A method of inhibiting scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 10 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. The polymers are also useful for flocculation and coagulation in wastewater treatment.

Systems and methods for applying a chemical treatment solution to a process stream in an industrial processing system while the system is online. The method includes measuring a real-time pH of the process stream, determining a dosage of the chemical treatment solution based on a relationship between the dosage and a scale saturation parameter that is calculated based on the real-time pH of the process stream, and controlling application of the chemical treatment solution to the process stream based on the determined dosage.

Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water is concentrated in a reverse osmosis step and salt from the resulting solution is removed in supercritical conditions prior to destruction of PFAS in supercritical conditions.

A method for applying a chemical treatment solution to a process stream in an industrial processing system while the system is online. The method includes measuring a mineral hardness and alkalinity of the process stream, determining a dosage of the chemical treatment solution based on a relationship between the dosage and a scale saturation parameter that is calculated based on the mineral hardness and the alkalinity of the process stream, and controlling application of the chemical treatment solution to the process stream based on the determined dosage.

A method for applying a chemical treatment solution to a process stream in an industrial processing system while the system is online. The method includes measuring a mineral hardness and alkalinity of the process stream, determining a dosage of the chemical treatment solution based on a relationship between the dosage and a scale saturation parameter that is calculated based on the mineral hardness and the alkalinity of the process stream, and controlling application of the chemical treatment solution to the process stream based on the determined dosage.

A system and method of controlling the treatment of water systems comprises multiple feeders for separately feeding treatment products, in the form of concentrated, non-hazardous, liquids with a single active ingredient, to a water system to treat various issues, such as corrosion and biofilms. A sensor verifies delivery of the treatment product to the water system. A controller controls activation of each feeder to control a feed rate according to programmed functions. The controller receives signals from sensors, which can be used as inputs in calculating feed rates or feeder activation times according to the programed functions and can alter treatment product feed rates based on real time data regarding water system chemistry or flow rates. The controller can send and receive data, signals, alerts, alarms or changes in programming to or from remote users, remote computers, or a water system controller.

A composition and method of inhibiting corrosion, white rust, and scale formation on components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion, white rust, and scale formation comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

A composition and method of inhibiting corrosion, white rust, and scale formation on components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion, white rust, and scale formation comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

Disclosed herein are the methods of using di-cationic or di-anionic compounds, which are derived from primary amine through an aza-Michael addition with an activated olefin, in a corrosion control composition to mitigate corrosion of a surface in a water system. The disclosed methods or compositions are found to be more effective than those methods or compositions including commonly used single quaternary compounds for mitigating corrosion for a metal surface in water systems.

Disclosed herein are the methods of using di-cationic or di-anionic compounds, which are derived from primary amine through an aza-Michael addition with an activated olefin, in a corrosion control composition to mitigate corrosion of a surface in a water system. The disclosed methods or compositions are found to be more effective than those methods or compositions including commonly used single quaternary compounds for mitigating corrosion for a metal surface in water systems.