An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

A co-doped optical fiber is provided having an attenuation of less than about 0.17 dB/km at a wavelength of 1550 nm. The fiber includes a core in the fiber having a graded refractive index profile with an alpha of greater than 5. The fiber also includes a cladding in the fiber that surrounds the core addition, the core includes silica that is co-doped with two or more halogens.

An optical component made of synthetic quartz glass includes a glass structure substantially free of oxygen defect sites and having a hydrogen content of 0.110.sup.16 to 1.010.sup.18 molecules/cm.sup.3, an SiH group content of less than 210.sup.17 molecules/cm.sup.3, a hydroxyl group content of 0.1 to 100 wt. ppm, and an Active temperature of less than 1070 C. The optical component undergoes a laser-induced change in the refractive index in response to irradiation by a radiation with a wavelength of 193 nm using 510.sup.9 pulses with a pulse width of 125 ns and a respective energy density of 500 J/cm.sup.2 at a pulse repetition frequency of 2000 Hz. The change totals a first measured value M.sub.193 nm when measured using the applied wavelength of 193 nm and a second measured value M.sub.633 nm when measured using a measured wavelength of 633 nm. The ratio M.sub.193 nm/M.sub.633 nm is less than 1.7.

A single mode optical fiber having a core made from silica and less than or equal to about 11 weight % germania and having a maximum relative refractive index .sub.1MAX. The optical fiber also has an inner cladding surrounding the core and having a minimum relative refractive index .sub.2MIN, a first outer cladding surrounding the inner cladding and a second outer cladding surrounding the first outer cladding. The viscosity at 1650 C. of the second outer cladding minus the viscosity at 1650 C. of the first outer cladding is greater than 0.1e.sup.7 Poise, and .sub.1MAX>.sub.2MIN. The single mode optical fiber may also have an outer cladding surrounding the inner cladding made from silica or SiON. The first outer cladding has a maximum relative refractive index .sub.3MAX, and .sub.3MAX>.sub.2MIN.

A single mode optical fiber having a core made from silica and less than or equal to about 11 weight % germania and having a maximum relative refractive index .sub.1MAX. The optical fiber also has an inner cladding surrounding the core and having a minimum relative refractive index .sub.2MIN, a first outer cladding surrounding the inner cladding and a second outer cladding surrounding the first outer cladding. The viscosity at 1650 C. of the second outer cladding minus the viscosity at 1650 C. of the first outer cladding is greater than 0.1e.sup.7 Poise, and .sub.1MAX>.sub.2MIN. The single mode optical fiber may also have an outer cladding surrounding the inner cladding made from silica or SiON. The first outer cladding has a maximum relative refractive index .sub.3MAX, and .sub.3MAX>.sub.2MIN.

Hollow ingots of transparent synthetic vitreous silica glass of external diameter greater than 400 mm and internal diameter greater than 300 mm are disclosed. The ingots are substantially free from bubbles or inclusions greater than 100 m in diameter, have no more than 100 ppB of any individual metallic impurity, and have chlorine concentration less than 5 ppM. Also disclosed are methods for producing such ingots, in which a porous soot body of density greater than 0.4 g/cm.sup.3 is deposited on an oxidation resistant mandrel. The soot body is dehydrated on a mandrel comprising graphite, carbon fiber reinforced carbon, silicon carbide, silicon impregnated silicon carbide, silicon carbide-coated graphite or vitreous silica, either under vacuum or in the presence of a reducing gas, and then sintered to transparent pore-free glass under vacuum or in an atmosphere of helium.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

A method of manufacturing a hollow core optical fiber including a vapor deposition step comprising vapor depositing a silica soot coating from one or more source materials over an outer surface of a cladding substrate tube of a workpiece that further includes capillary tubes disposed within a cavity of the cladding substrate tube. The compositions of the capillary tubes, the cladding substrate tube, and the silica soot coating can be manipulated with one or more viscosity-raising dopants or one or more viscosity-lowering dopants, or neither, to achieve a desired compositional profile of a hollow core optical fiber preform with a cladding consolidated from the silica soot coating of the workpiece. The desired composition profile results in a viscosity profile that prevents the capillary tubes from contacting each other during a drawing step performed upon the hollow core optical fiber preform.