Provided herein are methods, systems, and apparatuses for energy-efficient supercritical water oxidation of waste. The supercritical water oxidation processes and systems described herein may incorporate one or more of the following features: compression of large amounts of oxidant for plant-scale operations in an energy-efficient manner; the use of air as an oxidant; using reactor effluent to drive a turbine or other gas expander for energy recovery; and recovery of pressure and heat of reactor effluent. In some embodiments, the systems and methods are energy-neutral or energy-positive.

A salt separator separates salts and/or solid materials from a pumpable aqueous fluid mixture under process conditions, which lie in the range of the critical point for the fluid mixture. The salt separator contains a reaction zone in a cavity for transforming the pumpable aqueous fluid mixture into a raw mixture, e.g. a methanation reaction, and a feed opening for the pumpable aqueous fluid mixture to the cavity. The feed opening is realized in a rising pipe that protrudes into the cavity. A first extraction opening is provided for the raw mixture freed of salts and/or solid materials. The first extraction opening is arranged in the upper region of the cavity and a second extraction opening is provided for a brine containing the salt and/or the solid materials. The second extraction opening is arranged in the lower region of the cavity and is located lower down than the feed opening.

The present invention relates to the technical field of wastewater treatment. In the present invention, the reactor is provided with a double-shell reactor, a coaxial nozzle, an inner shell structure, evaporated water injection pipes and the like, so it is assured that the wastewater is inject into the reactor at a room temperature and is degraded thoroughly; moreover, with the evaporated water, the corrosion, salt deposition and local overheating in the reactor are prevented, so that the reaction process is guaranteed to be stable and reliable. and through a fuel system, a hydrothermal flame is formed in the reactor, so that the concentrated waste liquid injected into the reactor at the room temperature can be preheated to a supercritical reaction temperature, and the waste liquid is prevented from coking, scaling and the like in a preheating stage.

Methods, systems, and apparatuses configured to separate waste solids material from a supercritical wastewater feed may separate waste solids material from supercritical reactor effluent in a first region such that the waste solids material collects in a second region fluidically interposed between a first valve in an open state and a second valve in a closed state, the first valve being fluidically interposed between the first region and the second region. In addition, the first and second valves may be toggled between open and closed states according to a defined duty cycle such that the waste solids material is caused, at least in part, to be discharged from the second region via the second valve in response to the first valve being in a closed state and the second valve being in an open state.

The present invention relates to the technical field of wastewater treatment. In the present invention, the reactor is provided with a double-shell reactor, a coaxial nozzle, an inner shell structure, evaporated water injection pipes and the like, so it is assured that the wastewater is inject into the reactor at a room temperature and is degraded thoroughly; moreover, with the evaporated water, the corrosion, salt deposition and local overheating in the reactor are prevented, so that the reaction process is guaranteed to be stable and reliable. and through a fuel system, a hydrothermal flame is formed in the reactor, so that the concentrated waste liquid injected into the reactor at the room temperature can be preheated to a supercritical reaction temperature, and the waste liquid is prevented from coking, scaling and the like in a preheating stage.

A near-zero-release treatment system and method for high concentrated organic wastewater is in the chemical engineering and environment protection field, whose core technology is SCWO. The wastewater and sludge are grinded by the homogeneous pump, pressurized by high-pressure plunger pump, transported to successive pipeline for preheating and mixing with the oxygen and undergoes SCWO reaction in the reactor. After pressure release in the pressure relief device, the reacted fluid passes through the self-cleaning filter and gas liquid separator for insoluble solid and gas separation; then enters the MVR for crystallization of the soluble salts to realize near-zero-release of the feeding. The regular water treatment technology (coagulation sedimentation, membrane biotechnology, membrane technology, etc.) is adopted to complement SCWO, which lowers the operating parameters of the reactor and cuts the operating cost by treating the remaining COD with regular water treatment technology.

The present invention relates to supercritical water oxidation reactor adapted to contain inside the reactor an aqueous fluid below and above its supercritical state, said fluid comprising organic and/or inorganic material and a method of controlling such a reactor.

Described herein is a reactor (1) includes: a first reaction volume (V1), a second reaction volume (V2), wherein: the first reaction volume (V1) is in fluid communication with an inlet port for an oxidizer agent (OX_IN), an inlet port for at least one first reactant (R1_IN) and an outlet port for at least one reaction product (P1_OUT), said second reaction volume (V2) is in fluid communication with an inlet port for at least one second reactant (R2_IN), an outlet port for at least one second reaction product (P2_OUT) and is furthermore in thermal exchange relationship with said first reaction volume (V1), wherein, during operation, in said first reaction volume (V1) an oxidation reaction occurs between said at least one first reactant and said oxidizer agent with the formation of said at least one first reaction product, and in said second reaction volume (V2) a gasification reaction occurs of said second reactant with the contribution of a thermal energy flow exchanged between the first and the second reaction volumes (V1, V2) with formation of said at least one second reaction product.

The invention relates to an apparatus (1) for processing a slurry containing organic components, such as biomass, having a water contents of at least 50%, comprising a heat exchanger (7) to heat the slurry and a reactor (8) to convert at least a part of the organic components in the slurry, wherein at least one of the heat exchanger (7) and the reactor (8) comprises one or more pipes (7A; 8A). At least one transport screw (15) is accommodated in the pipe (7A; 8A) or at least one of the pipes (7A; 8A).

The disclosed technology relates to methods of inhibiting corrosion in reaction chambers configured for hydrothermal reaction of feeds containing a heteroatom. An embodiment of such a method comprises providing a feed stream comprising a phosphorus-containing material, an alkali metal compound, water, and a corrosion-inhibitor. The embodiment additionally includes introducing the feed stream and oxidant into a reactor chamber and oxidizing the phosphorus-containing material at an oxidation temperature greater than about 374 C. and an oxidation pressure exceeding about 25 bar, wherein the reactor chamber has inner surfaces comprising a material that corrodes when in contact with a phosphorus compound within the reactor. The embodiment additionally includes selectively reacting the corrosion-inhibitor with phosphorus within the reactor, thereby precipitating in the reactor chamber a phosphorus-containing solid inorganic compound. The embodiment further includes forming in the reactor chamber an alkali salt melt and carrying away from the reactor chamber a mixture comprising the solid phosphorus-containing inorganic compound and the alkali salt melt.