A system of generating steam from an emulsion stream produced from a reservoir via thermal recovery has a heat exchanger for adjusting the emulsion to a first temperature; at least one separation device for separating water from the emulsion at the first temperature to obtain produced water; an optional produced-water preheater, and a high-pressure evaporator for receiving the produced water and generating steam using the produced water. The evaporator has a vapor drum; a heating element receiving the water stream, and in fluid communication with the vapor drum via a pressure letdown device; a heating source for imparting sensible heat to the water stream for generating steam. The evaporator also includes a recirculation pump for circulation of blowdown concentrate, and a bubble generator for generating bubbles and injecting generated bubbles into the heating element to enable self-removal of scales and other solid deposits in the evaporator.

A system for desalting crude oil includes delivering a stream of salty crude oil and wash water into a mixing valve, mixing the stream of salty crude oil and wash water through the mixing valve to create a mixed stream of desalted crude oil and salty wash water, delivering the mixed stream of desalted crude oil and salty wash water to a static mixer, and mixing the mixed stream of crude oil and wash water in the static mixer. Within the static mixer, the mixed stream is mixed in a coalescing regime to coalesce smaller droplets of water into larger droplets of water. The mixed stream is subjected to an electric field to cause additional coalescence before being directed to a desalter where the salty wash water is separated from the desalted crude oil.

The combination of colloidal silica in conjunction with a chemical, such as a cationically-modified water soluble polymer, e.g. aluminum brine dispersion polymer, clarifies combinations of oil and water, for instance wastewater comprising an oil-in-water emulsion. The colloidal silica may have an average silica particle size of about 0.5 to about 10 nanometers.

Hierarchical porous membranes suitable for use in oil/water separation processes are provided. The membranes described herein are particularly well suited for separating trace amounts of water (e.g., no greater than 3 wt % water content, no greater than 1 wt % water content, or 50-1000 ppm water) from oil. The membranes have a wide range of applications, including deep seep oil exploration, oil purification, and oil spill cleanup.

The present invention provides improved methods for purifying and/or removing multiply charged cations and suspended solids from water. In particular the process relates to an additive composition that has the appropriate surfactant characteristics for effectively removing multiply charged cations and suspended solids from an aqueous or oil/aqueous mixed phase via foam fractionation. According to the invention, a hydrophobically modified polymer that acts as an associative thickener is used in the presence of a source of alkalinity or anionic reactant as well as surfactant in appropriate ratios to facilitate multiply charged cation and suspended solids removal for water purification in any of a number of commercial, environmental and industrial applications.

Methods and systems for use of switchable water, which is capable of reversibly switching between an initial ionic strength and an increased ionic strength, is described. The disclosed methods and systems can be used, for example, in distillation-free removal of water from solvents, solutes, or solutions, desalination, clay settling, viscosity switching, etc. Switching from lower to higher ionic strength is readily achieved using low energy methods such as bubbling with C0.sub.2, CS.sub.2 or COS or treatment with Bronsted acids. Switching from higher to lower ionic strength is readily achieved using low energy methods such as bubbling with air, inert gas, heating, agitating, introducing a vacuum or partial vacuum, or any combination or thereof.

A method is provided for recovering fractions from an animal rendering process wastewater stream, wherein the fractions include one or more of fat, oil, grease, and protein derived from an animal source. To recover the fractions, the wastewater stream is processed to separate insoluble or immiscible contaminants as collected skimmings, and treating the collected skimmings with an effective amount of a nonionic demulsifying surfactant.

The present disclosure provides compositions comprising anisotropic chain-like silica nanoparticles functionalized with hydrophilic groups. The anisotropic chain-like silica nanoparticles comprise linked arrays of charged silica nanoparticles, each linked array have at least one linear dimension of from about 100 nm to about 1200 nm and the anisotropic chain-like silica nanoparticles each in have a diameter of from about 10 nm to about 500 nm. These compositions are superoleophobic in the presence of water, e.g., when submerged in water. Also provided are layered coatings comprising these compositions, substrates comprising the layered coatings, articles comprising the layered coatings, methods of filtering a mixture of water and an oil using the compositions described herein, and methods of preparing a superoleophobic coating on a substrate using the compositions described herein.

A system of generating steam from an emulsion stream produced from a reservoir via thermal recovery has a heat exchanger for adjusting the emulsion to a first temperature; at least one separation device for separating water from the emulsion at the first temperature to obtain produced water; an optional produced water preheater, and a high pressure evaporator for receiving the produced water and generating steam using the produced water. The evaporator has a vapor drum; a heating element receiving the water stream, and in fluid communication with the vapor drum via a pressure letdown device; a heating source for imparting sensible heat to the water stream for generating steam. The evaporator also includes a recirculation pump for circulation of blowdown concentrate, and a bubble generator for generating bubbles and injecting generated bubbles into the heating element to enable self-removal of scales and other solid deposits in the evaporator.

The present invention provides a method for reducing or controlling wastewater and pollutant from emulsion polymerization resin production, comprising the following steps: (1) optimizing an emulsion polymerization reactor to lengthen a cleaning interval of the reactor so as to reduce the volumes of reactor cleaning wastewater and pollutant discharge; (2) demulsifying latex filter cleaning wastewater and removing a latex material so as to reduce the volume of the pollutant discharge; (3) demulsifying the highly concentrated reactor cleaning wastewater, then performing flotation recovery; (4) mixing graft polymerization wastewater and 1,3-diene polymerization wastewater, then performing demulsification; (5) mixing the demulsified latex wastewater and condensation and drying wastewater, then performing a coagulation and dissolved air flotation treatment; and (6) implementing a biological treatment process on the effluent from the coagulation and dissolved air flotation treatment to remove an organic material, nitrogen and phosphorus. The method of the present invention has the characteristics of reducing pollutants at a source, increasing product yield, saving resources, using different treatment according to wastewater property, and lowering treatment cost.