Disclosed are methods of monitoring the presence of naphthenic acids and related compounds. In particular, the invention provides a method of continuously monitoring naphthenic acids and related compounds that break through a filtration step in a wastewater treatment process.

Improved reverse osmosis (RO) systems include at least first and second stages wherein each stage has at least one RO membrane, each stage has a feed stream inlet, a permeate stream outlet, and a concentrate stream outlet, the feed stream inlet of the second stage is coupled to the concentrate stream outlet of the first stage, the second pressure is greater than the first pressure, and pressure exchangers associated with each of the first and second stages are configured to recover energy from the second stage concentrate stream. The systems include M reverse osmosis membranes in the first stage and N reverse osmosis membranes in the second stage, wherein M≧N. The first pressure and second pressure are configured so that spatial variance in flux of the first stage permeate stream relative to flux of the second stage permeate stream is minimized.

An electro-kinetic agglomerator for resolving crude oil and water emulsions containing charged particles by the application of a direct current voltage potential. The electro-kinetic agglomerator comprises a shaftless auger with a charged conductive rod positioned in the center of the shaftless auger and a charged porous drum surrounding wherein the electro-kinetic agglomerator has a DC voltage gradient such that the charged particles are attracted to the conductive rod.

The present invention comprises a process and apparatus for separation of hydrocarbons from hydrocarbon-containing produced water, wherein in stage 1 the hydrocarbon-containing produced water is supplied with a gas-containing component, whereupon a gas- and hydrocarbon-containing produced water mixture is fed to an inlet tube (22, 27) in the center of a tank, whereupon the said mixture is tangentially distributed via at least one nozzle (7) and at least one baffle plate (8.1), whereupon separated hydrocarbons are conveyed to at least one outlet from the tank and cleaned water is conveyed to an outlet (12) from the tank.

A near-zero-release treatment system and method for high concentrated organic wastewater is in the chemical engineering and environment protection field, whose core technology is SCWO. The wastewater and sludge are grinded by the homogeneous pump, pressurized by high-pressure plunger pump, transported to successive pipeline for preheating and mixing with the oxygen and undergoes SCWO reaction in the reactor. After pressure release in the pressure relief device, the reacted fluid passes through the self-cleaning filter and gas liquid separator for insoluble solid and gas separation; then enters the MVR for crystallization of the soluble salts to realize near-zero-release of the feeding. The regular water treatment technology (coagulation sedimentation, membrane biotechnology, membrane technology, etc.) is adopted to complement SCWO, which lowers the operating parameters of the reactor and cuts the operating cost by treating the remaining COD with regular water treatment technology.

A system and method of treating sour water, including providing sour water having hydrosulfide ions and a carbon-containing compound to an anodic chamber of an electrolyzer vessel, converting the hydrosulfide ions into sulfate ions in the anodic chamber via an oxido half-reaction of a first oxido-reduction reaction and generating carbon dioxide in the anodic chamber via an oxido half-reaction of a second oxido-reduction reaction associated with the carbon-containing compound. The technique includes reacting the carbon dioxide with hydroxide ions in the anodic chamber to generate bicarbonate ions. The technique includes discharging an anodic chamber solution having the sulfate ions and the bicarbonate ions from the electrolyzer vessel from the anodic chamber.

A method may include: introducing triglycerides, hydrogen, and a sulfiding agent into a hydroprocessing reactor; reacting the triglycerides with the hydrogen in the hydroprocessing reactor to form at least paraffins; separating at least a portion of a hydroprocessing reactor effluent from the hydroprocessing reactor in a first phase separator to produce a first sour water stream comprising water and a first quantity of hydrogen sulfide and a paraffin stream comprising at least a portion of the paraffins; introducing the first sour water stream into a sour water stripper and stripping the first sour water stream to form a gaseous stream comprising at least a portion of the first quantity of the hydrogen sulfide from the first sour water stream; and contacting the gaseous stream with an acidified wash water in an ammonia removal unit to produce an aqueous ammonia solution stream and a treated gaseous hydrogen sulfide stream; and introducing the treated hydrogen sulfide stream into the hydroprocessing reactor. The aqueous ammonia solution stream is neutralized with an acid to form an ammonium salt solution product.

Cysteine synthase enzymes (e.g. O-Acetyl-L-Serine Sulfhydrylase enzymes) may be used in combination with sulfide quinone reductase enzymes in additive compositions, fluid compositions, and methods for decreasing or removing hydrogen sulfide from recovered downhole fluids and/or the subterranean reservoir wellbore from which the downhole fluid was recovered. The fluid composition may include at least one cysteine synthase enzyme with at least one sulfide quinone reductase, and a base fluid, such as a water-based fluid, an organic-based fluid, and combinations thereof.

The present invention discloses a process and a composition for the treatment of wastewater. The composition comprises of microbes, enzymes and cofactors along with the nutrients. The composition is a synergistic composition and wastewater can be treated effectively for the removal of pollutants by using the synergistic composition.

A method of preparing a microorganisms-immobilized felt-based resin includes the following steps: providing a mixture of an acrylate monomer, an initiator, a solvent, and water; adding a felt to the mixture; initiating a polymerization reaction of the mixture to form a felt-based resin; and immobilizing microorganisms on the felt-based resin to form the microorganisms-immobilized felt-based resin.