing and/or medical treatment, includes a housing for a water ozonating manifold, at least one ozone generating cell coupled to the manifold, and optionally a data logging and authentication feature. Advantageously, a water inlet, an aqueous ozone outlet, and an electrical connector of the ozone generator cartridge are simultaneously pluggable into and unpluggable from a docking station of the aqueous ozone delivery device, for example, a hand or implement washing and sanitizing device or a medical treatment device.

An electrochemical dechlorination of water method is provided. Dechlorination of water, containing chlorine or chloramine, is performed in an electrochemical reactor by passing electrons directly from an electrical grid to the chlorine or the chloramine via a cathode, where the dechlorination for the chlorine is defined by HOCl+2e.sup.−.fwdarw.Cl.sup.−+OH.sup.31, and wherein the dechlorination for the chloramine is defined by NH.sub.2Cl+H.sup.++2e.sup.−.fwdarw.Cl.sup.−+NH.sub.3. The cathode can be a stainless steel cathode. In one variation, the cathode and the anode are separated by a cation-exchange membrane. By means of this method, wastewater can be dechlorinated using power from the electric grid without the addition of external chemicals, thereby avoiding the cost of the chemicals, their transport, and the presence of their degradation products in the effluent water.

An electrochemical oxidation reactor includes rotatable electrodes inside a reactor vessel. The electrodes are mounted to support plates, which in turn are mounted on shafts. The plates are attached to each other in a spaced relationship so that a gap is formed therebetween. The plates are each electrically insulated from each other. The electrodes are mounted to the inside surfaces of these plates, inside the gap. The gap is sized to receive liquid to be treated so that liquid located within the gap will react with the electrodes. An electrical charge is applied to each shaft so that a dielectric is formed across the gap within the fluid located in the gap. According to a first embodiment, an electrochemical reactor includes containing two spaced electrode support plates. According to another embodiment, an electrochemical reactor includes several spaced electrode support plates.

Methods for electrochemically oxidizing organic compounds in aqueous solution. The methods include contacting an aqueous solution comprising organic compounds with a first anode and electrochemically oxidizing at least a portion of the organic compounds to provide a first aqueous solution comprising oxidation products; and contacting the first aqueous solution comprising oxidation products with a first cathode and electrochemically reducing at least a portion of the oxidation products to provide a first aqueous solution comprising reduced products and residual oxidizable organic compounds. The first aqueous solution can be further treated to electrochemically oxidize at least a portion of the residual oxidizable organic compounds to provide a second aqueous solution comprising oxidation products, and the second aqueous solution can be further treated to electrochemically reduce at least a portion of the oxidation products to provide a third aqueous solution comprising reduced products and residual oxidizable organic compounds. Systems for electrochemically oxidizing organic compounds and effectively carrying out the methods are also provided.