The present invention describes a method of capturing a fluorinated carbon compound located within a liquid, the method comprising contacting the fluorinated carbon compound with a block copolymer having a backbone comprising a hydrophilic block and a fluoropolyether block, wherein the fluorinated carbon compound binds to and is captured by the block copolymer.

An induced symbiotic osmosis system and method for treating produced fluids from a hydraulic fracturing process or system for symbiotic fluids fractionation, salinity power generation, brines and salts solution reverse osmosis. The system includes a reverse osmosis membrane assembly to create potable water from produced water. The membrane assembly includes a hollow fiber or flat sheet membrane and headers to transfer desalinated water therefrom. The system can include an electro coagulation system, an ultra or nano filtration system, and a desalter to treat the produced water or brine. A heat exchanger can be positioned between adjacent reverse osmosis membrane assemblies. An osmotic power generation unit can create electrical power by receiving and utilizing produce water and brine water from a brine storage. The system reduces the release of global warming contributing gases associated with hydraulic fracturing, while producing potable water and power.

A method of moderating concentration of at least highly fluorinated alkyl materials (e.g., molecules) from a contaminated aqueous feed liquid containing an original composition of between 5 parts/trillion and 3000 parts/billion of the at least highly fluorinated materials per liter of water into an aqueous electronic separator having multiple chambers including a feed chamber having a liquid exit port from which a mediated aqueous contaminated feed liquid exits and a liquid input port into which the contaminated aqueous feed liquid enters the feed chamber; an anodic electrode chamber filled with an aqueous anodic liquid; and a cathodic electrode chamber filled with an aqueous cathodic liquid; wherein the feed chamber is between and adjacent to the anodic electrode chamber and the cathodic electrode chamber and the feed chamber is separated from each of the anodic electrode chamber and the cathodic electrode chamber by at least one semipermeable membrane.

An encapsulated reactant(s) having at least one encapsulant and at least one reactant, and methods of making and using the encapsulated reactant(s), are presently provided. An outermost encapsulant is substantially nonreacting, impermeable and nondissolving with water. The reactant(s) contribute to at least one reaction with contaminants in environmental media rendering the environmental media less harmful.

An above-ground low-energy method of dewatering highly contaminated waste e.g. leachate contaminated with at least a first group of contaminants and PFAS is described. The method comprises the step of removing the PFAS before removing the first group of contaminants. The removal of PFAS is undertaken by actively aerating the contaminated waste comprising PFAS to produce a waste stream comprising a concentration of PFAS and a liquid stream having at least some of the first group of contaminants. The one or more liquid streams are separated from the waste streams so as to dewater the contaminated waste. Optionally, the liquid streams are treated to remove the first group of contaminants.

In a system and process, organic waste is treated in a reactor to volatilize contaminants such as Perfluoroalkyl substances (PFAS) compounds and/or Contaminants of Emerging Concern (CECs) from the organic waste. Biochar may have reduced or undetectable PFAS compounds or CECs. Most or all of the gas may be thermally oxidized to convert PFAS compounds and/or CECs into less harmful and/or less toxic products or elemental compounds, which may be further removed. Energy may be recovered from one or more parts of the herein described system and process.

The present disclosure discloses a method for removing chlorinated hydrocarbons in groundwater through step-by-step electrocatalytic dechlorination degradation. A double-chamber electrolyzer reactor is used to carry out step-by-step electrocatalytic dechlorination degradation to remove chlorinated hydrocarbons in groundwater. The double-chamber electrolyzer reactor comprises a cathode chamber, a proton exchange membrane, an anode chamber and an intermediate processing unit, wherein the cathode chamber is separated from the anode chamber through the proton exchange membrane, and the intermediate processing unit is connected between the cathode chamber and the anode chamber through a cathode chamber water outlet, an anode chamber water inlet and pipelines. The double-chamber electrolyzer reactor adopted in the present disclosure is simple in structure and convenient to use, is capable of effectively enhancing the removal effect of electric catalysis on chlorinated hydrocarbon substances and reducing toxic and harmful substances produced by direct oxidization of chlorinated hydrocarbons, and has a good application prospect.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

A method and apparatus break down organic materials, typically contaminants, through oxidation. The method for the treatment of a volume of material, provides: a) introducing at least two electrodes into a location, the location containing the volume of material and the volume of material containing one or more species for treatment; b) providing connections between a voltage source and the at least two electrodes; c) applying a voltage of a first polarity to the connections for a first period of time, under the control of a voltage controller; d) applying a voltage of a second, reversed, polarity to the connections for a second period of time, under the control of the voltage controller; e) repeating steps c) and d) a plurality of times; preferably with steps c), d) and e) promoting oxidation of one or more of the one or more species for treatment.

A nano zero valent iron biological coupling device for organic wastewater includes a continuous flow stirred reactor, a flocculation sedimentation device and a membrane bioreactor arranged in series. A nano zero valent iron feeding device is arranged in the continuous flow stirred reactor, a flocculant and a coagulant aid are arranged in the flocculation sedimentation device, and a microbial reaction liquid is arranged in the membrane bioreactor. A nano iron biological coupling process includes: S1, placing the organic wastewater in the continuous flow stirred reactor, adding the nano zero valent iron, stirring and mixing; S2, placing the organic wastewater treated after S1 in the flocculation sedimentation device; S3, placing the organic wastewater treated after S2 in the membrane bioreactor and interacting with the microbial reaction liquid; S4, performing a membrane separation on the organic wastewater treated after S3 in the membrane bioreactor to obtain purified organic wastewater.