A method for preparing a doped optical fibre preform includes formulating, a rare earth material or a functional metal material and a co-doping agent into a doping solution, mixing a high-purity quartz powder with the doping solution, drying same at a temperature of 100 C.-150 C. for 12-48 hours, crushing and screening the same to obtain a doped quartz powder; depositing the doped quartz powder onto the surface of a target rod to form a doped core layer; replacing the doped quartz powder with the high-purity quartz powder, and depositing the high-purity quartz powder onto the surface of the doped core layer to form a quartz outer cladding; and removing the target rod, and gradually collapsing the entirety formed from the doped core layer and the quartz outer cladding at a high temperature to obtain the doped optical fibre preform.

The optical fiber offered is capable of not only restraining the attenuation due to glass defects, but also reducing the increase of manufacturing cost. The optical fiber is made of silica glass and includes a core and a cladding. The cladding encloses the core and has a refractive index smaller than that of the core. When the core is divided into inner core and outer core at half of the radius of the core, the average chlorine concentration of the inner core is larger than that of the outer core. The core includes any of the alkali metal group.

The optical fiber offered is capable of not only restraining the attenuation due to glass defects, but also reducing the increase of manufacturing cost. The optical fiber is made of silica glass and includes a core and a cladding. The cladding encloses the core and has a refractive index smaller than that of the core. When the core is divided into inner core and outer core at half of the radius of the core, the average chlorine concentration of the inner core is larger than that of the outer core. The core includes any of the alkali metal group.

An optical fiber preform includes a silica-glass core portion, and a cladding portion surrounding the core portion, the cladding portion being composed of a fluorine-containing silica glass having a lower refractive index than the core portion, the core portion including a first region that does not include the central axis thereof, the first region containing a first dopant selected from sodium, potassium, and compounds thereof, and a second region that includes the central axis, the second region containing a second dopant that reduces the viscosity of the silica glass, the second dopant having a diffusion coefficient of 110.sup.12 cm.sup.2/s or more and less than the first dopant at 2,000 C. to 2,300 C., in which the entire core portion has an average first dopant concentration of 10 atomic ppm or more and 2,000 atomic ppm or less and an average second dopant concentration of 10 atomic ppm or more.

Provided is an alkali doping process of bringing a melt of an alkali metal compound or an alkaline earth metal compound into contact with a part of the inner circumferential surface of a silica glass tube, and thus doping the silica glass tube with the alkali metal compound or the alkaline earth metal compound, and in the alkali doping process, the contact location between the inner circumferential surface of the silica glass tube and the melt is moved along the longitudinal direction of the silica glass tube while rotating the silica glass tube around its longitudinal axis.

An optical fiber preform of the present embodiment comprises a core portion and a cladding each comprised of silica glass. The core portion has a first dopant region including a central axis of the core portion and a second dopant region away from the central axis. The first dopant region contains a first dopant selected from among Na, K, and their compounds, and a concentration of the first dopant is 10 atomic ppm or more but 2,000 atomic ppm or less. The second dopant region contains a second dopant reducing viscosity of the silica glass. The second dopant has, as a characteristic at a temperature of 2,000 C. to 2,300 C., a diffusion coefficient of 110.sup.12 cm.sup.2/s or higher but lower than that of the first dopant, and a concentration of the second dopant region is 10 atomic ppm or more.

A method for preparing a doped optical fibre preform includes formulating, a rare earth material or a functional metal material and a co-doping agent into a doping solution, mixing a high-purity quartz powder with the doping solution, drying same at a temperature of 100C.-150C. for 12-48 hours, crushing and screening the same to obtain a doped quartz powder; depositing the doped quartz powder onto the surface of a target rod to form a doped core layer; replacing the doped quartz powder with the high-purity quartz powder, and depositing the high-purity quartz powder onto the surface of the doped core layer to form a quartz outer cladding; and removing the target rod, and gradually collapsing the entirety formed from the doped core layer and the quartz outer cladding at a high temperature to obtain the doped optical fibre preform.

An optical fiber containing alkali metal elements or the like in which Rayleigh scattering loss can be reduced is provided. An optical fiber includes a core composed of silica glass and a cladding which surrounds the core, has a refractive index lower than a refractive index of the core, and is composed of silica glass containing fluorine. The core contains a first group of dopants and a second group of dopants having a diffusion coefficient lower than a diffusion coefficient of the first group of dopants. The difference between the maximum value and the minimum value of residual stress in the optical fiber is 150 MPa or less.

An optical fiber is formed from silica-based glass. The optical fiber includes a core including a central axis and a cladding surrounding the core. A refractive index of the core is greater than a refractive index of the cladding. The core contains chlorine, and one or more kinds of elements selected from an element group consisting of alkali metal elements and alkaline earth metal elements. A relative refractive index difference of the core based on a refractive index of pure silica is 0.00% or greater and 0.15% or less. An average concentration of fluorine in the cladding is 1.2% or less in a mass fraction.

Provided is lithium disilicate crystalline glass containing cristobalite crystal phase for high strength and aesthetic traits and its manufacturing process thereof. Exemplary embodiments of the present invention provide the high strength and aesthetic lithium disilicate crystalline glass, one kind of dental restoration materials, and its manufacturing method which induces the growth of the different crystal phase, cristobalite, from glass with lithium disilicate crystal.