The present invention relates to the technical field of wastewater treatment, and discloses a method for enhanced bio-treatment of refractory organic pollutants with photo-excited holes as electron acceptors. The method comprises the following steps: 1) placing a composite semiconductor-coated carrier material into a reactor, introducing wastewater into the reactor inoculated with anaerobic sludge, and allowing the composite semiconductor-coated carrier material to be immersed in the wastewater, wherein the composite semiconductor-coated carrier material comprises a conductive carrier and composite semiconductor materials loaded on the conductive carrier; 2) carrying out habituated culture on the anaerobic sludge for a period of time, and loading a biological membrane on the surface of the composite semiconductor materials, to construct a photo-excited hole enhanced bioreactor; and 3) treating the refractory pollutants in the wastewater by utilizing the reactor under irradiation.

A nanofiltration membrane with a high flux for selectively removing hydrophobic endocrine disrupting chemicals and a preparation method thereof are provided. The method includes the following steps: immersing a porous support layer into a first solution, removing excess droplets from a surface of the support layer after taking the support layer out of the first solution, and then immersing the support layer attached with the first solution into a second solution for an interfacial polymerization reaction, followed by washing after completion of the reaction to obtain the subject nanofiltration membrane. The first solution is an aqueous solution containing a polyamine monomer and an acid binding agent, and the second solution is an organic solution containing an acid chloride monomer and a metal-organic framework.

The present invention discloses a Bacillus methylotrophicus strain named Bacillus methylotrophicus BP1.1, which was deposited in China Center for Type Culture Collection under Deposit No. CCTCC M 20191078 on Dec. 20, 2019. The present invention further discloses the use of the Bacillus methylotrophicus strain for degrading benzophenone ultraviolet sunscreens. By domesticating the activated sludge of the domestic sewage treatment plant step-by-step, the present invention provides a Bacillus methylotrophicus BP1.1 strain which has high efficiency in removing benzophenone ultraviolet sunscreens in water environment.

A method for removing organic pollutants from water bodies by activating persulfate with nutrient-enhanced soybean sprout-based biochar involves a method for removing organic pollutants from water bodies by activating persulfate with biochar. The invention is intended to solve the technical problems that existing biochar materials show poor catalytic activity when used for activating persulfate and requires the addition of a large amount of modifiers, which easily leads to secondary pollution to the environment, and the existing biochar materials are susceptible to interference from halogen ions, oxoanions, and natural organic matters in a persulfate system. The raw material of a catalyst used in the invention is soybean, and has an activation process mainly based on non-radical activation, exhibiting high reaction rate and saving persulfate. With the addition of 0.2 g/L catalyst and 0.5 mM potassium persulfate, the degradation efficiency against 10 mg/L phenol can reach 100% within 10 min.

The present disclosure relates to a catalyst that removes an organic compound by using a metal oxide catalyst and a preparation method thereof and a method for degradation of an organic compound using the same. Particularly, the present disclosure relates to a copper-iron oxide (Cu—Fe.sub.2O.sub.3) catalyst composition that is prepared by following steps of: adding a mixed solution of an iron (Fe) precursor and a copper (Cu) precursor to a precipitator solution (S1); obtaining precipitates by heating a solution prepared in the step S1 (S2); obtaining a metal oxalate by filtering the precipitates obtained in the step S2 (S3); drying the metal oxalate obtained in the step S3 (S4); and obtaining a copper-iron oxide catalyst by calcinating the metal oxalate subjected to the step S4 (S5) and a method for removal of an organic compound using the same.

The disclosure provides a novel electrocatalytic membrane reactor and use thereof in preparation of high-purity hydrogen. The electrocatalytic membrane reactor adopts an H-shaped electrolytic tank in which a cathode chamber is isolated from an anode chamber through a diaphragm, a membrane electrode is used as an anode, an auxiliary electrode is used as a cathode, a direct-current regulated power supply supplies a constant current, and the flow of a reaction solution is realized through a pump. In the disclosure, electrocatalysis is coupled with a membrane separation function, an oxygen evolution reaction is replaced with an organic electrochemical oxidation reaction in the anode chamber so as to reduce the overpotential of the oxygen evolution reaction, and a hydrogen evolving reaction is performed in the cathode chamber to prepare high-purity hydrogen.

Described herein are novel emulsion liquid membranes useful for extracting pollutants from industrial wastewater and water. The emulsion liquid membranes include, in various phases, at least one of nanoparticles, an ionic liquid, and combinations of nanoparticles and ionic liquids. Use of the present emulsion liquid membranes enhances the separation and the stability of the ELM method for pollutant extraction and recovery from wastewater and water.

he invention discloses a porphyrin-based metal coordination conjugated polymer, a preparation method therefor, and an application thereof in photocatalytic degradation of organic pollutants. The catalyst of the present invention has an 18π-conjugated skeleton, a nearly planar macrocyclic molecule, a stable rigid structure and a very stable highly conjugated system, so that the catalyst has excellent photoelectric conversion efficiency, a wide range of absorption spectra, strong redox capacity, and good chemical and thermal stability. A metal coordinated porphyrin acts as active center, a large number of derivatives can be derived, and the method has emerged as a promising alternative for the photocatalytic degradation of environmental pollutants and the like.

The invention relates to a method for preferably continuous treatment and/or purifying of water encumbered by contaminants, in particular organic contaminants, preferably micropollutants and/or trace substances, in particular untreated water, preferably for purposes of producing and/or obtaining treated and/or purified water, in particular pure water, preferably drinking water and/or service water. The invention further relates to a water treatment system for carrying out said method and to applications thereof.

The present invention relates to a bio-assisted method for treatment of spent caustic by treating with haloalkaliphilic consortium of bacteria capable of reducing or transforming sulphides, thiols, mercaptants and other sulphur containing compounds, phenols, hydrocarbons, naphthenic acids and their derivatives in spent caustic.